Catalytic washcoat with controlled porosity for NOx abatement

Patent metadata

Field	Value
Publication number	US-11717814-B2
Application number	US-201816620116-A
Country	US
Kind code	B2
Filing date	Jun 8, 2018
Priority date	Jun 9, 2017
Publication date	Aug 8, 2023
Grant date	Aug 8, 2023

Abstract

The present disclosure recognizes a correlation between zeolitic surface area (ZSA) of a catalyst composition and its catalytic activity. Particularly, the disclosure provides catalyst articles for diesel NO x abatement, including a substrate and a washcoat layer containing metal-promoted molecular sieves, wherein the zeolitic surface area (ZSA) of the catalyst article is about 100 m 2 /g or greater, the volumetric surface area is about 900 m 2 /in 3 or greater, and/or the total zeolitic surface area (tZSA) is about 1200 m 2 or greater. The disclosure further relates to methods for evaluating ZSA, volumetric ZSA, and tZSA, e.g., including the steps of coating a catalyst composition comprising metal-promoted molecular sieves onto a substrate; calcining and aging the catalyst composition; determining the ZSA (or volumetric ZSA or tZSA) thereof; and correlating the ZSA (or volumetric ZSA or tZSA) with catalyst composition NO x abatement activity to determine whether the catalyst composition is suitable for an intended use.

First claim

What is claimed:

1. A catalyst article for diesel NO x abatement, comprising:
a substrate; and
a washcoat layer coated on the substrate,
wherein the washcoat layer comprises metal-promoted molecular sieves, and
wherein the zeolitic surface area (ZSA) of the catalyst article is about 100 m 2 /g or greater.

2. The catalyst article of claim 1 , wherein the ZSA of the catalyst article is about 120 m 2 /g or greater.

3. The catalyst article of claim 1 , wherein the ZSA of the catalyst article is about 130 m 2 /g or greater.

4. The catalyst article of claim 1 , wherein the ZSA of the catalyst article is about 100 m 2 /g to about 600 m 2 /g.

5. The catalyst article of claim 1 , wherein the ZSA of the catalyst article is about 120 m 2 /g to about 200 m 2 /g.

6. A catalyst article for diesel NO, abatement, comprising:
a substrate; and
a washcoat layer coated on the substrate,
wherein the washcoat layer comprises metal-promoted molecular sieves, and
wherein the volumetric zeolitic surface area of the catalyst article is about 900 m 2 /in 3 or greater.

7. The catalyst article of claim 6 , wherein the volumetric zeolitic surface area of the catalyst article is about 1000 m 2 /in 3 or greater.

8. The catalyst article of claim 6 , wherein the volumetric zeolitic surface area of the catalyst article is about 1500 m 2 /in 3 or greater.

9. The catalyst article of claim 6 , wherein the volumetric zeolitic surface area of the catalyst article is about 900 m 2 /in 3 to about 5100 m 2 /in 3 .

10. The catalyst article of claim 6 , wherein the volumetric zeolitic surface area of the catalyst article is about 1100 m 2 /in 3 to about 2300 m 2 /in 3 .

11. The catalyst article of claim 6 , wherein the volumetric zeolitic surface area of the catalyst article is about 1500 m 2 /in 3 to about 2300 m 2 /in 3 .

12. A catalyst article for diesel NO, abatement, comprising:
a substrate; and
a washcoat layer coated on the substrate,
wherein the washcoat layer comprises metal-promoted molecular sieves, and
wherein the total zeolitic surface area (tZSA) of the catalyst article is about 1200 m 2 or greater.

13. The catalyst article of claim 12 , wherein the tZSA of the catalyst article is about 1500 m 2 or greater.

14. The catalyst article of claim 12 , wherein the tZSA of the catalyst article is about 2000 m 2 or greater.

15. The catalyst article of claim 12 , wherein the tZSA of the catalyst article is about 2200 m 2 or greater.

16. The catalyst article of claim 12 , wherein the tZSA of the catalyst article is about 1000 to about 6600 m 2 .

17. The catalyst article of claim 12 , wherein the tZSA of the catalyst article is about 1500 m 2 to about 3000 m 2 .

18. The catalyst article of clai 2 , wherein the tZSA of the catalyst article is about 2000 m 2 to about 3000 m 2 .

19. The catalyst article of claim 1 , wherein the metal-promoted molecular sieves comprise copper-promoted molecular sieves.

20. The catalyst article of claim 19 , wherein the copper-promoted molecular sieves comprise about 0.1 wt. % or more copper, calculated as copper oxide.

21. The catalyst article of claim 19 , wherein the copper-promoted molecular sieves comprise about 0.1 wt. % to about 7 wt. % copper, calculated as copper oxide.

22. The catalyst article of claim 1 , wherein the metal-promoted molecular sieves comprise molecular sieves promoted with copper and a second, different metal.

23. The catalyst article of claim 22 , wherein the second, different metal is selected from the group consisting of iron, cerium, zinc, strontium, and calcium.

24. The catalyst article of claim 1 , wherein the metal-promoted molecular sieves comprise copper- and iron-promoted molecular sieves.

25. The catalyst article of claim 1 , wherein the metal-promoted molecular sieves have a zeolitic structure type selected from the group consisting of AEI, AFT, AFV, AFX, AVL, CHA, DDR, EAB, EEI, ERI, IFY, IRN, KFI, LEV, LTA, LTN, MER, MWF, NPT, PAU, RHO, RTE, RTH, SAS, SAT, SAV, SFW, TSC, UFI, and combinations thereof.

26. The catalyst article of claim 1 , wherein the metal-promoted molecular sieves have a zeolitic structure type of CHA.

27. The catalyst article of claim 26 , wherein the CHA structure type is selected from the group consisting of SSZ-13, SSZ-62, natural chabazite, zeolite K-G, Linde D, Linde R, LZ-218, LZ-235, LZ-236, ZK-14, SAPO-34, SAPO-44, SAPO-47, and ZYT-6.

28. The catalyst article of claim 1 , wherein the washcoat layer is present with a loading of about 0.5 g/in 3 to about 6 g/in 3 .

29. The catalyst article of claim 1 , wherein the substrate is a flow-through honeycomb substrate.

30. The catalyst article of claim 1 , wherein the substrate is a wall flow filter substrate.

31. The catalyst article of claim 1 , wherein the catalyst article is effective to provide a NO x conversion of about 70% or greater at 200° C.

32. The catalyst article of claim 1 , wherein the catalyst article is in aged form such that the catalyst article has been aged at a temperature of at least 400° C. for at least 2 hours.

Assignees

• Basf Corp

Inventors

• Petrovic Ivan
• Mohanan Jaya L
• Petenko Joseph J

Classifications

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• B01J35/615

  100-500 m2/g · CPC title

• B01J35/617

  500-1000 m2/g · CPC title

• B01J35/618

  more than 1000 m2/g · CPC title

• B01J29/763 Primary

  CHA-type, e.g. Chabazite, LZ-218 · CPC title