Lubricating oil composition for internal combustion engine

Patent metadata

Field	Value
Publication number	US-11732207-B2
Application number	US-202117406599-A
Country	US
Kind code	B2
Filing date	Aug 19, 2021
Priority date	Aug 31, 2020
Publication date	Aug 22, 2023
Grant date	Aug 22, 2023

Abstract

A lubricating oil composition for an internal combustion engine has a HTHS viscosity at 150° C. of 2.55-2.84 mPa·s and includes: (A) a lubricating base oil including (a) mineral base oil(s) and/or (a) synthetic base oil(s), and having a kinematic viscosity at 100° C. of 3.8-4.6 mm2/s; (B) 1000-2000 mass ppm, in terms of metal content, of a metallic detergent including (a) metal salicylate detergent(s), and delivering ≥10 mmol/kg of total salicylate soap base per kilogram of the composition; (C) 1.0 to 4.0 mass % of a comb-shaped poly(meth)acrylate having a Mw of 350,000-1,000,000 and a PDI of ≤4.0; and (D) 100-1000 mass ppm, in terms of nitrogen, of a succinimide dispersant including (i) (a) non-modified succinimide dispersant(s) and/or (ii) (a) boric acid-modified succinimide dispersant(s), wherein the (i) and the (ii), in total, deliver ≥70 mass % of total nitrogen content of the component (D).

First claim

I claim:

1. A lubricating oil composition for an internal combustion engine, the composition consisting of:
(A) a lubricating base oil comprising at least one mineral base oil or at least one synthetic base oil or any combination thereof, and having a kinematic viscosity at 100° C. of 3.8 to 4.6 mm 2 /s,
(B) a metallic detergent comprising at least one metal salicylate detergent, wherein the component (B) is present in an amount of 1000 to 2000 mass ppm in terms of metal content on the basis of the total mass of the composition, and wherein the component (B) is present in an amount of no less than 10 mmol/kg in terms of total molar amount of any salicylate soap base per kilogram of the composition, and wherein the component (B) is overbased with at least one basic metal salt, wherein the at least one basic metal salt overbasing the component (B) consists of:
at least one first basic metal salt selected from the group consisting of at least one metal carbonate, at least one alkaline earth metal borate, and any combination thereof; and
optionally at least one base selected from the group consisting of at least one alkali metal hydroxide, at least one alkaline earth metal hydroxide, at least one alkali metal oxide, at least one alkaline earth metal oxide, and any combination thereof; and

at least one additive other than any metallic detergent, the at least one additive comprising:
(C) at least one comb-shaped poly(meth)acrylate in an amount of 1.0 to 4.0 mass % in terms of resin content on the basis of the total mass of the composition, the comb-shaped poly(meth)acrylate having a weight average molecular weight of 350,000 to 1,000,000 and a polydispersity index of no more than 4.0; and
(D) a succinimide dispersant in an amount of 100 to 1000 mass ppm in terms of nitrogen on the basis of the total mass of the composition, the component (D) comprising at least one non-modified succinimide dispersant or at least one boric acid-modified succinimide dispersant or any combination thereof, wherein a total nitrogen content derived from the non-modified succinimide dispersant and the boric acid-modified succinimide dispersant is no less than 70 mass % of a total nitrogen content of the component (D),
wherein the composition has HTHS viscosity at 150° C. of 2.55 to 2.84 mPa·s.

2. The lubricating oil composition according to claim 1 ,
wherein the (A) lubricating base oil is at least one Group III base oil of API base stock categories, or at least one Group IV base oil of API base stock categories, or any combination thereof.

3. The lubricating oil composition according to claim 1 ,
wherein the component (B) is present in an amount of no less than 15 mmol/kg in terms of total molar amount of any soap base per kilogram of the composition.

4. The lubricating oil composition according to claim 1 ,
wherein a total salicylate soap base of the component (B) is no less than 50 mol % of a total soap base of the component (B).

5. The lubricating oil composition according to claim 1 ,
wherein the component (C) has a weight average molecular weight of greater than 400,000 and no more than 1,000,000.

6. The lubricating oil composition according to claim 1 ,
wherein a ratio B/N of a total boron content B of the component (D) to a total nitrogen content N of the component (D) is 0 to 0.60.

7. The lubricating oil composition according to claim 1 ,
wherein the component (D) is a condensation reaction product of an alkyl- or alkenyl-succinic acid or anhydride thereof with a polyamine, or a modified product of the condensation reaction product, or any combination thereof, wherein the alkyl- or alkenyl-succinic acid has an alkyl or alkenyl group having 40 to 400 carbon atoms.

8. A method for lubricating an internal combustion engine of a hybrid electric vehicle, comprising
supplying the lubricating oil composition of claim 1 to an internal combustion engine of a hybrid electric vehicle.

9. The lubricating oil composition according to claim 1 , wherein the at least one basic metal salt overbasing the component (B) consists of:
at least one first basic metal salt selected from the group consisting of at least one alkali metal carbonate, at least one alkaline earth metal carbonate, and any combination thereof; and
optionally at least one base selected from the group consisting of at least one alkali metal hydroxide, at least one alkaline earth metal hydroxide, at least one alkali metal oxide, at least one alkaline earth metal oxide, and any combination thereof.

10. The lubricating oil composition according to claim 1 , wherein the at least one basic metal salt overbasing the component (B) consists of:
at least one first basic metal salt selected from the group consisting of at least one alkaline earth metal carbonate, at least one alkaline earth metal borate, and any combination thereof; and
optionally at least one base selected from the group consisting of at least one alkaline earth metal hydroxide, at least one alkaline earth metal oxide, and any combination thereof.

11. The lubricating oil composition according to claim 1 , wherein the at least one basic metal salt overbasing the component (B) consists of:
at least one alkaline earth metal carbonate; and
optionally at least one base selected from the group consisting of at least one alkaline earth metal hydroxide, at least one alkaline earth metal oxide, and any combination thereof.

12. The lubricating oil composition according to claim 1 ,
wherein the component (B) consists of at least one overbased product of at least one organic acid alkaline earth metal salt.

13. The lubricating oil composition according to claim 9 ,
wherein the component (B) consists of at least one overbased product of at least one organic acid alkaline earth metal salt.

14. The lubricating oil composition according to claim 10 ,
wherein the component (B) consists of at least one overbased product of at least one organic acid alkaline earth metal salt.

15. The lubricating oil composition according to claim 11 ,
wherein the component (B) consists of at least one overbased product of at least one organic acid alkaline earth metal salt.

Assignees

• Eneos Corp

Inventors

• Nakazawa Hiroki

Classifications

• C10M129/50 Primary

  monocarboxylic · CPC title

• C10M101/00

  Lubricating compositions characterised by the base-material being a mineral or fatty oil (containing more than 10% water C10M173/00) · CPC title

• C10M107/02

  Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation · CPC title

• C10M129/54

  containing hydroxy groups · CPC title

• C10M145/14

  Acrylate; Methacrylate · CPC title