Water vapor-permeable composite material

Patent metadata

Field	Value
Publication number	US-11739475-B2
Application number	US-202017753295-A
Country	US
Kind code	B2
Filing date	Aug 28, 2020
Priority date	Aug 30, 2019
Publication date	Aug 29, 2023
Grant date	Aug 29, 2023

Abstract

A composite material contains a nonwoven layer (i) which contains fibers formed from a first thermoplastic elastomer having meshes with a mesh size in the range from 10 to 100 μm, and a membrane layer (ii) which contains a second thermoplastic elastomer and having a layer thickness of less than 30 μm. The membrane is either pore-free (ii.1) or is porous and has pores with an average pore diameter of less than 2000 nm (ii.2). The membrane (ii) is at least partially in direct contact with the fibers of the nonwoven layer (i) and covers the mesh openings in the nonwoven layer (i) at least partially. The fibers of the first nonwoven layer (i) and the membrane (ii) in the contact area are at least partly joined to one another in an interlocking manner.

First claim

The invention claimed is:

1. A process for producing a composite material, comprising:
providing a nonwoven layer (i) comprising fibers formed from a first thermoplastic polyurethane and having meshes with a mesh size in the range from 10 to 100 μm, determined by scanning electron microscopy;
b) providing a membrane layer (ii) comprising a second thermoplastic polyurethane which is compatible with the first thermoplastic polyurethane of the nonwoven layer (i), wherein the membrane layer is porous and has pores with an average pore diameter of less than 2000 nm, determined by Hg porosimetry in accordance with DIN 66133;
c) applying the membrane layer (ii) to the nonwoven layer (i) and joining (i) and (ii) in an interlocking manner by cold welding;
to obtain a composite material;
wherein
cold welding according to (c) means that the fibers of the nonwoven layer (i) and the membrane (ii) in the contact area at least partly form an interlocking joint with one another, wherein on account of the presence of solvent firstly the nonwoven layer (i) and/or the membrane layer (ii) partly dissolve, and then the membrane layer (ii) hardens on the nonwoven layer (i) when the solvent is removed,
wherein (b) comprises:
b 1) providing a polymer solution comprising the second thermoplastic polyurethane, wherein the polymer solution further comprises at least one additive selected from the group consisting of polytetrahydrofuran and an ammonium compound, and wherein the polymer solution comprises the at least one additive in a weight-based mixing ratio of second thermoplastic polyurethane: additive of 1:10 to 10:1, and
b 2) creating a membrane layer (ii) from the polymer solution provided according to (b 1) by phase inversion.

2. The process for producing a composite material according to claim 1 , wherein the first TPU is identical to or different from the second TPU.

3. The process for producing a composite material according to claim 1 , wherein the membrane layer (ii) has a layer thickness of less than 30 μm, determined by scanning electron microscopy.

4. The process for producing a composite material according to claim 1 , wherein the polymer solution further comprises optionally water,
wherein (b 2) comprises:
(b 2 a) forming a film from the polymer solution;
(b 2 b) heating the film obtained according to (b 2 a) to a temperature of >60° C., to obtain the porous membrane layer having pores with an average pore diameter of less than 2000 nm, determined by Hg porosimetry in accordance with DIN 66133.

5. The process for producing a composite material according to claim 1 , wherein the fibers of the nonwoven layer (i) provided according to (a) have a diameter in the range from 0.01 to 100 μm, determined by scanning electron microscopy;
and/or
wherein the nonwoven layer (i) provided according to (a) has a mesh size in the range from 20 to 95 μm, determined by scanning electron microscopy.

6. The process for producing a composite material according to claim 4 , wherein in (b 2 b), the film obtained according to (b 2 a) is heated to a temperature in a range from >60° C. to 130° C.

7. The process for producing a composite material according to claim 4 , wherein the polymer solution comprises the at least one additive in the weight-based mixing ratio of second thermoplastic polyurethane:additive of 1:5 to 5:1.

8. The process for producing a composite material according to claim 5 , wherein the fibers of the nonwoven layer (i) provided according to (a) have a diameter in a range from 10 to 30 μm, determined by scanning electron microscopy.

9. The process for producing a composite material according to claim 5 , wherein the nonwoven layer (i) provided according to (a) has a mesh size in a range from 40 to 80 μm, determined by scanning electron microscopy.

10. The process for producing a composite material according to claim 1 , wherein the at least one additive is polytetrahydrofuran.

11. The process for producing a composite material according to claim 1 , wherein the at least one additive is an ammonium compound.

12. The process for producing a composite material according to claim 1 , wherein the first TPU is identical to the second TPU.

13. The process for producing a composite material according to claim 1 , wherein the first TPU is different from the second TPU.

14. The process for producing a composite material according to claim 1 , wherein the polymer solution further comprises water.

Assignees

• Basf Se

Inventors

• Prissok Frank
• Ahlers Juergen
• Doroodian Amir
• Harms Michael

Classifications

• B01D69/12 Primary

  Composite membranes; Ultra-thin membranes · CPC title

• B01D67/0009

  by phase separation, sol-gel transition, evaporation or solvent quenching · CPC title

• B01D69/1213

  Laminated layers · CPC title

• D06N3/0095 Primary

  by inversion technique; by transfer processes · CPC title

• B32B38/164

  Drying · CPC title