Adhesive for polyolefin and multilayered structure

Patent metadata

Field	Value
Publication number	US-11738538-B2
Application number	US-202117365828-A
Country	US
Kind code	B2
Filing date	Jul 1, 2021
Priority date	Jul 25, 2016
Publication date	Aug 29, 2023
Grant date	Aug 29, 2023

Abstract

A multilayered structure that includes an olefin resin layer and a gas-barrier layer. An adhesive layer is provided adjoining the olefin resin layer and the gas-barrier layer, the adhesive layer consisting of an acid-modified olefin resin. The acid-modified olefin resin has methyl branches in a number of 10 to 200 per 1000 carbon atoms on a main chain thereof, and has not more than 50 branches that are larger than the methyl groups.

First claim

What is claimed is:

1. A multilayered structure that includes an olefin resin layer and a gas-barrier layer, wherein:
an adhesive layer is provided adjoining said olefin resin layer and said gas-barrier layer;
said adhesive layer consists of an acid-modified olefin resin; and
said acid-modified olefin resin has methyl branches in a number of 10 to 200 per 1000 carbon atoms on a main chain thereof, and has not more than 50 branches per 1000 carbon atoms of the main chain that are larger than the methyl groups.

2. The multilayered structure according to claim 1 ,
wherein said acid-modified olefin resin has methyl branches in a number of not less than 20 but not more than 200 per 1000 carbon atoms on the main chain thereof.

3. The multilayered structure according to claim 1 ,
wherein said olefin resin layer is a propylene resin layer or an ethylene resin layer.

4. The multilayered structure according to claim 1 ,
wherein said gas-barrier layer is formed of an ethylene-vinyl alcohol copolymer.

5. The multilayered structure according to claim 1 ,
wherein the multilayered structure is a directly blow-formed container.

6. A multilayered structure that includes a propylene resin layer and an ethylene resin layer, wherein:
a gas-barrier layer is provided as an intermediate layer between said propylene resin layer and said ethylene resin layer;
an adhesive layer is provided between said propylene resin layer and said gas-barrier layer as well as between said gas-barrier layer and said ethylene resin layer, respectively;
said adhesive layers consisting of an acid-modified olefin resin; and
the number of the methyl branches possessed by said acid-modified olefin resin is 10 to 200 per 1000 carbon atoms of the main chain, and the number of the branches larger than the methyl groups is not more than 50 per 1000 carbon atoms of the main chain.

7. The multilayered structure according to claim 6 ,
wherein said gas-barrier layer is formed of an ethylene-vinyl alcohol copolymer.

8. The multilayered structure according to claim 6 ,
wherein the multilayered structure is a directly blow-formed container.

Assignees

• Toyo Seikan Group Holdings Ltd

Inventors

• Seito Shinya
• Ishihara Takayuki
• Akutsu Yosuke

Classifications

• B32B7/12 Primary

  using interposed adhesives or interposed materials with bonding properties · CPC title

• B32B27/00

  Layered products comprising {a layer of} synthetic resin {(fibrous or filamentary layer made of a synthetic resin B32B5/02; particulate layer made of a synthetic resin B32B5/16; foamed layer made of a synthetic resin B32B5/18)} · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• B32B33/00

  Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class · CPC title

• B65D65/40

  Applications of laminates for particular packaging purposes {(B65D1/0215, B65D1/28, B65D3/22, B65D5/0281, B65D5/563, B65D9/30, B65D29/02, B65D31/02, B65D75/26, B65D77/2024, B65D81/1275, B65D81/3811, B65D81/3823, B65D81/3834, B65D81/3846, B65D81/3858, B65D81/3874, B65D81/3886, B65D81/3897 take precedence; laminates per se or laminated packages characterised by the composition or)} · CPC title