Rubber compositions comprising a specific combination of a coupling agent and a hydrocarbon-based resin

Patent metadata

Field	Value
Publication number	US-11732117-B2
Application number	US-201816753221-A
Country	US
Kind code	B2
Filing date	Oct 3, 2018
Priority date	Oct 4, 2017
Publication date	Aug 22, 2023
Grant date	Aug 22, 2023

Abstract

A rubber composition is based on at least: a diene elastomer; a reinforcing inorganic filler; an agent for coupling the reinforcing inorganic filler with the diene elastomer, said coupling agent being a blocked mercaptosilane of formula (I), as described in the claims; a hydrocarbon-based resin predominantly composed of monomers chosen from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, and a crosslinking system. A semi-finished article and a tire may comprise at least one such rubber composition.

First claim

The invention claimed is:

1. A rubber composition based on at least:
a diene elastomer;
a reinforcing inorganic filler;
a coupling agent for coupling the reinforcing inorganic filler with the diene elastomer, the coupling agent being a blocked mercaptosilane of general formula (I):
(R 4 O) d R 3 (3-d) —Si—Z—S—C(═O)—R 5   (I)

in which:
the radical R 3 is selected from the group consisting of linear or branched C 1 -C 10 alkyls,
the radical R 4 is selected from the group consisting of a hydrogen atom or linear or branched C 1 -C 10 alkyls,
the radical R 5 is selected from the group consisting of a hydrogen atom or linear or branched C 1 -C 10 alkyls,
Z is a divalent bonding group containing a linear or branched C 1 -C 8 alkylene; and
d is an integer equal to 1, 2 or 3;

a hydrocarbon-based resin predominantly composed of monomers chosen from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof; and
a crosslinking system,
wherein the coupling agent has a content ranging from 3 to 20 phr, and
wherein the reinforcing inorganic filler has a content ranging from 40 to 200 phr.

2. The rubber composition according to claim 1 , wherein d is equal to 3.

3. The rubber composition according to claim 1 , wherein the hydrocarbon-based resin has a number-average molecular mass Mn that is within a range extending from 200 to 2000 g/mol.

4. The rubber composition according to claim 1 , wherein the hydrocarbon-based resin has a polydispersity index of less than or equal to 2.

5. The rubber composition according to claim 1 , wherein the hydrocarbon-based resin is further composed, in a minor amount, of aromatic monomers.

6. The rubber composition according to claim 5 , wherein a content of aromatic protons of the hydrocarbon-based resin is within a range extending from 1% to 20%.

7. The rubber composition according to claim 1 , wherein a content of hydrocarbon-based resin is within a range extending from 15 to 150 phr.

8. The rubber composition according to claim 1 , wherein the reinforcing inorganic filler comprises at least one silica.

9. The rubber composition according to claim 1 further comprising carbon black.

10. The rubber composition according to claim 1 , wherein the diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers, and mixtures thereof.

11. The rubber composition according to claim 10 , wherein the diene elastomer is selected from the group consisting of polybutadienes, butadiene-styrene copolymers, isoprene-butadiene copolymers, isoprene-styrene copolymers, isoprene-butadiene-styrene copolymers, and mixtures thereof.

12. The rubber composition according to claim 1 , wherein the diene elastomer is a functionalized elastomer.

13. The rubber composition according to claim 12 , wherein the functionalized elastomer has a glass transition temperature Tg of less than or equal to −40° C.

14. A semi-finished article for a tire comprising at least one rubber composition according to claim 1 .

15. A tire comprising at least one rubber composition according to claim 1 .

Assignees

• Michelin & Cie

Inventors

• Labrunie Philippe
• Longchambon Karine
• Copey Laurent

Classifications

• C08L15/00 Primary

  Compositions of rubber derivatives (C08L11/00, C08L13/00 take precedence) · CPC title

• B60C1/0016

  Compositions of the tread · CPC title

• B60C11/0008

  characterised by the tread rubber · CPC title

• B60C2011/0025

  Modulus or tan delta · CPC title

• C08L2312/08

  by silane · CPC title