Shoe with outsole containing vegetable oil extended high TG styrene/butadiene elastomer

Patent metadata

Field	Value
Publication number	US-11723430-B2
Application number	US-202017024895-A
Country	US
Kind code	B2
Filing date	Sep 18, 2020
Priority date	Sep 18, 2020
Publication date	Aug 15, 2023
Grant date	Aug 15, 2023

Abstract

A shoe comprising an outsole, where the outsole is comprised of a rubber composition comprised of (A) diene-based elastomer comprising: (1) from about 20 to about 45 phr of high Tg SSBR pre-extended with vegetable oil, wherein said SSBR has a Tg in a range of from about −20° C. to about +10° C. and a bound styrene content in a range of from about 25 to about 50 percent and a vinyl 1,2-content in a range of from about 10 to about 80 percent based on butadiene content, (2) from 55 to about 80 phr of at least one additional diene-based elastomer comprising of at least one of polybutadiene, cis 1,4-polyisoprene rubber, and acrylonitrile-butadiene rubber, and (B) about 20 to about 70 phr of reinforcing filler comprised of a combination of carbon black and silica where the filler is comprised of from about 50 to about 100 weight percent silica.

First claim

What is claimed is:

1. A shoe comprising an outsole, the outsole intended to be ground-contacting, where the outsole is comprised of a rubber composition comprised of, based on parts by weight per 100 parts by weight elastomer (phr):
(A) conjugated diene-based elastomer comprising:
(1) from about 20 to about 45 phr of high Tg styrene/butadiene elastomer (SSBR) pre-extended with vegetable triglyceride oil, wherein said SSBR has a Tg in a range of from about −20° C. to about +10° C. and a bound styrene content in a range of from about 25 to about 50 percent and a vinyl 1,2-content in a range of from about 10 to about 80 percent based on butadiene content,
(2) from 55 to about 80 phr of at least one additional conjugated diene-based elastomer comprising of at least one of polybutadiene, cis 1,4-polyisoprene rubber, and acrylonitrile-butadiene rubber and combinations thereof, and

(B) about 20 to about 70 phr of reinforcing filler comprised of a combination of rubber reinforcing carbon black and precipitated silica where the reinforcing filler is comprised of from about 50 to about 100 weight percent precipitated silica.

2. The shoe of claim 1 , wherein additional conjugated diene-based elastomer comprises the acrylonitrile-butadiene rubber and the rubber composition further comprise from 0.1 to 10 phr of an epoxidized soybean oil.

3. The shoe of claim 1 where the high Tg SSBR is extended with about 5 to about 40 parts by weight vegetable triglyceride oil per 100 parts by weight of said high Tg SSBR.

4. The shoe of claim 1 wherein the vegetable triglyceride oil is comprised of at least one of soybean oil and sunflower oil.

5. The shoe of claim 1 wherein the amount of the vegetable triglyceride oil in the rubber composition ranges from 1 to 20 phr.

6. The shoe of claim 1 wherein the rubber composition further comprises a coupling agent selected from the group consisting of bis(3-triethoxysilylpropyl) polysulfides and organoalkoxymercaptosilanes and combinations thereof.

7. The shoe of claim 6 wherein the precipitated silica is pre-treated with at least one of said coupling agents.

8. The shoe of claim 1 wherein said rubber composition contains from zero to about 20 phr of freely added petroleum based rubber processing oil.

9. The shoe of claim 1 wherein the rubber composition further comprises from 0.1 to 30 phr of corncob granules.

10. The shoe of claim 1 , wherein the rubber composition further comprises from 1 to 10 phr of zinc rosinate.

11. The shoe of claim 1 where the triglyceride vegetable oil is comprised of at least one of sunflower oil, rapeseed oil, canola oil, palm oil and soybean oil.

12. The shoe of claim 1 wherein the SSBR is an end-functionalized styrene/butadiene elastomer with functional groups reactive with hydroxyl groups on said precipitated silica comprised of at least one of alkoxy, amine, siloxy and thiol groups.

13. The shoe of claim 1 wherein the SSBR is tin or silicon coupled.

14. The shoe of claim 1 wherein said triglyceride vegetable oil is comprised of soybean oil.

15. The tire of claim 1 wherein said triglyceride oil is comprised of sunflower oil.

Assignees

• Goodyear Tire & Rubber

Inventors

• Sandstrom Paul Harry

Classifications

• A43B13/04 Primary

  Plastics, rubber or vulcanised fibre · CPC title

• A43B13/122

  characterised by the outsole or external layer · CPC title

• A43B13/187

  Resiliency achieved by the features of the material, e.g. foam, non liquid materials · CPC title

• C08K3/04

  Carbon · CPC title

• C08K3/36

  Silica · CPC title