Refractory material

Patent metadata

Field	Value
Publication number	US-11718718-B2
Application number	US-202016877716-A
Country	US
Kind code	B2
Filing date	May 19, 2020
Priority date	Nov 28, 2017
Publication date	Aug 8, 2023
Grant date	Aug 8, 2023

Abstract

Provided is an expansive refractory material that not only has excellent fire resistance but also can provide a heat insulating function for protecting a content by expanding to form a heat insulating layer when the refractory material is brought close to a heat source or comes into contact with flame. The refractory material at least includes: discontinuous reinforcing fibers having a thermal conductivity of 4 W/(m·K) or higher; and a flame-retardant thermoplastic resin, wherein the discontinuous reinforcing fibers are dispersed in the refractory material. The refractory material has a post-expansion porosity of 30% or higher.

First claim

What is claimed is:

1. A refractory material at least comprising: discontinuous reinforcing fibers having a thermal conductivity of 4 W/(m·K) or higher; and a flame-retardant thermoplastic resin, wherein the discontinuous reinforcing fibers are dispersed in the flame-retardant thermoplastic resin to form the refractory material,
wherein the refractory material after expansion has a porosity of 30% or higher.

2. The refractory material according to claim 1 , wherein the refractory material after expansion has a thermal conductivity of 0.15 W/(m·K) or lower.

3. The refractory material according to claim 1 , wherein the refractory material after expansion has a thermal resistance of 0.05 m 2 ·K/W or higher.

4. The refractory material according to claim 1 , wherein the refractory material has a flexural modulus of 3 GPa or higher and a flexural strength of 50 MPa or higher.

5. The refractory material according to claim 1 , wherein the flame-retardant thermoplastic resin has a limiting oxygen index of 30 or higher.

6. The refractory material according to claim 1 , wherein in the refractory material a proportion of the discontinuous reinforcing fibers based on a total amount of a resin matrix including the flame-retardant thermoplastic resin and the discontinuous reinforcing fibers is in a range from 15 to 80 wt %.

7. The refractory material according to claim 1 , wherein the discontinuous reinforcing fibers have an average fiber length in a range from 2 to 50 mm.

8. The refractory material according to claim 1 , wherein the discontinuous reinforcing fibers include at least one selected from the group consisting of carbon fibers, silicon carbide fibers, alumina fibers, ceramic fibers, basalt fibers, and metal fibers.

9. The refractory material according to claim 1 , wherein the flame-retardant thermoplastic resin includes at least one resin selected from the group consisting of a polyetherimide-series resin, a polysulfone-series resin, a polyethersulfone-series resin, and a polyetheretherketone-series resin.

10. A method for producing a refractory material as recited in claim 1 , the method comprising:
preparing one or more mixed nonwoven fabrics each at least including a flame-retardant thermoplastic resin in a particulate or fibrous form and discontinuous reinforcing fibers having a thermal conductivity of 4 W/(m·K) or higher; and
heating the one or more overlaid mixed nonwoven fabrics at a temperature equal to or higher than a flow starting temperature of the thermoplastic resin under pressure, followed by cooling the resultant under pressure.

11. The refractory material according to claim 1 , wherein the discontinuous fibers in bent state are restricted by the flame-retardant thermoplastic resin.

12. The method according to claim 10 , wherein the material after cooling has discontinuous fibers in bent state restricted by the flame-retardant thermoplastic resin.

Assignees

• Kuraray Co

Inventors

• Katsuya Satoshi
• Washitake Yosuke
• Endo Ryokei
• Suiko Shunsuke

Classifications

• C08J5/042 Primary

  with carbon fibres · CPC title

• C08J2371/10

  from phenols · CPC title

• C08J2379/02

  Polyamines · CPC title

• C08J5/048 Primary

  Macromolecular compound to be reinforced also in fibrous form · CPC title

• C08J2379/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title