Methods and systems for diagnosis of failure mechanisms and for prediction of lifetime of metal batteries

Patent metadata

Field	Value
Publication number	US-11740297-B2
Application number	US-202117249158-A
Country	US
Kind code	B2
Filing date	Feb 22, 2021
Priority date	Feb 25, 2020
Publication date	Aug 29, 2023
Grant date	Aug 29, 2023

Abstract

Methods for diagnosing failure mechanisms and for predicting lifetime of metal batteries include monitoring rest voltage and Coulombic Efficiency over relatively few cycles to provide profiles that indicate, by the trends thereof, a particular failure mechanism (e.g., electrolyte depletion, loss of metal inventory, increased cell impedance). The methods also include cycling over relatively few cycles an anode-free cell, having the same cathode and electrolyte as the metal battery, but with a current collector instead of the anode. Discharge capacity is monitored and profiled, and a discharge capacity curve is fitted to the discharge capacity profile to discern a capacity retention per cycle. The lifetime of the metal battery is determined using the capacity retention per cycle discerned from the anode-free cell. Related systems include a metal-based battery and an anode-free cell or a battery cell reconfigurable between a metal-based and an anode-free cell.

First claim

What is claimed is:

1. A method for analyzing operation of a metal-based battery cell, the method comprising:
providing a metal-based battery cell comprising a cathode, an anode, and an electrolyte between the cathode and the anode;
cycling the metal-based battery cell;
measuring, over the cycling, a rest voltage and Coulombic efficiency (CE) of the metal-based battery cell, without conducting additional testing, to provide rest voltage and CE profiles indicating, by trends indicated therein, at least one of an increased cell impedance failure mechanism, a loss of metal inventory failure mechanism, or an electrolyte depletion failure mechanism;
providing an anode-free battery cell comprising the cathode, a current collector, and the electrolyte between the cathode and the current collector, the anode-free battery cell not comprising the anode of the metal-based battery cell;
cycling, over fewer than 100 cycles, the anode-free battery cell;
measuring, over the fewer than 100 cycles, a discharge capacity of the anode-free battery cell;
fitting a discharge capacity curve to the measured discharge capacity to discern a capacity retention per cycle of the anode-free battery cell; and
based in part on the capacity retention per cycle discerned from the anode-free battery cell, and without measuring discharge capacities of the metal-based battery cell directly, predicting a cycle life of the metal-based battery cell.

2. The method of claim 1 , wherein providing the metal-based battery cell comprises providing the metal-based battery cell with the anode, the anode comprising one or more of lithium (Li), sodium (Na), zinc (Zn), potassium (K), palladium (Pd), iron (Fe), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), cobalt (Co), nickel (Ni), copper (Cu), silver (Ag), indium (In), aluminum (Al), gallium (Ga), tin (Sn), lead (Pb), bismuth (Bi), alloys thereof, or other combinations thereof.

3. The method of claim 1 , wherein providing the anode-free battery cell comprises providing the anode-free battery cell with the current collector, the current collector comprising at least one metal having a higher plating potential than a metal of the anode of the metal-based battery cell.

4. The method of claim 3 , wherein providing the anode-free battery cell with the current collector comprises providing a current collector comprising one or more of copper (Cu), steel, aluminum (Al), and carbon (C).

5. The method of claim 1 , wherein providing the metal-based battery cell and providing the anode-free battery cell comprise providing the electrolyte at a level of at least about 10 g of electrolyte per Amp-hour.

6. The method of claim 1 , wherein providing the metal-based battery cell and providing the anode-free battery cell comprise providing the electrolyte at a level of between about 3 g of electrolyte per Amp-hour and about 10 g of electrolyte per Amp-hour.

7. The method of claim 1 , wherein providing the metal-based battery cell and providing the anode-free battery cell comprise providing the electrolyte at a level of about 3 g of electrolyte per Amp-hour or fewer.

8. The method of claim 1 , wherein providing the anode-free battery cell comprises removing the anode from the metal-based battery cell and providing the current collector in place of the anode.

9. The method of claim 1 , wherein:
cycling, over the fewer than 100 cycles, the anode-free battery cell comprises cycling the anode-free battery cell over fewer than about 50 cycles; and
measuring, over the fewer than 100 cycles, the discharge capacity of the anode-free battery cell comprises measuring the discharge capacity over the fewer than about 50 cycles.

10. A system for diagnosing failure mechanisms and for predicting a cycle life of a metal-based battery cell, the system comprising:
a metal-based battery cell comprising a cathode, an anode, and an electrolyte between the cathode and the anode; and
an anode-free cell comprising another of the cathode, a current collector, and another of the electrolyte between the cathode and the current collector,
the anode comprising a metal, and
the current collector of the anode-free cell comprising another metal different from the metal of the anode of the metal-based battery cell.

11. The system of claim 10 , wherein the metal-based battery cell and the anode-free cell are configured as coin cells.

12. The system of claim 10 , wherein the cathode comprises a metal material comprising at least one of a metal oxide material, a metal phosphate material, a sulfur-based metal material, or an organic material.

13. The system of claim 10 , wherein the anode comprises lithium (Li), sodium (Na), zinc (Zn), potassium (K), palladium (Pd), iron (Fe), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), cobalt (Co), nickel (Ni), copper (Cu), silver (Ag), indium (In), aluminum (Al), gallium (Ga), tin (Sn), lead (Pb), bismuth (Bi), or combinations thereof.

14. The system of claim 10 , wherein the current collector comprises copper (Cu), steel, aluminum (Al), carbon (C), or combinations thereof.

15. The system of claim 10 , wherein:
the anode comprises lithium; and
the current collector comprises copper.

16. The system of claim 10 , wherein the anode-free cell, prior to operation, comprises no lithium in its current collector.

17. The system of claim 10 , wherein:
the metal-based battery cell further comprises a separator within the electrolyte; and
the anode-free cell further comprises another of the separator within the electrolyte.

18. The system of claim 10 , wherein:
the metal-based battery cell further comprises a solid electrolyte with target metal ion conduction; and
the anode-free cell further comprises another of the solid electrolyte with target metal ion conduction.

19. A system for diagnosing failure mechanisms and for predicting a cycle life of a metal-based battery cell, the system comprising:
at least one battery cell comprising:
a cathode;
an electrolyte; and
either an anode or a current collector, the anode being selectively removable to replace the anode with the current collector, and the current collector being selectively removable to replace the current collector with the anode.

20. The system of claim 19 , wherein the electrolyte comprises a solid state electrolyte or a gel state electrolyte.

Assignees

• Battelle Energy Alliance Llc

Inventors

• Li Bin
• Dufek Eric J
• Gao Ningshengjie

Classifications

• G01R31/392 Primary

  Determining battery ageing or deterioration, e.g. state of health · CPC title

• H01M10/488

  Cells or batteries combined with indicating means for external visualization of the condition, e.g. by change of colour or of light density · CPC title

• G01R31/378

  specially adapted for the type of battery or accumulator · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M10/052

  Li-accumulators · CPC title