Negative electrode for lithium secondary battery and lithium secondary battery comprising same

Patent metadata

Field	Value
Publication number	US-11728488-B2
Application number	US-202217930714-A
Country	US
Kind code	B2
Filing date	Sep 8, 2022
Priority date	Nov 7, 2017
Publication date	Aug 15, 2023
Grant date	Aug 15, 2023

Abstract

A negative electrode for a lithium secondary battery comprises a current collector and a negative electrode active material layer formed on the current collector, wherein the negative electrode active material layer includes a first negative electrode active material and a first binder, and a second active material layer formed on the first active material layer and including a second negative electrode active material and a second binder, a content of the first binder is greater than that of the second binder, a loading level of the negative electrode active material layer is 10 mg/cm 2 to 30 mg/cm 2 , a loading level of the first active material layer is 4 mg/cm 2 to 25 mg/cm 2 , a loading level of the second active material layer is 4 mg/cm 2 to 25 mg/cm 2 , and a loading level of the second active material layer is equal to or higher than that of the first active material layer.

First claim

What is claimed is:

1. A negative electrode for a lithium secondary battery, the negative electrode comprising:
a current collector; and
a negative electrode active material layer on the current collector,
wherein the negative electrode active material layer comprises a first active material layer including a first active material and a first binder, and a second active material layer on the first active material layer and including a second active material and a second binder,
wherein a content of the first binder is greater than a content of the second binder,
wherein the negative electrode has an active mass density of 1.20 g/cc to 1.80 g/cc: and
wherein an average particle size (D50) of the first active material is larger than an average particle size (D50) of the second active material.

2. The negative electrode of claim 1 , wherein the content of the first binder is 1 wt % to 10 wt % based on a total weight of the first active material layer.

3. The negative electrode of claim 1 , wherein the content of the second binder is 0.5 wt % to 10 wt % based on a total weight of the second active material layer.

4. The negative electrode of claim 1 ,
wherein a ratio of the content of the second binder to the content of the first binder is more than 0 and less than 1.

5. The negative electrode of claim 1 ,
wherein a ratio of a loading level of the first active material layer to a loading level of the second active material layer is 1:1 to 1:7.

6. The negative electrode of claim 1 , wherein at least one selected from among the first active material layer and the second active material layer further comprises a conductive material.

7. The negative electrode of claim 1 , wherein a conductive layer is further included between the first active material layer and the second active material layer.

8. The negative electrode of claim 1 , wherein the first binder and the second binder are respectively non-aqueous binders or aqueous binders.

9. The negative electrode of claim 1 , wherein at least one selected from among the first binder and the second binder is an aqueous binder.

10. The negative electrode of claim 1 , wherein a pellet density of each of the first active material of the first active material layer and the second active material of the second active material layer is 1.1 g/cc to 2.0 g/cc.

11. The negative electrode of claim 1 , wherein a pellet density of the second active material of the second active material layer is smaller than a pellet density of the first active material of the first active material layer by 0.01 g/cc to 0.5 g/cc.

12. A lithium secondary battery comprising:
a negative electrode;
a positive electrode; and
an electrolyte,
wherein the negative electrode is of claim 1 .

13. The negative electrode of claim 1 , wherein the average particle size (D50) of the first active material is 5 μm to 25 μm and/or the average particle size (D50) of the second active material is 5 μm to 25 μm.

14. The negative electrode of claim 1 , wherein a ratio of the average particle size (D50) of the first active material to the average particle size (D50) of the second active material is at most 4.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Cha Inoh
• Kim Deok-Hyun
• Lee Jinhee

Classifications

• H01M2004/027

  Negative electrodes · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/621

  Binders · CPC title

• H01M4/13 Primary

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title