Cable component including a halogen-free flame retardant composition

Patent metadata

Field	Value
Publication number	US-11732195-B2
Application number	US-202015930566-A
Country	US
Kind code	B2
Filing date	May 13, 2020
Priority date	Nov 28, 2017
Publication date	Aug 22, 2023
Grant date	Aug 22, 2023

Abstract

Embodiments of a flame retardant composition are provided. The composition includes from 55% to 85% by weight of a blended matrix and from 15% to 45% by weight of a flame retardant package distributed within the blended matrix. The blended matrix includes a polyolefin component and a nitrogen-containing polymer component. In particular, the nitrogen-containing polymer component has a melting temperature of less than 240° C. The flame retardant package includes an acid source, a carbon source, a polyoxometalate ionic liquid, and a synergist. The flame retardant composition can be utilized in cables, such as fiber optic cables.

First claim

What is claimed is:

1. A flame retardant composition, comprising:
55% to 85% by weight of a blended matrix, the blended matrix comprising:
a polyolefin component; and
a nitrogen-containing polymer component, the nitrogen-containing polymer component having a melting temperature of less than 240° C.; and

15% to 45% by weight of a flame retardant package distributed within the blended matrix, the flame retardant package comprising:
an acid source;
a carbon source;
a polyoxometalate ionic liquid (PIL); and
a synergist;
wherein the PIL comprises a further acid source and a further carbon source.

2. The flame retardant composition of claim 1 , wherein the nitrogen-containing polymer component includes a polyamide.

3. The flame retardant composition of claim 2 , wherein the polyamide is selected from a group consisting of polyamide 6, polyamide 6/6, polyamide 6/12, polyamide 11, and combinations thereof.

4. The flame retardant composition of claim 1 , wherein the nitrogen-containing polymer component includes a thermoplastic polyurethane.

5. The flame retardant composition of claim 1 , wherein the polyolefin component is selected from a group consisting of an ethylene-vinyl acetate copolymer, an ethylene-acrylate copolymer, a low density polyethylene, a medium density polyethylene, a high density polyethylene, a linear low density polyethylene, a very low density polyethylene, a polyolefin elastomer copolymer, a propylene homopolymer, a propylene copolymer, an impact modified polypropylene, an ethylene/alpha-olefin copolymer, a butene-branched copolymer, or an octene-branched copolymers, and combinations thereof.

6. The flame retardant composition of claim 1 , wherein the blended matrix further comprises a compatibilizer component.

7. The flame retardant composition of claim 6 , wherein the compatibilizer comprises up to 3% by weight of maleic anhydride.

8. The flame retardant composition of claim 1 , wherein the blended matrix comprises:
the polyolefin component in an amount of from 30% to 80% by weight of the total weight of the flame retardant composition;
the nitrogen-containing polymer component in an amount of from 5% to 25% by weight of the total weight of the flame retardant composition; and
a compatibilizer in an amount of from 0% to 5% by weight of the total weight of the flame retardant composition;
wherein the polyolefin component, the nitrogen-containing polymer component, and the compatibilizer together comprise 55% to 85% of the total weight of the flame retardant composition.

9. The flame retardant composition of claim 1 , wherein the PIL is formed from an ionic liquid selected from a group consisting of 1-ethyl-3-methyl-imidazolium ethyl sulfate, 1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-hexyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, 1-ethyl-3-methylimidazolium trifluoromethanesulfonate, scandium(III) trifluoromethanesulfonate, praseodymium (III) trifluoromethanesulfonate, 1,3-dialkyl-1,2,3-triazolium hexafluorophosphate, 1,3-dialkyl-1,2,3-triazolium bis(trifluoromethanesulfonyl)imide, 1,2,4-trimethylpyrazolium methyl sulfate, and combinations thereof.

10. The flame retardant composition of claim 1 , wherein the PIL is formed from a compound selected from a group consisting of a pentaerythritol/polyphosphate compound, an acid-sugar based compound, a cyclodextrin derivative containing at least one acid group, an acid-polyol, an acid-aminoacid, an organo-base-acid, and combinations thereof.

