Apparatuses and methods for producing covetic materials using microwave reactors

Patent metadata

Field	Value
Publication number	US-11739409-B2
Application number	US-202117241852-A
Country	US
Kind code	B2
Filing date	Apr 27, 2021
Priority date	Aug 2, 2018
Publication date	Aug 29, 2023
Grant date	Aug 29, 2023

Abstract

Apparatuses and methods for producing covetic materials by exciting a hydrocarbon gas with pulse microwaves to form hydrocarbon radicals in a hot first region of a microwave reactor. Graphene nanoplatelets are formed by the nucleation, growth and assembly of the hydrocarbon radicals, and contact a metal melt introduced downstream of the hot region to produce a mixture of molten metal and graphene nanoplatelets which assemble in-flight to form covetic materials. Graphene planes are infused in the metal matrix to achieve carbon loadings of at least 60%.

First claim

What is claimed is:

1. An apparatus for producing covetic materials comprising:
a microwave energy source configured to generate pulsed microwave energy;
a reactor disposed in communication with the microwave energy source, the reactor comprising:
a first region configured to receive a hydrocarbon gas fed through a first inlet port and the microwave energy to dissociate the hydrocarbon gas into carbon and hydrogen species;
a second inlet port disposed downstream of the first region and configured to feed a metal melt into the reactor; and
a second region disposed downstream of the first region and in fluid communication with the second inlet port, the second region configured to form carbon particles from the dissociated carbon species and to produce a mixture of molten metal and carbon particles; and

an exit port configured to output the mixture of molten metal and carbon particles and form covetic materials as the mixture cools leaving the exit port.

2. The apparatus of claim 1 , wherein the metal melt comprises one or more of aluminum, copper, or silver.

3. The apparatus of claim 1 , wherein a temperature of the first region is greater than a temperature of the second region.

4. The apparatus of claim 1 , further comprising a melting apparatus to form the metal melt, wherein the melting apparatus comprises a tungsten inert gas (TIG) welder power supply and control unit configured to melt metal powder in a plasma of inert gas.

5. The apparatus of claim 1 , further comprising one or more of a cyclone apparatus, a mechanical tumbler agitator, or a fluidized bed apparatus disposed downstream of the exit port.

6. The apparatus of claim 5 , wherein the one or more of the cyclone apparatus, the mechanical tumbler agitator, or the fluidized bed apparatus is configured to cool the mixture of molten metal and carbon particles.

7. The apparatus of claim 1 , wherein the metal melt comprises one or more of a molten metal, a molten metal composite, a molten ceramic-metal, or a metal matrix.

8. The apparatus of claim 1 , wherein the metal melt comprises one or more of fully-melted metal or partially melted metal.

9. The apparatus of claim 1 , wherein the metal melt comprises metal droplets.

10. The apparatus of claim 1 , wherein the covetic materials comprise sub-micron size metal particles and few layer graphene (FLG).

11. The apparatus of claim 1 , wherein the covetic materials comprise graphene planes disposed in the metal matrix.

12. The apparatus of claim 1 , wherein a pressure inside the reactor is at least 20 Torr.

Assignees

• Lyten Inc

Inventors

• Stowell Michael W
• Lanning Bruce
• Williams Peter Todd
• Cook Daniel

Classifications

• H05H1/46

  using applied electromagnetic fields, e.g. high frequency or microwave energy (H05H1/26 takes precedence) · CPC title

• H05H1/26

  Plasma torches · CPC title

• C23C4/067 Primary

  containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic · CPC title

• H05H1/30

  using applied electromagnetic fields, e.g. high frequency or microwave energy (H05H1/28 takes precedence) · CPC title

• H05H1/461

  Microwave discharges · CPC title