Piezoelectric substrate, piezoelectric woven fabric, piezoelectric knitted fabric, piezoelectric device, force sensor, and actuator

Patent metadata

Field	Value
Publication number	US-11723279-B2
Application number	US-201716307749-A
Country	US
Kind code	B2
Filing date	Jun 5, 2017
Priority date	Jun 6, 2016
Publication date	Aug 8, 2023
Grant date	Aug 8, 2023

Abstract

The present invention provides: a piezoelectric substrate which includes a first piezoelectric body having an elongated shape and helically wound in one direction, and which does not include a core material, in which the first piezoelectric body includes a helical chiral polymer (A) having an optical activity; in which the length direction of the first piezoelectric body is substantially parallel to the main direction of orientation of the helical chiral polymer (A) included in the first piezoelectric body; and in which the first piezoelectric body has a degree of orientation F, as measured by X-ray diffraction according to the following Equation (a), within the range of 0.5 or more but less than 1.0:

degree of orientation F =(180°−α)/180°  (a)

(in which α represents the half-value width of the peak derived from the orientation).

First claim

The invention claimed is:

1. A piezoelectric substrate comprising:
(i) a first piezoelectric body having an elongated shape and helically wound in one direction, wherein the piezoelectric substrate does not comprise a core material; or
(ii) a first piezoelectric body having an elongated shape and helically wound in one direction around a core material, wherein the core material is a non-electrically conductive core material having an elongated shape,
wherein the first piezoelectric body comprises a helical chiral polymer (A) having optical activity,
wherein a length direction of the first piezoelectric body is substantially parallel to a main direction of orientation of the helical chiral polymer (A) included in the first piezoelectric body,
wherein the first piezoelectric body has a degree of orientation F, as measured by X-ray diffraction according to Equation (a), within a range of 0.5 or more but less than 1.0:
the degree of orientation F =(180°−α)/180°  (a)

wherein α represents a half-value width of a peak of an orientation, and
wherein adjacent portions of the first piezoelectric body are adhered with each other by an adhesive composition.

2. The piezoelectric substrate according to claim 1 ,
wherein the first piezoelectric body is in a fibrous form composed of a single bundle or a plurality of bundles, and has a major axis diameter of a cross section from 0.0001 mm to 10 mm.

3. The piezoelectric substrate according to claim 1 ,
wherein the first piezoelectric body is in a form of an elongated flat plate and has a thickness from 0.001 mm to 0.2 mm and a width from 0.1 mm to 30 mm, and
wherein a ratio of the width of the first piezoelectric body to the thickness of the first piezoelectric body is 1.5 or more.

4. The piezoelectric substrate according to claim 1 , further comprising a fiber wound in a different direction from the one direction of the wound first piezoelectric body,
wherein the first piezoelectric body and the fiber are alternately crossed with each other to be formed into a braided structure.

5. The piezoelectric substrate according to claim 1 , further comprising a second piezoelectric body having an elongated shape and wound in a different direction from the one direction of the wound first piezoelectric body,
wherein the second piezoelectric body comprises a helical chiral polymer (A) having optical activity,
wherein a length direction of the second piezoelectric body is substantially parallel to a main direction of orientation of the helical chiral polymer (A) included in the second piezoelectric body,
wherein the second piezoelectric body has a degree of orientation F, as measured by X-ray diffraction according to Equation (a), within the range of 0.5 or more but less than 1.0,
wherein the first piezoelectric body and the second piezoelectric body are alternately crossed with each other to be formed into a braided structure, and
wherein the helical chiral polymer (A) included in the first piezoelectric body has a different chirality from a chirality of the helical chiral polymer (A) included in the second piezoelectric body.

6. The piezoelectric substrate according to claim 1 , wherein the first piezoelectric body has a helix angle from 10° to 80°.

7. The piezoelectric substrate according to claim 1 , wherein the core material and the first piezoelectric body are twisted with each other.

8. The piezoelectric substrate according to claim 7 ,
wherein the first piezoelectric body is in a fibrous form composed of a single bundle or a plurality of bundles, and
wherein the first piezoelectric body has a major axis diameter of a cross section from 0.0001 mm to 2 mm.

9. The piezoelectric substrate according to claim 1 ,
wherein the first piezoelectric body comprises an adhesive composition, and
wherein a cured product of the adhesive composition has a tensile elastic modulus, as measured in accordance with ASTM D-882, from 0.1 MPa to 10 GPa.

10. The piezoelectric substrate according to claim 1 , wherein the helical chiral polymer (A) included in the first piezoelectric body is a polylactic acid polymer having a main chain comprising a repeating unit represented by Formula (1):

11. The piezoelectric substrate according to claim 1 , wherein the helical chiral polymer (A) included in the first piezoelectric body has an optical purity of 95.00% ee or more.

12. The piezoelectric substrate according to claim 1 , wherein the helical chiral polymer (A) included in the first piezoelectric body is composed of D-form or L-form.

13. The piezoelectric substrate according to claim 1 , wherein α content of the helical chiral polymer (A) included in the first piezoelectric body is 80% by mass or more with respect to a total amount of the first piezoelectric body.

14. A piezoelectric woven fabric having a woven fabric structure composed of warp threads and weft threads,
wherein at least one of the warp threads or the weft threads comprises the piezoelectric substrate according to claim 1 .

15. A piezoelectric device comprising the piezoelectric woven fabric according to claim 14 .

16. A piezoelectric woven fabric having a woven fabric structure composed of warp threads and weft threads,
wherein both of the warp threads and the weft threads comprise the piezoelectric substrate according to claim 1 ,
wherein the first piezoelectric body included in the warp threads is wound in a different winding direction from a winding direction of the first piezoelectric body included in the weft threads, and
wherein the helical chiral polymer (A) included in the warp threads and the helical chiral polymer (A) included in the weft threads have identical chiralities.

17. A piezoelectric woven fabric having a woven fabric structure composed of warp threads and weft threads,
wherein both of the warp threads and the weft threads comprise the piezoelectric substrate according to claim 1 ,
wherein the first piezoelectric body included in the warp threads and the first piezoelectric body included in the weft threads have identical winding directions, and
wherein the helical chiral polymer (A) included in the warp threads has a different chirality from a chirality of the helical chiral polymer (A) included in the weft threads.

18. A piezoelectric knitted fabric having a knitted fabric structure comprising the piezoelectric substrate according to claim 1 .

19. A piezoelectric device comprising the piezoelectric knitted fabric according to claim 18 .

20. A force sensor comprising the piezoelectric substrate according to claim 1 .

21. An actuator comprising the piezoelectric substrate according to claim 1 .

Assignees

• Mitsui Chemicals Inc
• Murata Manufacturing Co

Inventors

• Yoshida Mitsunobu
• Tanimoto Kazuhiro
• Onishi Katsuki
• Nishikawa Shigeo
• Ando Masamichi

Classifications

• H10N30/857 Primary

  Macromolecular compositions · CPC title

• C08G63/08

  Lactones or lactides · CPC title

• C08L67/04

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• D01F6/625

  derived from hydroxy-carboxylic acids, e.g. lactones · CPC title

• G01L1/16

  using properties of piezoelectric devices · CPC title