Fluoropolyether-containing polymer-modified silane, surface treating agent, and article
US-2015274889-A1 · Oct 1, 2015 · US
US11746237B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11746237-B2 |
| Application number | US-201816969435-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 22, 2018 |
| Priority date | Feb 13, 2018 |
| Publication date | Sep 5, 2023 |
| Grant date | Sep 5, 2023 |
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Provided are: a (hydrolyzable) organosiloxane compound which is represented by general formula (1) and contains a lipophilic group capable of forming a cured film having excellent lipophilicity and wear resistance; and a surface treatment agent containing the compound. (In the formula, A is any one among —CH 3 , —C(═O)OR 1 , —C(═O)NR 1 2 , —C(═O)SR 1 , and —P(═O)(OR 1 ) 2 ; R 1 is a hydrogen atom, a C1-30 alkyl group, a C6-30 aryl group, or a C7-30 aralkyl group; Y is independently a divalent organic group; W is independently a C1-4 alkyl group, a phenyl group, a hydroxyl group, or a hydrolyzable group; R is independently a C1-4 alkyl group or a phenyl group; X is independently a hydroxyl group or a hydrolyzable group; n is an integer of 1-3; and q is an integer of 1-3.)
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The invention claimed is: 1. An organosiloxane compound having the general formula (1): wherein A is —C(═O)OR 1 , —C(═O)NR 1 2 , —C(═O)SR 1 , or —P(═O)(OR 1 ) 2 , R 1 is hydrogen, a C 1 -C 30 alkyl group, C 6 -C 30 aryl group, or C 7 -C 30 aralkyl group, Y is independently a divalent organic group, W is independently a C 1 -C 4 alkyl group, phenyl group, hydroxyl group or hydrolyzable group, R is independently a C 1 -C 4 alkyl group or phenyl group, X is independently a hydroxyl group or hydrolyzable group, n is an integer of 1 to 3, and q is an integer of 1 to 3. 2. The organosiloxane compound of claim 1 , having the general formula (2): wherein R 2 is a C 1 -C 20 alkyl group, C 6 -C 20 aryl group or C 7 -C 20 aralkyl group, Q is a single bond or a divalent group selected from among silalkylene, silarylene, and straight, branched or cyclic divalent organopolysiloxane residues of 2 to 10 silicon atoms, m is each independently an integer of 1 to 20, and X is independently a hydroxyl group or hydrolyzable group. 3. The organosiloxane compound of claim 1 wherein in formula (1), X is each independently selected from the group consisting of hydroxyl, C 1 -C 10 alkoxy, C 2 -C 10 alkoxy-substituted alkoxy, C 1 -C 10 acyloxy, C 2 -C 10 alkenyloxy, halogen, oxime, isocyanate, and cyanate. 4. A surface treating agent comprising the organosiloxane compound of claim 1 . 5. The organosiloxane compound of claim 2 wherein in formula (2), X is each independently selected from the group consisting of hydroxyl, C 1 -C 10 alkoxy, C 2 -C 10 alkoxy-substituted alkoxy, C 1 -C 10 acyloxy, C 2 -C 10 alkenyloxy, halogen, oxime, isocyanate, and cyanate.
by carbon linkages · CPC title
containing less than 25 silicon atoms · CPC title
in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms (C09D183/10 takes precedence) · CPC title
Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title
containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen · CPC title
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