Poly(aryl-ether-ketone) (PAEK) powder suitable for multiple use in sintering methods

Patent metadata

Field	Value
Publication number	US-11746188-B2
Application number	US-201716080261-A
Country	US
Kind code	B2
Filing date	Feb 28, 2017
Priority date	Mar 4, 2016
Publication date	Sep 5, 2023
Grant date	Sep 5, 2023

Abstract

Provided is a poly(aryl-ether-ketone) (PAEK) powder suitable for use in a method for building objects layer-by-layer by electromagnetic radiation-generated sintering, which is obtained from a thermal pretreatment at a temperature between 260° C. and 290° C. and which has a melting temperature which is stable, at the build temperature, and below or equal to 330° C.

First claim

The invention claimed is:

1. A method for building a three-dimensional object layer-by-layer by electromagnetic radiation-generated sintering of powder,
wherein the powder is a poly(aryl-ether-ketone) (PAEK) powder, the powder being obtained from thermal pretreatment at a temperature between 260° C. and 290° C. and having a melting temperature which is stable at the build temperature and which is below or equal to 330° C.,
wherein the powder comprises a mixture of recycled and non-recycled powders,
wherein parameters of the sintering machine include laser power and powder bed temperature,
wherein the sintering is conducted in a sintering machine and wherein at least two successive sinterings are carried out while keeping the laser power of the sintering machine and the bed temperature unchanged, and
wherein the second sintering of the at least two successive sinterings uses the unsintered powder from the first sintering of the at least two successive sinterings as recycled powder.

2. The method according to claim 1 , wherein the thermal pretreatment is carried out for a period between 5 min and 120 min.

3. The method according to claim 1 , wherein the powder comprises a mixture of several polymers belonging to the PAEK family, the melting temperature Tm of which is below or equal to 330° C.

4. The method according to claim 1 , wherein the powder comprises at least one poly(ether-ketone-ketone) (PEKK) powder which represents more than 60% by weight, bounds included.

5. The method according to claim 1 , wherein the powder is a poly(ether-ketone-ketone) (PEKK) powder.

6. The method according to claim 4 , wherein the PEKK powder has a percentage by weight of terephthalic units relative to the sum of terephthalic and isophthalic units comprised between 55% and 65%.

7. The method according to claim 1 , wherein molecular weight of the powder remains stable during sintering.

8. The method according to claim 1 , wherein melting temperature of the powder does not increase by more than 2° C. after each sintering run.

9. The method according to claim 1 , wherein melting temperature of the powder does not increase by more than 1° C. after each sintering run.

10. A method for building a three-dimensional object layer-by-layer by electromagnetic radiation-generated sintering of powder,
wherein the powder is a poly(aryl-ether-ketone) (PAEK) powder, the powder being obtained from thermal pretreatment at a temperature between 260° C. and 290° C. and having a melting temperature which is stable at the build temperature and which is below or equal to 330° C.,
wherein the powder comprises a mixture of recycled and non-recycled powders, the recycled powders having been used in an identical and/or a different number of cycles,
wherein parameters of the sintering machine include laser power and powder bed temperature,
wherein the sintering is conducted in a sintering machine and wherein successive sintering is carried out while keeping the bed temperature unchanged,
wherein the bed temperature is the same bed temperature as the one which would be used for sintering a totally non-recycled powder of the PAEK.

11. The method according to claim 10 , wherein the bed temperature is the same bed temperature as the one which would be used for sintering a totally non-recycled powder of the PAEK, and the laser power is the same laser power as the one which would be used for sintering a totally non-recycled powder of the PAEK.

12. A method for building a three-dimensional object layer-by-layer by electromagnetic radiation-generated sintering of powder,
wherein the powder is a poly(aryl-ether-ketone) (PAEK) powder, the powder being obtained from thermal pretreatment at a temperature between 260° C. and 290° C. and having a melting temperature which is stable at the build temperature and which is below or equal to 330° C.,
wherein the powder comprises a mixture of recycled and non-recycled powders, the recycled powders having been used in an identical and/or a different number of cycles,
wherein parameters of the sintering machine include laser power and powder bed temperature,
wherein the sintering is conducted in a sintering machine and wherein successive sintering is carried out while keeping laser power of the sintering machine, the bed temperature unchanged, wherein the laser power is the same laser power as the one which would be used for sintering a totally non-recycled powder of said PAEK.

13. The method according to claim 12 , wherein the bed temperature is the same bed temperature as the one which would be used for sintering a totally non-recycled powder of the PAEK, and the laser power is the same laser power as the one which would be used for sintering a totally non-recycled powder of the PAEK.

Assignees

• Arkema France

Inventors

• Brule Benoît
• Pascal Jérome

Classifications

• C08G65/4012 Primary

  Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones · CPC title

• B29C64/153

  using layers of powder being selectively joined, e.g. by selective laser sintering or melting · CPC title

• B29C64/264

  Arrangements for irradiation · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B29K2071/00

  Use of polyethers {, e.g. PEEK, i.e. polyether-etherketone or PEK, i.e. polyetherketone or derivatives thereof}, as moulding material · CPC title