Process for enhancement of RON of FCC gasoline with simultaneous reduction in benzene

Patent metadata

Field	Value
Publication number	US-11732200-B2
Application number	US-202217656445-A
Country	US
Kind code	B2
Filing date	Mar 25, 2022
Priority date	Mar 25, 2021
Publication date	Aug 22, 2023
Grant date	Aug 22, 2023

Abstract

The present invention relates to an integrated process for increasing the research octane number (RON) of FCC gasoline with simultaneous reduction in benzene content. In this process, benzene rich gasoline fraction is reacted with light olefin rich gaseous streams like FCC off gas/dry gas, coker off gas to produce alkyl aromatics using FCC catalyst system containing ZSM-5 zeolite. The catalyst is continuously drawn from the FCC regenerator by suitably placing the alkylation reactor in communication with the FCC regenerator. The product stream of the alkylation reactor is routed to main fractionator for separation of off gas and benzene lean gasoline. This integrated process not only improves the octane number of gasoline but also lowers the gasoline benzene content. Further the integrated alkylation reactor system acts as a heat sink lowering the FCC regenerator temperature and enables the FCC unit to process high CCR feeds.

First claim

We claim:

1. A process for increasing a research octane number (RON) and simultaneously reducing benzene content of a feed, the process comprising:
integrating an alkylation reactor (A) with a fluid catalytic cracking (FCC) regenerator (B), wherein the integrating comprises:
continuously withdrawing a hot regenerated catalyst from the FCC regenerator, wherein the FCC regenerator is configured to combust coke on a catalyst to generate the hot regenerated catalyst;
contacting the hot regenerated catalyst with a stream comprising a light olefin and a stream having 10 wt % benzene to produce alkyl aromatics in the alkylation reactor; and
sending back a spent catalyst to the FCC regenerator, wherein the catalyst comprises an FCC catalyst and 5-50 wt % of ZSM-5 additive.

2. The process as claimed in claim 1 , wherein the FCC catalyst comprises Y-type Zeolite, an active alumina material, a binder material, and an inert filler, wherein the binder material comprises silica, alumina or a combination thereof, and wherein the inert filler comprises kaolin.

3. The process as claimed in claim 1 , wherein the stream having benzene has a temperature in a range of 40-60° C., and wherein the stream comprising the light olefin has a temperature in a range of 30-50º.

4. The process as claimed in claim 1 , wherein the stream comprising the light olefin is selected from the group consisting of a dilute ethylene stream, an FCC off gas/a dry gas, and a coker off gas.

5. The process as claimed in claim 1 , wherein benzene content is reduced by 30-50 weight percent relative to the stream having benzene.

6. The process as claimed in claim 1 , wherein the RON of the feed is increased by 2-10 units.

7. The process as claimed in claim 1 , wherein the alkyl aromatics comprise alkyl benzene.

8. A refinery system for increasing a research octane number (RON) and for simultaneously reducing benzene content of a feed, the system comprising:
an FCC riser (D), wherein the FCC riser is configured to contact hydrocarbon streams with a hot regenerated catalyst, and cracking the hydrocarbon streams into lighter molecular weight hydrocarbon products;
an FCC Regenerator (B) configured to combust coke on a catalyst to produce a hot regenerated catalyst and a flue gas, and to add heat to the catalyst, providing energy to offset endothermic cracking reactions occurring in the FCC riser, wherein the catalyst comprises an FCC catalyst and 5-50 wt % of ZSM-5 additive;
a Main Fractionator (E) configured to fractionate gaseous vapor into cuts comprising H2, C1-C4, and light naphtha, and liquid products comprising heavy naphtha, light cycle oils, heavy cycle oils and slurry oils;
a Gascon Section (F) configured to separate the light naphtha and the gaseous vapor into a dry gas stream and an LPG stream;
an Amine Absorber Section (G) configured to remove hydrogen sulfide from the dry gas stream;
a Light Naphtha Splitter (H) configured to separate the light naphtha into three cuts, wherein the three cuts comprise a light cut, a medium cut and a heavy cut;
a Benzene rich Splitter (I) configured to fractionate the medium cut into a top cut and a bottom cut, and to concentrate benzene into a separate stream;
an Alkylation reactor/unit (A) integrated with the FCC regenerator (B) and is configured to contact the hot regenerated catalyst with the dry gas stream and a benzene stream to produce alkyl aromatics, and to continuously withdraw the hot regenerated catalyst from the FCC regenerator and send back to the FCC regenerator after alkylation reaction.

9. The system as claimed in claim 8 , wherein a temperature of the alkylation reactor is in a range of 300-400° C.

10. The system as claimed in claim 8 , wherein the alkylation reactor is configured to perform as a catalyst cooler or a heat sink.

Assignees

• Indian Oil Corp Ltd

Inventors

• Bhutia Sandup Tshering
• Nath Vineeth Venu
• Mahant Arvind Wamandas
• Gupta Bandaru Hari Venkata Prasad
• Thakur Ram Mohan
• Sau Madhusudan
• Kapur Gurpreet Singh
• RAMAKUMAR Sankara Sri Venkata

Classifications

• C10G35/065 Primary

  containing crystalline zeolitic molecular sieves, other than aluminosilicates · CPC title

• C07C2/66

  Catalytic processes · CPC title

• C10G35/095

  containing crystalline alumino-silicates, e.g. molecular sieves {(C10G35/065 takes precedence)} · CPC title

• C10G2300/305

  Octane number, e.g. motor octane number [MON], research octane number [RON] · CPC title

• C10G29/205 Primary

  by reaction with hydrocarbons added to the hydrocarbon oil · CPC title