Process for the production of fluorinated cyclobutane
US-2017233316-A1 · Aug 17, 2017 · US
US11739243B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11739243-B2 |
| Application number | US-202117381572-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 21, 2021 |
| Priority date | Dec 21, 2018 |
| Publication date | Aug 29, 2023 |
| Grant date | Aug 29, 2023 |
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The present disclosure provides minimum-boiling, homogeneous azeotropic and azeotrope-like compositions of 1,2,2-trifluoro-1-trifluoromethylcyclobutane (“TFMCB”) with each of ethanol, n-pentane, cyclopentane, trans-1,2-dichloroethylene, and perfluoro(2-methyl-3-pentanone).
Opening claim text (preview).
The invention claimed is: 1. An azeotrope or azeotrope-like composition consisting essentially of effective amounts of 1,2,2-trifluoro-1-trifluoromethylcyclobutane and perfluoro(2-methyl-3-pentanone), wherein the azeotrope or azeotrope-like composition has a boiling point of about 48.70° C.±0.01° C. at a pressure of about 14.7 psia±0.2 psia. 2. The azeotrope or azeotrope-like composition of claim 1 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 1 wt. % to about 20 wt. % 1,2,2-trifluoro-1-trifluoromethylcyclobutane and from about 80 wt. % to about 99 wt. % perfluoro(2-methyl-3-pentanone). 3. The azeotrope or azeotrope-like composition of claim 1 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 5 wt. % to about 15 wt. % 1,2,2-trifluoro-1-trifluoromethylcyclobutane and from about 85 wt. % to about 95 wt. % perfluoro(2-methyl-3-pentanone). 4. The azeotrope or azeotrope-like composition of claim 1 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 8 wt. % to about 12 wt. % 1,2,2-trifluoro-1-trifluoromethylcyclobutane and from about 88 wt. % to about 92 wt. % perfluoro(2-methyl-3-pentanone). 5. The azeotrope or azeotrope-like composition of claim 1 , wherein the azeotrope or azeotrope-like composition consists essentially of about 10 wt. % 1,2,2-trifluoro-1-trifluoromethylcyclobutane and about 90 wt. % perfluoro(2-methyl-3-pentanone). 6. An azeotrope or azeotrope-like composition consisting of 1,2,2-trifluoro-1-trifluoromethylcyclobutane and perfluoro(2-methyl-3-pentanone), wherein the azeotrope or azeotrope-like composition has a boiling point of about 48.70° C.±0.01° C. at a pressure of about 14.7 psia±0.2 psia. 7. The azeotrope or azeotrope-like composition of claim 1 , wherein the azeotrope or azeotrope-like composition consists of from about 1 wt. % to about 20 wt. % 1,2,2-trifluoro-1-trifluoromethylcyclobutane and from about 80 wt. % to about 99 wt. % perfluoro(2-methyl-3-pentanone). 8. The azeotrope or azeotrope-like composition of claim 1 , wherein the azeotrope or azeotrope-like composition consists of from about 5 wt. % to about 15 wt. % 1,2,2-trifluoro-1-trifluoromethylcyclobutane and from about 85 wt. % to about 95 wt. % perfluoro(2-methyl-3-pentanone). 9. The azeotrope or azeotrope-like composition of claim 1 , wherein the azeotrope or azeotrope-like composition consists of from about 8 wt. % to about 12 wt. % 1,2,2-trifluoro-1-trifluoromethylcyclobutane and from about 88 wt. % to about 92 wt. % perfluoro(2-methyl-3-pentanone). 10. The azeotrope or azeotrope-like composition of claim 1 , wherein the azeotrope or azeotrope-like composition consists of about 10 wt. % 1,2,2-trifluoro-1-trifluoromethylcyclobutane and about 90 wt. % perfluoro(2-methyl-3-pentanone).
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