Resin composition, modifier, and resin composition including the modifier

Patent metadata

Field	Value
Publication number	US-11732118-B2
Application number	US-202117401515-A
Country	US
Kind code	B2
Filing date	Aug 13, 2021
Priority date	Aug 17, 2020
Publication date	Aug 22, 2023
Grant date	Aug 22, 2023

Abstract

An object of this invention is to provide a resin composition usable as a modifier with which the brittleness of a plastic material including a plurality of resins, such as a laminate of different kinds of materials collected for recycling, can be overcome and the impact resistance and elongation at break can be enhanced. Provided is a resin composition (A) including the following components (1) and (2): (1) a composition (a1) including at least two kinds of ethylene-vinyl acetate copolymers having different vinyl acetate contents; and (2) a copolymer (a2) that is at least one copolymer selected from an ethylene-acrylic acid copolymer and an ethylene-methacrylic acid copolymer.

First claim

The invention claimed is:

1. A resin composition (A) comprising the following components (1) and (2):
(1) a composition (a1) including at least two kinds of ethylene-vinyl acetate copolymers having different vinyl acetate contents; and
(2) a copolymer (a2) that is at least one copolymer selected from an ethylene-acrylic acid copolymer and an ethylene-methacrylic acid copolymer,
wherein an absolute value of a difference between a solubility parameter of one of the ethylene-vinyl acetate copolymers in the composition (a1) and a solubility parameter of the ethylene-acrylic acid copolymer or the ethylene-methacrylic acid copolymer in the copolymer (a2) is not more than 0.3 MPa, the solubility parameters being calculated according to Fedors method.

2. The resin composition (A) as set forth in claim 1 , wherein
the resin composition (A) contains the composition (a1) in an amount of not less than 50 wt % and not more than 99 wt % and the copolymer (a2) in an amount of not less than 1 wt % and not more than 50 wt %, a total of the composition (a1) and the copolymer (a2) being 100 wt %.

3. The resin composition (A) as set forth in claim 1 , wherein
the copolymer (a2) has an acrylic acid content or a methacrylic acid content of not less than 3 mol % and not more than 15 mol %.

4. The resin composition (A) as set forth in claim 1 , wherein
the composition (a1) is a composition including three or more kinds of ethylene-vinyl acetate copolymers having different vinyl acetate contents.

5. The resin composition (A) as set forth in claim 1 , wherein
in a case where a difference in vinyl acetate content is taken between the copolymers in the composition (a1), a difference in vinyl acetate content in each pair of copolymers in the composition (a1) is not more than 40 wt %.

6. A modifier comprising the resin composition (A) recited in claim 1 , the modifier making at least two kinds of resins compatible with each other.

7. A resin composition (C) comprising the resin composition (A) recited in claim 1 in an amount of not less than 1 wt % and not more than 50 wt % and a thermoplastic resin (B) in an amount of not less than 50 wt % and not more than 99 wt %, a total of the resin composition (A) and the thermoplastic resin (B) being 100 wt %.

8. The resin composition (C) as set forth in claim 7 , wherein
the thermoplastic resin (B) includes at least one kind selected from the group consisting of polyolefin, polyester, an acrylic resin, polyamide, polycarbonate, polystyrene, and a styrene-acrylonitrile copolymer.

9. The resin composition (C) as set forth in claim 7 , wherein
the thermoplastic resin (B) is at least one kind selected from the group consisting of high-density polyethylene, low-density polyethylene, linear low-density polyethylene, polypropylene, an ethylene-propylene copolymer, an ethylene-vinyl alcohol copolymer, nylon 6, nylon 6,6, nylon 11, nylon 12, polyethylene terephthalate, a glycol-modified polyethylene terephthalate resin, polybutylene terephthalate, polylactic acids including poly-L-lactic acid, poly-D-lactic acid, a copolymer of L-lactic acid and D-lactic acid, and a stereo complex of poly-L-lactic acid and poly-D-lactic acid, and polybutylene succinate.

10. The resin composition (C) as set forth in claim 9 , wherein
the thermoplastic resin (B) is at least one kind selected from the group consisting of high-density polyethylene, low-density polyethylene, linear low-density polyethylene, polypropylene, an ethylene-propylene copolymer, an ethylene-vinyl alcohol copolymer, nylon 6, nylon 6,6, nylon 11, nylon 12, polyethylene terephthalate, a glycol-modified polyethylene terephthalate resin, and polybutylene terephthalate.

11. The resin composition (C) as set forth in claim 7 , wherein
the thermoplastic resin (B) includes at least two or more kinds of resins.

12. The resin composition (C) as set forth in claim 7 , wherein
the thermoplastic resin (B) is made of a used molded article.

13. A method for producing a resin composition (C) comprising the resin composition (A) recited in claim 1 in an amount of not less than 1 wt % and not more than 50 wt % and a thermoplastic resin (B) in an amount of not less than 50 wt % and not more than 99 wt %, a total of the resin composition (A) and the thermoplastic resin (B) being 100 wt %, the method comprising a step of kneading the thermoplastic resin (B) and a modifier comprising the resin composition (A) recited in claim 1 with a twin-screw extruder, the modifier making at least two kinds of resins compatible with each other.

14. The method as set forth in claim 13 , wherein
the step of kneading is carried out with the twin-screw extruder at a screw speed of not lower than 50 rpm and not higher than 3000 rpm.

15. A molded product produced by forming the resin composition (C) recited in claim 7 .

Assignees

• Tosoh Corp

Inventors

• KUGIMOTO Daisuke
• Kamiya Koki
• Kouda Shingo

Classifications

• C08L23/06 Primary

  Polyethylene · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L2207/062

  HDPE · CPC title

• C08L2207/066

  LDPE (radical process) · CPC title