Current collectors having surface structures for controlling formation of solid-electrolyte interface layers

Patent metadata

Field	Value
Publication number	US-11728490-B2
Application number	US-202117237418-A
Country	US
Kind code	B2
Filing date	Apr 22, 2021
Priority date	Apr 22, 2021
Publication date	Aug 15, 2023
Grant date	Aug 15, 2023

Abstract

The present disclosure provides an electrochemical cell that includes an electrically conductive material layer, a precursor material disposed on or adjacent to a first surface of the electrically conductive material layer, and an electroactive material layer disposed on or adjacent to the precursor material. In certain variations, the precursor material forms a continuous layer and a solid-electrolyte interface layer is disposed on or adjacent to an exposed surface of the electroactive material layer. In other variations, the precursor material forms a plurality of distinct precursor structures disposed on the first surface of the electrically conductive material layer in a predetermined pattern, such that at least a portion of each distinct precursor structure is unobstructed by the electroactive material layer. The distinct precursor structures are configured to form surface structures that chemically attach the solid-electrolyte interface layer and the electrically conductive material layer.

First claim

What is claimed is:

1. An electrochemical cell comprising:
an electrically conductive material layer;
a precursor material disposed on or adjacent to a first surface of the electrically conductive material layer, wherein the precursor material is disposed on or adjacent to the first surface of the electrically conductive material so as form a distinct, substantially continuous layer or the precursor material is disposed on or adjacent to the first surface of the electrically conductive material layer so as form a plurality of distinct precursor structures disposed on the first surface of the electrically conductive material layer in a predetermined pattern, and wherein the precursor material has an ionic conductivity less than about 10 −4 S/cm; and
an electroactive material layer disposed on or adjacent to the precursor material.

2. The electrochemical cell of claim 1 , wherein the distinct, substantially continuous layer has an average thickness greater than or equal to about 0.001 μm to less than or equal to about 20 μm.

3. The electrochemical cell of claim 1 , further comprising:
a solid-electrolyte interface layer disposed on or adjacent to an exposed surface of the electroactive material layer.

4. The electrochemical cell of claim 1 , wherein the solid-electrolyte interface layer comprises one or more materials selected from the group consisting of: lithium carbonate (Li 2 CO 3 ), lithium peroxide (Li 2 O 2 ), lithium hydroxide (LiOH), lithium oxide (Li 2 O), lithium fluoride (LiF), lithium nitride (Li 3 N), polyolefins, semicarbonates, and combinations thereof.

5. The electrochemical cell of claim 1 , wherein at least a portion of each distinct precursor structure is unobstructed by the electroactive material layer.

6. The electrochemical cell of claim 1 , wherein at least a portion of each distinct precursor structure extends through the electroactive material layer.

7. The electrochemical cell of claim 1 , wherein the distinct precursor structures cover greater than or equal to about 1% to less than or equal to about 50% of a total surface area of the first surface of the electrically conductive material layer, and
wherein the distinct precursor structures have an average spacing greater than or equal to about 0.1 μm to less than or equal to about 50 μm.

8. The electrochemical cell of claim 1 , wherein an average height of each distinct precursor structure is greater than or equal to about 20% to less than or equal to about 400% greater than an average thickness of the electroactive material layer.

9. The electrochemical cell of claim 1 , wherein an average height of each distinct precursor structure is greater than about 1 μm to less than or equal to about 500 μm, and
wherein the electroactive material layer has an initial thickness greater than about 10 μm to less than or equal to about 200 μm.

10. The electrochemical cell of claim 1 , further comprising:
a solid-electrolyte interface layer disposed on or adjacent to an exposed surface of the electroactive material layer and contacting each of the distinct precursor structures, wherein the distinct precursor structures are configured to form surface structures that chemically attach the solid-electrolyte interface layer and the electrically conductive material layer.

11. The electrochemical cell of claim 10 , wherein the solid-electrolyte interface layer comprises one or more materials selected from the group consisting of: lithium carbonate (Li 2 CO 3 ), lithium peroxide (Li 2 O 2 ), lithium hydroxide (LiOH), lithium oxide (Li 2 O), lithium fluoride (LiF), lithium nitride (Li 3 N), polyolefins, semicarbonates, and combinations thereof.

12. The electrochemical cell of claim 1 , wherein the precursor material comprises one or more materials selected from the group consisting of: polytetrafluoroethylene (PTFE), lithium fluoride (LiF), polyvinylidene difluoride (PVdF), perfluoro-organosiloxane, and combinations thereof.

13. An electrochemical cell comprising:
an electrically conductive material layer;
a plurality of distinct precursor structures disposed on the first surface of the electrically conductive material layer in a predetermined pattern, wherein the distinct precursor structures cover greater than or equal to about 1% to less than or equal to about 50% of a total surface area of the first surface of the electrically conductive material layer, and the distinct precursor structures have an average spacing greater than or equal to about 0.1 μm to less than or equal to about 50 μm; and
an electroactive material layer disposed on or adjacent to the precursor material such that at least a portion of each distinct precursor structure is unobstructed by the electroactive material layer.

14. The electrochemical cell of claim 13 , wherein at least a portion of each distinct precursor structure extends through the electroactive material layer.

15. The electrochemical cell of claim 13 , further comprising:
a solid-electrolyte interface layer disposed on or adjacent to an exposed surface of the electroactive material layer and contacting each of the distinct precursor structures, wherein the distinct precursor structures are configured to form surface structures that chemically attach the solid-electrolyte interface layer and the electrically conductive material layer.

16. The electrochemical cell of claim 13 , wherein the solid-electrolyte interface layer comprises one or more materials selected from the group consisting of: lithium carbonate (Li 2 CO 3 ), lithium peroxide (Li 2 O 2 ), lithium hydroxide (LiOH), lithium oxide (Li 2 O), lithium fluoride (LiF), lithium nitride (Li 3 N), polyolefins, semicarbonates, and combinations thereof; and
wherein each of the distinct precursor structures comprises one or more materials selected from the group consisting of: polytetrafluoroethylene (PTFE), lithium fluoride (LiF), polyvinylidene difluoride (PVdF), perfluoro-organosiloxane, and combinations thereof.

17. An electrochemical cell comprising:
an electrically conductive material layer;
an electroactive material layer disposed on or adjacent to an exposed surface of the electrically conductive material layer;
a solid-electrolyte interface layer disposed on or adjacent to an exposed surface of the electroactive material layer; and
a plurality of distinct surface structures freely available through the electroactive material layer and chemically attaching a first surface of the electrically conductive material layer and the solid-electrolyte interface layer.

18. The electrochemical cell of claim 17 , wherein the plurality of surface structures comprise lithium fluoride (LiF), and
wherein the solid-electrolyte interface layer comprises one or more materials selected from the group consisting of: lithium carbonate (Li 2 CO 3 ), lithium peroxide (Li 2 O 2 ), lithium hydroxide (LiOH), lithium oxide (Li 2 O), lithium fluoride (LiF), lithium nitride (Li 3 N), polyolefins, semicarbonates, and combinations thereof.

19. The electrochemical cell of claim 17 , wherein the distinct surface structures cover greater than or equal to about 1% to less than or equal to about 50% of a total surface area of the first surface of the electrically conductive material layer, and
wherein the distinct surface structures have an average spacing greater than or equal to about 0.1 μm to less than or equal to about 50 μm.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Schmidt Robert D
• Dadheech Gayatri V

Classifications

• H01M4/667 Primary

  in the form of layers, e.g. coatings · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M10/0562

  Solid materials · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M2300/008

  Halides · CPC title