System comprising pH/ORP electrodes with improved anti-poisoning characteristics

Patent metadata

Field	Value
Publication number	US-11719666-B2
Application number	US-202017024722-A
Country	US
Kind code	B2
Filing date	Sep 18, 2020
Priority date	Sep 19, 2019
Publication date	Aug 8, 2023
Grant date	Aug 8, 2023

Abstract

A reference electrode system for a pH-sensor system includes: a first junction having a membrane with a sealed side; a reference electrode, the reference electrode and/or an electrically conducting wire of the reference electrode being covered completely except for an end portion of the reference electrode, by a sleeve; and a tube that is arranged, at least partly, around the reference electrode, the electrically conducting wire, and the sleeve, the tube having a closed end which is arranged near the end portion of the reference electrode.

First claim

What is claimed is:

1. A reference electrode system for a pH-sensor system, the reference electrode system comprising:
a first junction comprising a membrane with a sealed side;
a reference electrode, comprising a top end portion and a bottom end portion, wherein the reference electrode and/or an electrically conducting wire of the reference electrode is covered completely, except for the bottom end portion of the reference electrode, by a sleeve and wherein the top end portion and/or the electrically conducting wire protrudes from the sleeve; and
a tube, having an open top end portion and a closed bottom end, the tube being arranged, at least partly, around the reference electrode, the electrically conducting wire, and the sleeve, the closed bottom end of the tube being arranged near the end of the bottom portion of the reference electrode;
wherein the closed end of the tube prevents ions from penetrating therethrough.

2. The reference electrode system of claim 1 , further comprising:
at least one second junction comprising a connecting element that is, at least partly, surrounded by a rubber material,
wherein the at least one second junction is arranged between the first junction and the reference electrode.

3. The reference electrode system of claim 2 , wherein, when the reference electrode system comprises a plurality of second junctions, connecting elements thereof are arranged so as to be vertically displaced.

4. The reference electrode system of claim 3 , wherein each connecting element comprises wood and/or is a wooden dowel.

5. The reference electrode system of claim 2 , wherein the rubber material comprises a fluorocarbon-based synthetic rubber.

6. The reference electrode system of claim 1 , wherein the membrane comprises polytetrafluoroethylene or PTFE, and/or
wherein the reference electrode is a wire that comprises Ag/AgCl.

7. The reference electrode system of claim 1 , wherein the sealed side is arranged circumferentially at, at least, the sealed side of the membrane and comprises at least one of:
an O-ring, a potting compound, and/or a layer of glue.

8. The reference electrode system of claim 1 , wherein the sleeve comprises electrically insulating plastic and/or silicone.

9. A pH-sensor system, comprising:
the reference electrode system of claim 1 ;
a sensor enclosure; and
a measuring electrode,
wherein a sealed side of a first junction of the reference electrode system is arranged between a membrane of the first junction and the sensor enclosure, and/or between the membrane and the measuring electrode so as to seal a front-side of the membrane from a back-side of the membrane.

10. A method for manufacturing a pH-sensor system, the method comprising the steps of:
providing a sensor enclosure, a first end of the sensor enclosure being open;
arranging a measuring electrode at least partly in the sensor enclosure and connecting the measuring electrode to a first electrically conducting wire;
arranging a reference electrode, comprising a top end portion and a bottom end portion, at least partly in the sensor enclosure and connecting the reference electrode to a second electrically conducting wire;
covering the reference electrode and/or the second electrically conducting wire completely, except for the bottom end portion of the reference electrode, by a sleeve and wherein the top end portion and/or the electrically conducting wire protrudes from the sleeve;
arranging a tube, having an open top end portion and a closed bottom end, the tube being arranged, at least partly, around the reference electrode, the wire, and the sleeve, the closed bottom end of the tube being arranged near the end of the bottom portion of the reference electrode, wherein the closed end of the tube prevents ions from penetrating therethrough; and
arranging, at or close to the first end, a first junction comprising a membrane with a sealed side so as to seal a front-side of the membrane from a back-side of the membrane.

11. The method of claim 10 , further comprising the step of:
before arranging the first junction, arranging, at least one second junction in the sensor enclosure,
wherein the at least one second junction comprises a connecting element that is, at least partly, surrounded by a rubber material so as to seal a first portion of the connecting element from a second, opposite, portion of the connecting element.

Assignees

• Abb Schweiz Ag

Inventors

• Carr Benjamin
• Knight Kenton

Classifications

• G01N27/301 Primary

  Reference electrodes · CPC title

• G01N27/302 Primary

  pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes (ion selective electrodes G01N27/333, glass electrodes G01N27/36) · CPC title

• G01N27/4035

  Combination of a single ion-sensing electrode and a single reference electrode (G01N27/406 and G01N27/413 take precedence) · CPC title

• G01N27/31

  Half-cells with permeable membranes, e.g. semi-porous or perm-selective membranes · CPC title

• G01N27/36

  Glass electrodes · CPC title