Decorative material having excellent printing properties and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-11745530-B2
Application number	US-201917276035-A
Country	US
Kind code	B2
Filing date	Jul 15, 2019
Priority date	Sep 13, 2018
Publication date	Sep 5, 2023
Grant date	Sep 5, 2023

Abstract

The present invention relates to a decorative material having excellent printability, and the decorative material according to the present invention has an ink-receiving layer having a radially fine sloping structure having a dendritic shape, whereby the absorbing and/or fixing property, i.e., printability, of the ink printed on the ink-receiving layer is improved, and clarity is excellent, so that aesthetic effects are excellent. In addition, since the ink-receiving layer is manufactured through UV curing, it can be directly coated on a substrate layer, and can include various kinds of substrate layers; and since it is manufactured using a solvent-free type resin composition without using an organic solvent, and has an excellent absorbing and/or fixing property with respect to a water soluble ink, it has environmental friendly advantages.

First claim

The invention claimed is:

1. A decorative material comprising a substrate layer, an ink-receiving layer, and a printed layer;
wherein the ink-receiving layer comprises an ink-receiving layer of an acrylic resin composition having a dendritic shape, which is a radially sloping structure extending from a center to a periphery with a point on the surface as the center; and
an average size of ink droplets present in a unit area of 0.1 cm 2 when observing the surface with an optical microscope is 50 μm or less.

2. The decorative material of claim 1 , wherein the radially sloping structure is present in a number of 20 to 400 in a unit area of 1 mm×1 mm of the surface.

3. The decorative material according to claim 1 , wherein the average diameter of the radially sloping structure is 5 μm to 500 μm.

4. The decorative material according to claim 1 , wherein the surface roughness (Rz) of the ink-receiving layer is 0.5 μm to 10 μm on average.

5. The decorative material according to claim 1 , wherein the ink-receiving layer has an average static water contact angle of 5° to 60°.

6. The decorative material according to claim 1 , further comprising a transparent layer on the printed layer.

7. A method of manufacturing a decorative material, comprising the steps of:
irradiating an acrylic resin composition applied on a substrate layer with ultraviolet rays to form an ink-receiving layer having a dendritic shape in which one point on a surface is set as a center and which has a radially sloping structure extending from the center to a periphery; and
forming a printed layer with ink on the formed ink-receiving layer,
wherein the step of forming the printed layer is carried out at a printing speed of 50 to 150 m/min.

8. The method according to claim 7 , wherein the light irradiation step comprises:
a first light irradiation step of irradiating the acrylic resin composition applied on the substrate layer with light having a wavelength of 200 nm or less under an inert gas condition to activate the composition; and
a second light irradiation step of irradiating the activated composition with light of a wavelength between 200 nm and 400 nm under an air condition to cure the composition to form the ink-receiving layer.

9. The method according to claim 8 , wherein the first light irradiation step is carried out at a light irradiation amount of 1 mJ/cm 2 to 150 mJ/cm 2 .

10. The method according to claim 8 , wherein the first light irradiation step is carried out under a nitrogen (N 2 ) condition in which the concentration of oxygen (O 2 ) is 10 ppm to 3,500 ppm.

11. The method according to claim 7 , wherein the acrylic resin composition comprises:
100 parts by weight of a urethane (meth)acrylic oligomer;
30 to 90 parts of an acrylic monomer having a hydrophilic functional group; and
50 to 150 parts of a polyfunctional acrylic monomer.

12. The method according to claim 8 , wherein the acrylic resin composition further contains at least one filler selected from the group consisting of silica, alumina, glass beads, and organic beads.

13. The method according to claim 12 , wherein the content of the filler is 15 parts by weight or less, based on 100 parts of the acrylic resin composition.

14. The method according to claim 7 , wherein the acrylic resin composition has a viscosity of 500 cps or less.

15. The method according to claim 7 , further comprising a step of forming a transparent layer on the printed layer after the step of forming the printed layer.

Assignees

• Lg Hausys Ltd

Inventors

• Lee Han Na
• Kim Heon Jo
• Yang Se Ra

Classifications

• B41M7/0045 Primary

  using protective coatings or film forming compositions cured by mechanical wave energy, e.g. ultrasonics, cured by electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams, or cured by magnetic or electric fields, e.g. electric discharge, plasma · CPC title

• B44C1/16

  for applying transfer pictures or the like · CPC title

• C08F222/102

  of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C08J7/123 Primary

  Treatment by wave energy or particle radiation (C08J7/18 takes precedence) · CPC title