Drying method of polyimide paste and manufacturing method of solar cell having high photoelectric conversion efficiency

Patent metadata

Field	Value
Publication number	US-11742439-B2
Application number	US-201816759467-A
Country	US
Kind code	B2
Filing date	Aug 24, 2018
Priority date	Oct 26, 2017
Publication date	Aug 29, 2023
Grant date	Aug 29, 2023

Abstract

A drying method of a polyimide paste which can maintain a printing shape while maintaining productivity includes an organic solvent and a polyimide resin dissolved in the organic solvent, and which becomes cured polyimide by being cured as a result of being dried and heated, the drying method including a step of applying the polyimide paste to a surface of a base material, a step of applying a solvent including a polar material to a surface of the base material at least at a portion where the polyimide paste is applied, and a step of, after applying the solvent including the polar material, drying the polyimide paste and the solvent including the polar material.

First claim

The invention claimed is:

1. A drying method of a polyimide paste which includes an organic solvent and a polyimide resin dissolved in the organic solvent, and which becomes cured polyimide by being cured as a result of being dried and heated, the drying method comprising:
a step of applying the polyimide paste to a surface of a base material;
a step of applying a solvent including a polar material to a surface of the base material at least at a portion where the polyimide paste is applied; and
a step of, after applying the solvent including the polar material, drying the polyimide paste and the solvent including the polar material.

2. The drying method of the polyimide paste according to claim 1 ,
wherein the polar material is at least one type among water, ethylene glycol, acetic acid, methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, and formic acid.

3. The drying method of the polyimide paste according to claim 1 ,
wherein the solvent including the polar material is a solvent which includes the polar material of equal to or more than one percent by mass.

4. The drying method of the polyimide paste according to claim 2 ,
wherein the solvent including the polar material is a solvent which includes the polar material of equal to or more than one percent by mass.

5. A manufacturing method of a solar cell which includes a cured polyimide film formed with cured polyimide as part of a structure of the solar cell, the manufacturing method comprising:
a step of, when the cured polyimide film is formed, drying a polyimide paste using the drying method of the polyimide paste according to claim 1 .

6. A manufacturing method of a solar cell which includes a cured polyimide film formed with cured polyimide as part of a structure of the solar cell, the manufacturing method comprising:
a step of, when the cured polyimide film is formed, drying a polyimide paste using the drying method of the polyimide paste according to claim 2 .

7. A manufacturing method of a solar cell which includes a cured polyimide film formed with cured polyimide as part of a structure of the solar cell, the manufacturing method comprising:
a step of, when the cured polyimide film is formed, drying a polyimide paste using the drying method of the polyimide paste according to claim 3 .

8. A manufacturing method of a solar cell which includes a cured polyimide film formed with cured polyimide as part of a structure of the solar cell, the manufacturing method comprising:
a step of, when the cured polyimide film is formed, drying a polyimide paste using the drying method of the polyimide paste according to claim 4 .

9. A manufacturing method of a solar cell which includes a cured polyimide film formed with cured polyimide as part of a structure of the solar cell, the manufacturing method comprising:
a step of forming a pn junction which joins a p-type layer and an n-type layer within a semiconductor substrate;
a step of forming a p-type electrode which electrically contacts the p-type layer; and
a step of forming an n-type electrode which electrically contacts the n-type layer, and, further, when the cured polyimide film is formed,
a step of applying a polyimide paste which includes an organic solvent and a polyimide resin dissolved in the organic solvent, and which becomes the cured polyimide by being cured as a result of being dried and heated, to a surface of a structure including the semiconductor substrate;
a step of applying a solvent including a polar material of at least one type among water, ethylene glycol, acetic acid, methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, and formic acid, to a surface of the structure including the semiconductor substrate at least at a portion where the polyimide paste is applied;
a step of, after applying the solvent including the polar material, drying the polyimide paste and the solvent including the polar material; and
a step of heating and curing the dried polyimide paste to form the cured polyimide film.

10. The manufacturing method of the solar cell according to claim 9 ,
wherein the solvent including the polar material is a solvent which includes the polar material of equal to or more than one percent by mass.

Assignees

• Shinetsu Chemical Co

Inventors

• Watabe Takenori
• Hashigami Hiroshi
• Ohtsuka Hiroyuki

Classifications

• H10P14/683 Primary

  carbon-based polymeric organic materials, e.g. polyimides, poly cyclobutene or PVC · CPC title

• H10F10/14

  Photovoltaic cells having only PN homojunction potential barriers · CPC title

• H10F77/20

  Electrodes · CPC title

• H10F71/00 Primary

  Manufacture or treatment of devices covered by this subclass (patterning processes to connect thin photovoltaic cells in integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/33; manufacture or treatment of encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/80; manufacture or treatment of integrated devices, or assemblies of multiple devices, comprising at least one element in which radiation controls the flow of current H10F39/00) · CPC title

• H10F77/30

  Coatings (arrangements for preventing damage to photovoltaic cells caused by corpuscular radiation H10F77/80) · CPC title