Encased polymer nanofiber-based electronic nose

Patent metadata

Field	Value
Publication number	US-11714075-B2
Application number	US-202017032614-A
Country	US
Kind code	B2
Filing date	Sep 25, 2020
Priority date	Dec 21, 2012
Publication date	Aug 1, 2023
Grant date	Aug 1, 2023

Abstract

A chemical sensor and a system and method for sensing a chemical species. The chemical sensor includes a plurality of nanofibers whose electrical impedance varies upon exposure to the chemical species, a substrate supporting and electrically isolating the fibers, a set of electrodes connected to the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured, and a membrane encasing the fibers and having a thickness ranging from 50 μm to 5.0 mm. The system includes the chemical sensor, an impedance measuring device coupled to the electrodes and configured to determine an electrical impedance of the plurality of fibers, and an analyzer configured to identify the chemical species based on a change in the electrical impedance.

First claim

The invention claimed is:

1. A chemical wearable sensor comprising:
at least one chemical sensor integrated with a fabric, the at least one chemical sensor configured for collection and identification of a chemical identity of at least one liquid droplet incident on the at least one chemical sensor, the at least one chemical sensor having,
a plurality of sensing fibers disposed with the fabric,
a set of electrodes connected to the plurality of sensing fibers at spatially separated points to permit an electrical impedance of a circuit connected to the plurality of sensing fibers to be measured, and
a protective membrane encasing the plurality of sensing fibers, having a thickness which prevents damage from physical contact, holding the at least one liquid droplet apart from the plurality of sensing fibers, and allowing chemical species from the at least one liquid droplet to selectively penetrate through the protective membrane,
wherein
a lateral space exists between each of the electrodes,
the protective membrane non-conformally bridges over lateral space between the electrodes, and
the protective membrane separates the at least one liquid droplet from the set of electrodes.

2. The sensor of claim 1 , further comprising:
a processor in communication with a circuit connected to the plurality of sensing fibers, and configured to:
measure a response in the electrical impedance from the set of electrodes in the presence of the at least one liquid droplet; and
determine from the response the chemical identity of the at least one liquid droplet.

3. The sensor of claim 1 , wherein the fabric comprises antibacterial fibers including photocatalytic compounds which, when activated by light, produce biocidal free-radical species.

4. The sensor of claim 1 , wherein the fabric comprises photocatalytic compounds and the plurality of sensing fibers comprise fibers transparent to light.

5. The sensor of claim 1 , wherein the fabric comprises a textile having the plurality of sensing fibers integrated into the textile.

6. The sensor of claim 5 , wherein the textile comprises a multi-layered fabric.

7. The sensor of claim 1 , wherein the fabric comprises catalytic compounds comprising at least one of titania and silver.

8. The sensor of claim 1 , wherein the fabric comprises catalytic compounds comprising nanoparticulate metal and metal oxide nanoparticles.

9. The sensor of claim 1 , wherein the plurality of sensing fibers comprise electrically conductive fibers.

10. The sensor of claim 9 , wherein the electrically conductive fibers comprise gas-absorbing fibers.

11. The sensor of claim 1 , wherein the plurality of sensing fibers comprise nanofibers having an average fiber diameter less than 1000 nm or less than 100 nm.

12. The sensor of claim 1 , wherein the plurality of sensing fibers have an electrical impedance which changes due to at least one of an increase in volumetric size of the sensing fibers by sorption of the chemical species or a change in electrical conduction by a chemical reaction of the chemical species with a material of the sensing fibers.

13. The sensor of claim 1 , wherein the protective membrane comprises a disposable membrane.

14. The sensor of claim 1 , wherein the protective membrane comprises fibers embedded therein which are separate from the plurality of sensing fibers.

15. A chemical wearable sensor comprising:
at least one chemical sensor integrated with a fabric, the at least one chemical sensor configured for collection and identification of a chemical identity of at least one liquid droplet incident on the at least one chemical sensor, the at least one chemical sensor having,
a plurality of sensing fibers disposed with the fabric,
a set of electrodes connected to the plurality of sensing fibers at spatially separated points to permit an electrical impedance of a circuit connected to the plurality of sensing fibers to be measured, and
a protective membrane encasing the plurality of sensing fibers, having a thickness which prevents damage from physical contact, holding the at least one liquid droplet apart from the plurality of sensing fibers, and allowing chemical species from the at least one liquid droplet to selectively penetrate through the protective membrane, wherein the thickness of the protective membrane ranges from 50 μm to 5 mm.

16. The sensor of claim 15 , wherein the at least one chemical sensor comprises an array of chemical sensors comprising a first gas permeable sensor and a second gas permeable sensor.

17. The sensor of claim 16 , wherein
the first gas permeable sensor and the second gas permeable sensor comprise a stack of sensors serially stacked on top of each other with the protective membrane above the stack,
the first gas permeable sensor comprises a plurality of first sensing fibers and a first set of first electrodes connected to the plurality of first sensing fibers, and
the second gas permeable sensor comprises a plurality of second sensing fibers and a second set of second electrodes connected to the plurality of second sensing fibers.

18. The sensor of claim 17 , wherein
the first set of first electrodes of the first gas permeable sensor are disposed on top of the second set of second electrodes, and
the first electrodes of the first set of first electrodes have an orientation rotated around a top-to-bottom direction of the stack from the second electrodes of the second set of second electrodes of the second gas permeable sensor.

19. The sensor of claim 15 , wherein
the protective membrane directly contacts both the electrodes and the plurality of sensing fibers, and
the set of electrodes are disposed directly on the sensing fibers with the protective membrane disposed directly on the electrode.

20. A chemical sensor comprising:
at least one chemical sensor integrated with a substrate, the at least one chemical sensor configured for collection and identification of a chemical identity of at least one liquid droplet incident on the at least one chemical sensor, the at least one chemical sensor having,
a plurality of sensing fibers disposed with the substrate,
a set of electrodes connected to the plurality of sensing fibers at spatially separated points to permit an electrical impedance of a circuit connected to the plurality of sensing fibers to be measured, and
a protective membrane encasing the plurality of sensing fibers, having a thickness which prevents damage from physical contact, holding the at least one liquid droplet apart from the plurality of sensing fibers, and allowing chemical species from the at least one liquid droplet to selectively penetrate through the protective membrane,
wherein
a lateral space exists between each of the electrodes,
the protective membrane non-conformally bridges over lateral space between the electrodes, and
the protective membrane separates the at least one liquid droplet from the set of electrodes.

Assignees

• Res Triangle Inst

Inventors

• Ensor David S
• Han Li

Classifications

• G01N33/0047 Primary

  Organic compounds · CPC title

• G01N27/127

  comprising nanoparticles · CPC title

• G01N27/227

  Sensors changing capacitance upon adsorption or absorption of fluid components, e.g. electrolyte-insulator-semiconductor sensors, MOS capacitors (G01N27/225 takes precedence) · CPC title

• B82Y30/00 Primary

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title