Fibrous substrates for hydrogen generation

Patent metadata

Field	Value
Publication number	US-11746007-B2
Application number	US-202117208853-A
Country	US
Kind code	B2
Filing date	Mar 22, 2021
Priority date	Mar 22, 2021
Publication date	Sep 5, 2023
Grant date	Sep 5, 2023

Abstract

The disclosure describes a system for generating hydrogen gas from a hydrocarbon through pyrolysis with reduced soot formation and increased carbon loading. The system includes a pyrolysis reactor configured to generate the hydrogen gas from the hydrocarbon through pyrolysis. The pyrolysis reactor includes one or more fibrous substrates configured to provide a deposition surface for carbon generated from the pyrolysis of the hydrocarbon. Each fibrous substrate has an effective void fraction between 40% and 95%, and includes a plurality of fibers configured to maintain chemical and structural stability between about 850° C. and about 1300° C. The one or more fibrous substrates may have a relatively high surface area to fiber volume of the plurality of fibers.

First claim

What is claimed is:

1. A system for generating hydrogen, comprising:
a pyrolysis reactor configured to generate the hydrogen gas from a hydrocarbon through pyrolysis, wherein the pyrolysis reactor comprises one or more fibrous substrates defining a deposition surface for carbon generated from the pyrolysis of the hydrocarbon, wherein each fibrous substrate of the one or more fibrous substrates has an effective void fraction between 40% and 95%, and wherein each fibrous substrate of the one or more fibrous substrates comprises a plurality of fibers configured to maintain chemical and structural stability between 850° C. and 1300° C.

2. The system of claim 1 , wherein the plurality of fibers has an average fiber diameter that is less than about 10 microns.

3. The system of claim 1 , wherein respective fibers of the plurality of fibers each have a non-circular cross-section.

4. The system of claim 3 , wherein respective fibers of the plurality of fibers have a perimeter that includes at least one of a serrated shape or a multi-lobal shape.

5. The system of claim 1 , wherein respective fibers of the plurality of fibers are hollow.

6. The system of claim 1 ,
wherein the pyrolysis reactor defines an inlet at a first end, an outlet at a second end, and an axis between the first and second ends, and
wherein the one or more fibrous substrates have a surface area that varies axially along the axis from the inlet to the outlet.

7. The system of claim 1 ,
wherein the pyrolysis reactor defines an inlet at a first end, an outlet at a second end, and an axis between the first and second ends, and
wherein the one or more fibrous substrates have a surface area that varies radially along the axis from the inlet to the outlet.

8. The system of claim 1 ,
wherein pyrolysis reactor defines an inlet at a first end, an outlet at a second end, and an axis between the first and second ends, and
wherein the pyrolysis reactor is configured to heat at least one fibrous substrate such that the pyrolysis reactor has a temperature that varies axially along the axis from the inlet to the outlet.

9. The system of claim 1 , wherein the plurality of fibers comprises at least one of carbon, zirconium dioxide, or silicon dioxide.

10. The system of claim 1 , wherein the one or more fibrous substrates are self-supporting.

11. The system of claim 1 , wherein the hydrocarbon is methane, wherein the pyrolysis reactor is configured to generate carbon and a first portion of hydrogen gas from the methane, and wherein the system further comprises:
a Sabatier reactor configured to:
receive the first portion of hydrogen gas from the pyrolysis reactor and a second portion of hydrogen gas from an oxygen generation system;
generate the methane and water from carbon dioxide and the first and second portions of hydrogen gas; and
discharge the methane to the pyrolysis reactor; and

an oxygen generation system configured to:
receive the water from the Sabatier reactor;
generate oxygen and the second portion of hydrogen gas from the water; and
discharge the second portion of hydrogen gas to the Sabatier reactor.

12. A method for generating hydrogen gas, comprising:
receiving, by a pyrolysis reactor, a hydrocarbon; and
pyrolyzing, by the pyrolysis reactor, the hydrocarbon to generate the hydrogen gas and carbon,
wherein the pyrolysis reactor comprises one or more fibrous substrates defining a deposition surface for the carbon generated from the pyrolysis of the hydrocarbon,
wherein each fibrous substrate of the one or more fibrous substrates has an effective void fraction between 40% and 95%, and
wherein each fibrous substrate of the one or more fibrous substrates comprises a plurality of fibers configured to maintain chemical and structural stability between 850° C. and 1300° C.

13. The method of claim 12 , wherein the plurality of fibers has an average fiber diameter that is less than about 10 microns.

14. The method of claim 12 , wherein the respective fibers of the plurality of fibers have a non-circular cross-section.

15. The method of claim 14 , wherein the respective fibers of the plurality of fibers have a perimeter that includes at least one of a serrated shape or a multi-lobal shape.

16. The method of claim 12 , wherein the respective fibers of the plurality of fibers have a hollow lumen.

17. The method of claim 12 ,
wherein the pyrolysis reactor defines an inlet at a first end, an outlet at a second end, and an axis between the first and second ends, and
wherein the one or more fibrous substrates have a surface area that varies axially along the axis from the inlet to the outlet.

18. The method of claim 12 ,
wherein the pyrolysis reactor defines an inlet at a first end, an outlet at a second end, and an axis between the first and second ends, and
wherein the one or more fibrous substrates have a surface area that varies radially across the axis from the inlet to the outlet.

19. The method of claim 12 ,
wherein the pyrolysis reactor defines an inlet at a first end, an outlet at a second end, and an axis between the first and second ends, and
wherein heating the hydrocarbon further comprises heating the pyrolysis reactor such that the pyrolysis reactor has a temperature that varies axially along the axis from the inlet to the outlet.

20. The method of claim 12 , further comprising:
generating, by the pyrolysis reactor, hydrogen gas and carbon from methane;
generating, by a Sabatier reactor, methane and water from carbon dioxide and the hydrogen gas from the pyrolysis reactor;
discharging, by the Sabatier reactor, the methane to the methane pyrolysis reactor.
generating, by an electrolysis system, oxygen gas and hydrogen gas from the water from the Sabatier reactor; and
discharging, by the electrolysis system, the hydrogen gas to the Sabatier reactor.

Assignees

• Honeywell Int Inc

Inventors

• Michalakos Peter M
• Childers Amanda

Classifications

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• C01B3/24 Primary

  of hydrocarbons · CPC title

• B01J6/008 Primary

  Pyrolysis reactions (of hydrocarbons C10G9/00) · CPC title

• C25B1/04

  by electrolysis of water · CPC title

• C01B2203/0272

  containing a non-catalytic decomposition step · CPC title