Substrate with a molybdenum nitride layer system, and coating method for producing a layer system
US-2022372629-A1 · Nov 24, 2022 · US
US11731202B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11731202-B2 |
| Application number | US-202117234578-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 19, 2021 |
| Priority date | Apr 19, 2021 |
| Publication date | Aug 22, 2023 |
| Grant date | Aug 22, 2023 |
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A coating includes a first base layer including a nitride of at least Al and Cr, a second base layer including a nitride of at least Al and Cr overlying the first base layer, and an outermost indicator layer overlying the second base layer. The first base layer has a positive residual compressive stress gradient. The second base layer has substantially constant residual compressive stresses. The outermost indicator layer includes a nitride of Si and Me, wherein Me is at least one of Ti, Zr, Hf, and Cr. The outermost indicator layer has residual compressive stresses that are less than the residual compressive stresses of the second base layer.
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What is claimed is: 1. A coating, comprising: a first base layer comprising a nitride of at least Al and Cr, wherein the first base layer has residual compressive stresses that vary over a thickness direction to define a positive residual compressive stress gradient from a first residual compressive stress at a first distance from the substrate to a second residual compressive stress at a second distance from the substrate, wherein the second distance is greater than the first distance, and wherein the second residual compressive stress is greater than the first residual compressive stress; a second base layer comprising a nitride of at least Al and Cr overlying the first base layer, wherein the second base layer has residual compressive stresses that are substantially constant over a thickness direction, wherein the substantially constant residual compressive stresses are greater than or equal to the second residual compressive stress of the first base layer; and an outermost indicator layer overlying the second base layer, wherein the outermost indicator layer comprises a nitride of Si and Me, wherein Me is at least one of Ti, Zr, Hf, and Cr, wherein the outermost indicator layer has residual compressive stresses that are less than the residual compressive stresses of the second base layer. 2. The coating of claim 1 , wherein the first base layer comprises alternating sublayers, wherein the alternating sublayers include a first sublayer having a first ratio of Al:Cr and a second sublayer having a second ratio of Al:Cr, wherein the first ratio is different from the second ratio. 3. The coating of claim 1 , wherein the second base layer comprises alternating sublayers, wherein the alternating sublayers include a first sublayer having a first ratio of Al:Cr and a second sublayer having a second ratio of Al:Cr, wherein the first ratio is different from the second ratio. 4. The coating of claim 1 , wherein the first base layer comprises at least 90 vol. % face-centered cubic crystalline phase. 5. The coating of claim 1 , wherein the first base layer has a volume fraction of face-centered cubic crystalline phase that varies over the thickness direction to define a gradient from a first volume fraction of face-centered cubic crystalline phase at the first distance from the substrate to a second volume fraction of face-centered cubic crystalline phase at the second distance from the substrate, wherein the second volume fraction of face-centered cubic crystalline phase is greater than the first volume fraction of face-centered cubic crystalline phase. 6. The coating of claim 5 , wherein the second base layer has a volume fraction of face-centered cubic crystalline phase that is substantially constant over a thickness direction, wherein the substantially constant volume fraction of face-centered cubic crystalline phase is greater than or equal to the second volume fraction of face-centered cubic crystalline phase of the first base layer. 7. A coated cutting tool, comprising: a substrate having a rake face, a flank face, and a cutting edge formed at the intersection of the rake face and the flank face; and the coating of claim 1 overlying the substrate. 8. A method for cutting a material, comprising cutting the material using the coated cutting tool of claim 7 . 9. The coated cutting tool of claim 7 , wherein the first base layer comprises alternating sublayers, wherein the alternating sublayers include a first sublayer having a first ratio of Al:Cr and a second sublayer having a second ratio of Al:Cr, wherein the first ratio is different from the second ratio. 10. The coated cutting tool of claim 7 , wherein the second base layer comprises alternating sublayers, wherein the alternating sublayers include a first sublayer having a first ratio of Al:Cr and a second sublayer having a second ratio of Al:Cr, wherein the first ratio is different from the second ratio. 11. The coated cutting tool of claim 7 , wherein the first base layer comprises at least 90 vol. % face-centered cubic crystalline phase. 12. The coated cutting tool of claim 7 , wherein the first base layer has a volume fraction of face-centered cubic crystalline phase that varies over the thickness direction to define a gradient from a first volume fraction of face-centered cubic crystalline phase at the first distance from the substrate to a second volume fraction of face-centered cubic crystalline phase at the second distance from the substrate, wherein the second volume fraction of face-centered cubic crystalline phase is greater than the first volume fraction of face-centered cubic crystalline phase. 13. The coated cutting tool of claim 12 , wherein the second base layer has a volume fraction of face-centered cubic crystalline phase that is substantially constant over a thickness direction, wherein the substantially constant volume fraction of face-centered cubic crystalline phase is greater than or equal to the second volume fraction of face-centered cubic crystalline phase of the first base layer.
Composition of the cutting inserts · CPC title
Cutting tools of which the bits or tips {or cutting inserts} are of special material · CPC title
characterised by physical features other than shape · CPC title
Nitrides (C23C14/0617 takes precedence) · CPC title
characterized by the composition of the alternating layers · CPC title
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