11. The flame retardant composition of claim 1 , wherein the flame retardant composition has a limiting oxygen index of at least 30% according to ISO 4589.

12. The flame retardant composition of claim 1 , wherein the PIL comprises a polyoxometalate selected from a group consisting of [PW 12 O 40 ] 3− , [PMo 12 O 40 ] 3− , [SiW 12 O 40 ] 4− , [SiMo 12 O 40 ] 4− , [BW 12 O 40 ] 3− , [BMo 12 O 40 ] 3− , [AsW 12 O 40 ] 5− , [AsMo 12 O 40 ] 5− , [GeW 12 O 40 ] 4− , [GeMo 12 O 40 ] 4− , [PMo 9 V 3 O 40 ] 5− , [PMo 10 V 2 O 40 ] 5− , [PMo 11 VO 40 ] 4− , [P 2 W 18 O 62 ] 6− , [P 2 Mo 18 O 62 ] 6− , [As 2 W 18 O 62 ] 6− , [As 2 Mo 18 O 62 ] 6− , [W 6 O 19 ] 2− , [Mo 6 O 19 ] 2− , [V 6 O 19 ] 8− , [Nb 6 O 19 ] 8− , [PW 12 O 40 ] 3− , [W 2 O 11 ] 2− , and combinations thereof.

13. The flame retardant composition of claim 1 , wherein the synergist is selected from a group consisting of a zeolite, a clay, a bentonite, a zinc borate, and combinations thereof.

14. The flame retardant composition of claim 1 , wherein the flame retardant package comprises:
the carbon source and the acid source together in an amount of from 15% to 40% by weight of the total weight of the flame retardant composition;
the PIL and the synergist together in an amount of from 0.2% to 5% by weight of the total weight of the flame retardant composition; and
wherein the carbon source, the acid source, the PIL, and the synergist together comprise from 15% to 45% by weight of the total weigh of the flame retardant composition.

15. A cable comprising:
at least one conductor;
a jacket that surrounds the at least conductor;
wherein the jacket comprises a flame retardant package distributed within a blended matrix;
wherein the blended matrix comprises:
a polyolefin component;
a nitrogen-containing polymer component having a melting temperature below 240° C.; and
a compatibilizer; and

wherein the flame retardant package comprises:
an acid source;
a carbon source;
a polyoxometalate ionic liquid (PIL); and
a synergist carrier;
wherein the PIL comprises a further acid source and a further carbon source.

16. The cable of claim 15 , wherein the at least one conductor comprises an optical fiber.

17. The cable of claim 16 , wherein the jacket is a buffer tube of the optical fiber.

18. The cable of claim 15 , wherein the nitrogen-containing polymer component is selected from a group consisting of polyamide 6, polyamide 12, polyamide 6/12, polyamide 11, a thermoplastic polyurethane, and combinations thereof.

19. The cable of claim 15 , wherein the PIL is formed from a compound selected from a group consisting of a pentaerythritol/polyphosphate compound, an acid-sugar based compound, a cyclodextrin derivative containing at least one acid group, an acid-polyol, an acid-aminoacid, an organo-base-acid, and combinations thereof.

20. The flame retardant composition of claim 1 , wherein the further acid source comprises an element selected from phosphorous, boron, sulfur, and combinations thereof.

Assignees

• Corning Res & Dev Corp

Inventors

• Cheng Xiaole
• Fewkes Edward John
• Gallo Emanuela
• Jiang Dayue
• Zaytseva Natalya Vyacheslavovna

Classifications

• C09K21/12 Primary

  containing phosphorus · CPC title

• C08L23/12 Primary

  Polypropene · CPC title

• G02B6/4436

  Heat resistant · CPC title

• H01B3/302

  Polyurethanes or polythiourethanes; Polyurea or polythiourea · CPC title

• H01B3/305

  Polyamides or polyesteramides · CPC title