Process for start-up of an autothermal reformer

Patent metadata

Field	Value
Publication number	US-11746009-B2
Application number	US-202017125540-A
Country	US
Kind code	B2
Filing date	Dec 17, 2020
Priority date	Dec 19, 2019
Publication date	Sep 5, 2023
Grant date	Sep 5, 2023

Abstract

The invention relates to a process for the start-up of an autothermal reformer, wherein syngas is produced in the autothermal reformer during start-up through steam reforming. To facilitate autoignition in the autothermal reformer reactor of the autothermal reformer, the reformed syngas is recycled to an upstream section of the autothermal reformer reactor and is mixed with process steam and a hydrocarbon containing process stream. As soon as a minimum hydrogen threshold concentration at the upstream section of the autothermal reformer reactor is reached in the mixed process stream, oxygen is added to the burner of the ATR reactor to obtain autoignition of the mixed process stream. Due to the process of the invention, an external hydrogen source for facilitating autoignition of the mixed stream can be omitted. The invention further relates to a plant configured to carry out the process of the invention.

First claim

What is claimed is:

1. A process for the start-up of an autothermal reformer, the autothermal reformer comprising an autothermal reformer reactor with a burner, the process comprising:
heating an inert gas by an inert gas heating means, and introducing the heated inert gas in a circulation loop containing the autothermal reformer reactor;
heating a mixture of inert gas and process steam by a mixture heating means, and introducing the heated mixture of inert gas and process steam in the circulation loop containing the autothermal reformer reactor;
introducing heated process steam in the circulation loop as soon as a minimum outlet threshold temperature of the autothermal reformer reactor is reached, wherein inert gas is removed from the circulation loop;
heating a hydrocarbon containing process stream by a hydrocarbon stream heating means, and introducing the heated hydrocarbon containing process stream into the autothermal reformer reactor, whereby a syngas stream containing carbon oxides and hydrogen is produced in the autothermal reformer reactor through steam reforming;
cooling the produced syngas stream to separate water from the syngas stream as process condensate, whereby a dry syngas stream is obtained;
recycling a fraction of the dry syngas stream from a downstream section of the autothermal reformer reactor to an upstream section of the autothermal reformer reactor; whereby
a mixed process stream is obtained at the upstream section of the autothermal reformer reactor, the mixed process stream containing the process steam, the hydrocarbon containing process stream and the recycled dry syngas stream;
introducing the mixed process stream to the burner of the autothermal reformer reactor;
introducing an oxygen containing process stream to the burner of the autothermal reformer reactor as soon as a minimum hydrogen threshold concentration in the mixed process stream at the upstream section of the autothermal reformer reactor is reached; whereby
autoignition of the mixed process stream is obtained; and
operating the autothermal reformer to produce syngas through autothermal reforming.

2. The process according to claim 1 , wherein the minimum hydrogen threshold concentration in the mixed process stream is up to 15.0 mol-% on a wet basis.

3. The process according to claim 1 , wherein the minimum outlet threshold temperature of the autothermal reformer reactor is between 500° C. to 650° C.

4. The process according to claim 1 , wherein the fraction of the dry syngas stream is compressed by means of a gas compressor prior to being introduced into the autothermal reformer reactor.

5. The process according to claim 4 , wherein the hydrocarbon containing process stream is compressed by the gas compressor.

6. The process according to claim 1 , wherein the fraction of the dry syngas stream is compressed by means of a steam ejector prior to being introduced into the autothermal reformer reactor.

7. The process according to claim 6 , wherein the hydrocarbon containing process stream is compressed by the steam ejector.

8. The process according to claim 6 , wherein the heated process steam is used as a motive fluid for the steam ejector.

9. The process according to claim 1 , wherein the fraction of dry syngas recycled from the downstream section of the autothermal reformer reactor to the upstream section of the ATR is 40 to 70% of the volumetric flow of the dry syngas stream.

10. The process according to claim 1 , wherein the fraction of dry syngas recycled to the upstream section of the autothermal reformer reactor is 55 to 65% of the volumetric flow of the mixed process stream obtained at the upstream section of the ATR.

11. The process according to claim 1 , wherein the mixed process stream is heated to 500 to 650° C. before introducing it to the main burner of the autothermal reformer reactor.

12. The process according to claim 1 , wherein the autothermal reformer reactor is operated at 950° C. to 1050° C. after autoignition to produce syngas through autothermal reforming.

13. The process according to claim 1 , wherein the autothermal reformer is operated in series with a steam reformer, whereby syngas is produced by the autothermal reformer through autothermal reforming, and syngas is produced by the steam reformer through steam reforming.

14. The process according to claim 13 , wherein the syngas produced by the steam reformer is added to the upstream section of the autothermal reformer, whereby the mixed process stream contains the process steam, the hydrocarbon containing process stream, the recycled dry syngas stream and the added syngas produced by the steam reformer.

Assignees

• Air Liquide
• Air Liquide

Inventors

• Lim Chin Han
• Kopetsch Hans
• Gronemann Veronika

Classifications

• C01B3/34 Primary

  by reaction of hydrocarbons with gasifying agents · CPC title

• C01B3/346 Primary

  Chemistry & Metallurgy · mapped topic

• B01J19/0013

  Controlling the temperature of the process · CPC title

• B01J2219/00128

  by evaporation of reactants · CPC title

• B01J2219/00157

  by means of a burner · CPC title