Non-curable thermally conductive pituitous silicone material

Patent metadata

Field	Value
Publication number	US-11732175-B2
Application number	US-202018005678-A
Country	US
Kind code	B2
Filing date	Oct 28, 2020
Priority date	Oct 28, 2020
Publication date	Aug 22, 2023
Grant date	Aug 22, 2023

Abstract

A non-curable thermally conductive material contains: (a) a matrix material containing: (i) 90 to 98 wt % of a non-functional non-crosslinked organosiloxane fluid having a dynamic viscosity of 50 to 350 centiStokes; and (ii) 2 to less than 10 wt % of a crosslinked hydrosilylation reaction product of an alkenyl terminated polydiorganosiloxane having a degree of polymerization greater than 300 and an organohydrogensiloxane crosslinker with 2 or more SiH groups per molecule where the molar ratio of SiH groups to alkenyl groups is 0.5 to 2.0; (b) greater than 80 wt % to less than 95 wt % thermally conductive filler dispersed throughout the matrix material; and (c) treating agents selected from alkyltrialkoxy silanes where the alkyl contains one to 14 carbon atoms and monotrialkoxy terminated diorganopolysiloxanes having a degree of polymerization of 20 to 110 and the alkoxy groups each contain one to 12 carbon atoms dispersed in the matrix material.

First claim

The invention claimed is:

1. A non-curable thermally conductive material comprising:
(a) a matrix material comprising:
(i) greater than 90 weight-percent and at the same time 98 weight percent or less based on matrix material weight of a non-functional non-crosslinked organosiloxane fluid having a dynamic viscosity in a range of 50 to 350 centiStokes; and
(ii) 2 to less than 10 weight-percent based on matrix material weight of a crosslinked hydrosilylation reaction product of an alkenyl terminated polydiorganosiloxane having a degree of polymerization that is greater than 300 and an organohydrogensiloxane crosslinker comprising on average 2 or more SiH groups per molecule where the ratio of the alkenyl terminated polydiorganosiloxane and organohydrogen siloxane is such that the molar ratio of SiH groups to alkenyl groups is in a range of 0.5 to 2.0;

(b) greater than 80 weight-percent and at the same time less than 95 wt % based on non-curable thermally conductive material weight of a thermally conductive filler dispersed throughout the matrix material; and
(c) treating agents selected from alkyltrialkoxy silanes where the alkyl contains from one to 14 carbon atoms and monotrialkoxy terminated diorganopolysiloxanes having a degree of polymerization in a range of 20 to 110 and the alkoxy groups each contain from one to 12 carbon atoms dispersed in the matrix material.

2. The non-curable thermally conductive material of claim 1 , wherein the non-functional non-crosslinked organosiloxane fluid is a phenylmethylsiloxane-dimethylsiloxane copolymer.

3. The non-curable thermally conductive material of claim 1 , wherein the alkenyl terminated polydiorganosiloxane has the following chemical structure (I):
ViR 2 SiO—[R 2 SiO] x —SiR 2 Vi   (I)

where Vi is a vinyl group and subscript x has an average value between 400 and 900 and R is independently in each occurrence selected from alkyl and aryl groups having from one to 8 carbon atoms.

4. The non-curable thermally conductive material of claim 1 , wherein the organohydrogensiloxane crosslinker has the following chemical structure (II):
R 3 SiO—[R 2 SiO] a —[HRSiO] b —SiR 3   (II)

where R is independently in each occurrence selected from alkyl and aryl groups having from one to 8 carbon atoms; a has an average value in a range of 3-100; and b has an average value in a range of 2-30.

5. The non-curable thermally conductive material of claim 1 , wherein the thermally conductive filler is any one or any combination of more than one of the following: spherical aluminum particles having an average size of 8 to 10 micrometers, spherical aluminum particles having an average particle size of one to 3 micrometers, zinc oxide particles having an average particle size of 0.10 to 0.15 micrometers, alumina particles have an average particle size of 10 to 20 micrometers, and spherical alumina particles have an average particle size of one to 5 micrometers.

6. The non-curable thermally conductive material of claim 1 , wherein the non-curable thermally conductive material comprises both alkyltrimethoxy silane and monotrialkoxy terminated diorganopolysiloxane treating agents.

7. The non-curable thermally conductive material of claim 1 , wherein the alkyltrimethoxy silane is n-decyltrimethoxysilane and the monotrialkoxy terminated diorganopolysiloxane has the following chemical structure: (CH 3 ) 3 Si[(CH 3 ) 2 SiO] m (OCH 3 ) 3 ; where m has a value in a range of 30 to 110.

8. A process for making the non-curable thermally conductive material of claim 1 , the process comprising the steps of: (a) combining the alkenyl terminated polydiorganosiloxane and organohydrogensiloxane crosslinker together with a hydrosilylation catalyst, the non-functional non-crosslinked organosiloxane fluid, the treating agent, and optionally, any or all of the thermally conductive filler; (b) crosslinking the reactants to make the crosslinked hydrosilylation reaction product in the presence of the treating agent and, optionally, the thermally conductive filler; and (c) mixing in the thermally conductive filler to a concentration of greater than 80 weight-percent and at the same time less than 95 wt % based on the weight of combined materials if not already at that concentration.

9. An article comprising the non-curable thermally conductive material of claim 1 in thermal contact with at least two objects.

10. The article of claim 9 , wherein one object is a bare die and another object is a heat sink.

Assignees

• Dow Silicones Corp

Inventors

• Bhagwagar Dorab
• Hale Cassie
• Wei Peng
• Ge Qianqing
• Zheng Yan
• Li Zhanjie

Classifications

• H10W40/251

  Organics · CPC title

• C08G77/80

  Siloxanes having aromatic substituents, e.g. phenyl side groups · CPC title

• C08G77/50

  by carbon linkages · CPC title

• C09K5/14 Primary

  Solid materials, e.g. powdery or granular · CPC title

• C08G77/08

  characterised by the catalysts used · CPC title