Lignin-based polymers with enhanced melt extrusion ability

Patent metadata

Field	Value
Publication number	US-11739218-B2
Application number	US-202117487061-A
Country	US
Kind code	B2
Filing date	Sep 28, 2021
Priority date	Jan 25, 2018
Publication date	Aug 29, 2023
Grant date	Aug 29, 2023

Abstract

A solid polymer blend material comprising: (i) a lignin-acrylonitrile component containing a homogeneous blend of a lignin component and an acrylonitrile-containing rubber component; and (ii) a styrene-containing thermoplastic component that is non-elastomeric; wherein components (i) and (ii) are homogeneously dispersed in the polymer blend material. Methods for producing the blend material are also described. Methods for producing objects made of the blend material by melt extrusion are also described, comprising: (a) melt blending components (i) and (ii) to form a polymer blend in which components (i) and (ii) are homogeneously blended, wherein the polymer blend exhibits a melt viscosity of no more than 2000 Pa·s at a shear rate of 100-1000 s −1 and when heated to a temperature of no more than 240° C.; and (b) forming an object made of said polymer blend material.

First claim

What is claimed is:

1. A solid polymer blend material comprising:
(i) a lignin-acrylonitrile component containing a homogeneous blend of a lignin component and an acrylonitrile-containing rubber component; and
(ii) a high impact polystyrene component that is non-elastomeric;
wherein components (i) and (ii) are homogeneously dispersed in the solid polymer blend material.

2. The polymer blend material of claim 1 , wherein the lignin is present in an amount of 10-60 wt % by weight of the polymer blend material.

3. The polymer blend material of claim 1 , wherein the lignin is present in an amount of 20-40 wt % by weight of the polymer blend material.

4. The polymer blend material of claim 1 , wherein said high impact polystyrene component is present in an amount of 10-60 wt % by weight of the polymer blend material.

5. The polymer blend material of claim 1 , wherein said acrylonitrile-containing rubber component is nitrile butadiene rubber.

6. A method of producing an object made of a lignin-containing polymer blend material by melt extrusion, the method comprising:
(a) melt blending the following components: (i) a lignin-acrylonitrile component containing a homogeneous blend of a lignin component and an acrylonitrile-containing rubber component;
and (ii) a high impact polystyrene component that is non-elastomeric, to form a melt of a polymer blend in which components (i) and (ii) are homogeneously blended, wherein the polymer blend exhibits a melt viscosity of no more than 2000 Pa·s at a shear rate of 100-1000 s −1 and when heated to a temperature of no more than 240° C.; and
(b) forming an object made of said polymer blend material in solid form, wherein the polymer blend in solid form comprises: (i) lignin-acrylonitrile component; and (ii) said high impact polystyrene component that is non-elastomeric; wherein components (i) and (ii) are homogeneously dispersed in the solid polymer blend material.

7. The method of claim 6 , wherein step (b) employs an extrusion process to form said object.

8. The method of claim 7 , wherein said extrusion process occurs in a heating chamber containing a nozzle, and pressure is induced on the melt of the polymer blend material while the polymer blend material is in said heating chamber to adjust the flow rate of the melt through the nozzle to result in the melt having a melt viscosity of no more than 2000 Pa·s.

9. The method of claim 8 , wherein said heating chamber is connected to a piston that induces pressure on the melt of the solid polymer blend material as the piston pushes the melt through the nozzle.

10. The method of claim 8 , wherein pressure is induced on the melt of the polymer blend material by exerting pressure on a solid filament of the polymer blend material as the solid filament is being fed into said heating chamber, wherein the pressure pushes the solid filament into the heating chamber at a desired flow rate.

11. The method of claim 7 , wherein said extrusion process occurs in an additive manufacturing process.

12. The method of claim 6 , wherein step (b) employs a casting process in which the melt is casted in a mold.

13. The method of claim 12 , wherein said casting process is an injection molding process.

14. The method of claim 13 , wherein said injection molding process is a resin transfer molding process.

15. The method of claim 12 , wherein said casting process is a compression molding process.

16. The method of claim 6 , wherein the lignin is present in an amount of 10-60 wt % by weight of the solid polymer blend material.

17. The method of claim 6 , wherein the lignin is present in an amount of 20-40 wt % by weight of the solid polymer blend material.

18. The method of claim 6 , wherein said high impact polystyrene component is present in an amount of 10-60 wt % by weight of the polymer blend material.

19. The method of claim 6 , wherein said acrylonitrile-containing rubber component is nitrile butadiene rubber.

20. The method of claim 1 , wherein said acrylonitrile-containing rubber component is present in an amount of 10-30 wt % of the polymer blend material.

Assignees

• Ut Battelle Llc

Inventors

• Naskar Amit K
• Nguyen Ngoc A

Classifications

• C08L97/005 Primary

  Lignin · CPC title

• B29C64/106

  using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material · CPC title

• B29C64/118

  using filamentary material being melted, e.g. fused deposition modelling [FDM] · CPC title

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• C08H6/00

  Macromolecular compounds derived from lignin, e.g. tannins, humic acids · CPC title