Rare Earth Element—Aluminum Alloys

Patent metadata

Field	Value
Publication number	US-11718898-B2
Application number	US-202016927787-A
Country	US
Kind code	B2
Filing date	Jul 13, 2020
Priority date	Jul 12, 2019
Publication date	Aug 8, 2023
Grant date	Aug 8, 2023

Abstract

An alloy includes aluminum, a rare earth element, and an alloying element selected from the following: Si, Cu, Mg, Fe, Ti, Zn, Zr, Mn, Ni, Sr, B, Ca, and a combination thereof. The aluminum (Al), the rare earth element (RE), and the alloying element are characterized by forming at least one form of an intermetallic compound. An amount of the rare earth element in the alloy is in a range of about 1 wt. % to about 12 wt. %, and an amount of the alloying element in the alloy is greater than an amount of the alloying element present in the intermetallic compound.

First claim

What is claimed is:

1. An alloy, comprising:
aluminum;
a rare earth element; and
an alloying element selected from the group consisting of: Si, Cu, Mg, Fe, Ti, Zn, Zr, Mn, Ni, Sr, B, Ca, and a combination thereof,
wherein the aluminum (Al), the rare earth element (RE), and the alloying element are characterized by forming at least one form of an intermetallic compound,
wherein an amount of the rare earth element in the alloy is in a range of about 1 wt. % to about 12 wt. %,
wherein an amount of the alloying element in the alloy is greater than an amount of the alloying element present in the intermetallic compound,
wherein the amount of alloying element present in the intermetallic compound is a portion of the amount of alloying element in the alloy.

2. The alloy as recited in claim 1 , comprising an Al-based matrix, wherein the alloying element is present in the Al-based matrix.

3. The alloy as recited in claim 1 , wherein the alloy includes more than one composition of the intermetallic compound, wherein each composition of the intermetallic compound has a different crystal structure.

4. The alloy as recited in claim 1 , wherein the rare earth element is selected from the group consisting of: Ce, La, Nd, Pr, and mischmetal.

5. The alloy as recited in claim 1 , wherein the alloying element is a combination of a first alloying element and at least one second alloying element that is different from the first alloying element,
wherein the at least one form of the intermetallic compound comprises Al-RE-the first alloying element.

6. The alloy as recited in claim 5 , wherein the second alloying element has partial occupancy within the intermetallic compound Al-RE-the first alloying element.

7. The alloy as recited in claim 1 , wherein the alloying element includes Si, wherein the alloy is characterized as having:
a ratio of amounts of Si:RE greater than 2:1,
ternary intermetallic compound Al—RE-Si,
Si having an elemental form, and
an Al-based matrix.

8. The alloy as recited in claim 7 , wherein the ternary intermetallic compound Al—RE-Si is selected from the group consisting of: RE(Si 1-x ,Al x ) 2 , AlRESi 2 , AlxRESi 2-x , Al 2 RESi 2 , and Al 4 RE 3 Si 6 .

9. The alloy as recited in claim 1 , wherein the alloying element includes Cu, wherein the alloy is characterized as having:
a ratio of amounts of Cu:RE greater than 1.5:1,
a ternary intermetallic compound Al—RE-Cu, and
an Al-based matrix comprising Cu.

10. The alloy as recited in claim 9 , wherein the ternary intermetallic compound Al—RE-Cu is selected from the group consisting of: Al 8 RECu 4 , Al 10 RE 2 Cu 7 , Al 3 RECu, AlRECu, and AlRE 2 Cu 2 .

11. The alloy as recited in claim 1 , wherein the alloying element include Mg, wherein the alloy is characterized as having:
a ratio of amounts of Mg:RE is greater than 1:1
a ternary intermetallic compound Al—RE-Mg, and
an Al-based matrix comprising Mg.

12. The alloy as recited in claim 1 , wherein the alloying element includes Ni, wherein the alloy is characterized as having:
a ratio of amounts of Ni:RE greater than 0.8:1,
a ternary intermetallic compound Al—RE-Ni, and
an Al-based matrix comprising Ni.

13. The alloy as recited in claim 12 , wherein the ternary intermetallic compound Al—RE-Ni is selected from the group consisting of: Al—RE-Ni: AlRENi, Al 2 RENi, Al 23 RE 4 Ni 6 , Al 5 RENi 2 , Al 4 RENi, Al 5 RE 2 Ni 5 , Al 3 RENi 2 , Al 7 RENi 2 , Al 17 RE 40 Ni 43 , and AlRENi 4 .

14. The alloy as recited in claim 1 , wherein the alloying element includes Mn, wherein the alloy is characterized as having:
a ratio of amounts of Mn:RE greater than 0.8:1,
a ternary intermetallic compound Al—RE-Mn, and
an Al-based matrix comprising Mn.

15. The alloy as recited in claim 1 , wherein the alloying element include Fe, wherein the alloy is characterized as having:
a ratio of amounts of Fe:RE greater than 0.8:1,
a ternary intermetallic compound Al—RE-Fe, and
an Al-based matrix comprising Fe.

16. The alloy as recited in claim 15 , wherein the ternary intermetallic compound Al—RE-Fe is selected from the group consisting of: Al 10 REFe 2 , Al 8 REFe 2 , and AL 8 REFe 4 .

17. The alloy as recited in claim 1 , wherein the alloying element includes Zn, wherein the alloy is characterized as having:
a ratio of amounts of Zn:RE greater than 1:1,
a ternary intermetallic compound Al—RE-Zn, and
an Al-based matrix comprising Zn.

18. The alloy as recited in claim 1 , wherein the alloy has a structure comprising:
a plurality of particles; and
an Al-based matrix positioned around the particles,
wherein each particles comprises a core having a first intermetallic compound, and a shell surrounding the core,
wherein the shell has a second intermetallic compound that is different from the first intermetallic compound.

19. The alloy as recited in claim 18 , wherein the core includes the aluminum and the rare earth element, the shell includes the at least one form of a ternary intermetallic compound comprising the aluminum, the rare earth element, and the alloying element, and the Al-based matrix includes the alloying element.

20. A composite material comprising the alloy as recited in claim 1 and an additional material, wherein an amount of the alloy is in a range of about 50 vol. % to about 99.9 vol. % of a total vol. % of the composite material.

Assignees

• L Livermore Nat Security Llc
• Univ Tennessee Res Found
• Univ Iowa State Res Found Inc
• Ut Battelle Llc
• Eck Ind Inc

Inventors

• Moore Emily E
• Henderson Hunter B
• Perron Aurelien
• Mccall Scott K
• Rios Orlando
• Sims Zachary C
• Kesler Michael S
• Weiss David
• Turchi Patrice E A
• Ott Ryan T

Classifications

• C22C21/02 Primary

  with silicon as the next major constituent · CPC title

• Y10T428/12181

  Composite powder [e.g., coated, etc.] · CPC title