Method of making a grease thickener and the thickener made by the method

Patent metadata

Field	Value
Publication number	US-11713431-B2
Application number	US-202217741982-A
Country	US
Kind code	B2
Filing date	May 11, 2022
Priority date	Jun 28, 2018
Publication date	Aug 1, 2023
Grant date	Aug 1, 2023

Abstract

A continuous process for producing a polyurea concentrate or powder. The process includes combing at least one amine and an isocayante in the presence of a liquid diluent or a base oil in a rotor stator mixer. The concentrate comprises a polyurea in a base oil wherein the concentration of from about 20 weight percent to about 50, or 40 or 35 or 30 weight percent of polyurea based on total weight of grease thickener. The powder has particle size of 2 to 400 microns. This concentrate or powder can then be formulated by grease manufacturers to the desired final properties without the need for handling of the isocyanate and amine raw materials.

First claim

What is claimed is:

1. A process comprising providing at least one amine and a first base oil to a rotor stator mixer which is operating at a shear rate of less than 5000 reciprocal seconds (l/sec), adding a isocyanate to the rotor stator mixer in a shear zone of the rotor stator mixer and in a position located at a distance from an outlet of the rotor stator mixer that is not more than half the diameter of the rotor stator mixer such that a residence time in the mixer after addition of the isocyanate is less than 20 seconds to produce a grease thickener concentrate comprising a polyurea.

2. The process of claim 1 characterized in that the process is continuous.

3. The process of claim 1 wherein the at least one amine is a mixture comprising a first linear primary amine having six to eighteen carbon atoms and either a second linear primary amine having six to eighteen carbon atoms and being different from the first linear primary amine or a cyclic primary amine.

4. The process of claim 1 wherein the residence time is less than 10 seconds.

5. The process of claim 1 wherein the residence time is less than 5 seconds.

6. The process of claim 1 wherein the at least one amine is a primary amine and the isocyanate is a di-isocyanate such that the polyurea formed is a diurea.

7. The process of claim 1 wherein the at least one amine comprises an alkylamine and a fatty amine.

8. The process of claim 1 wherein the grease thickener concentrate comprises at least 20 weight percent of the polyurea based on total weight of the grease thickener concentrate.

9. The process of claim 1 wherein the first base oil is selected from API Groups I, II, III, IV or V.

10. The process of claim 1 further comprising diluting the grease thickener concentrate with a second base oil and adding an additive selected from antioxidants; antiwear compounds; extreme pressure compounds, rust and corrosion inhibitors; tackifiers; detergents; dispersants; antifoaming additives; and combinations thereof to form a grease.

11. The process of claim 10 wherein the second base oil is the same as the first base oil.

12. A process for preparing a polyurea compound comprising reacting an amine and a polyisocyanate in the presence of a liquid diluent in a rotor stator mixer under conditions sufficient to produce a dispersion of the polyurea compound in the liquid diluent wherein the polyisocyanate is fed to the rotor stator mixer at a distance that is no more than half the diameter of the rotor stator mixer from an outlet of the rotor stator mixer and directly into a shear zone of the rotor stator mixer to form a polyurea.

13. The process of claim 12 further comprising recovering the polyurea in a dry, solid particulate form.

14. A method of forming a grease comprising mixing a base lubricating oil and a polyurea prepared by the process of claim 13 to form a mixture; heating the mixture to a temperature in the range of from 150° C. to 180° C.; and thereafter milling the heated mixture to form a homogenized grease.

15. The process of claim 13 wherein the solid particulate form has an average particle size of 2 to 400 microns.

Assignees

• Dow Global Technologies Llc

Inventors

• Jia Zhe
• Cuthbert John B
• Malotky David L
• Saba Stacey A
• Hook Bruce D
• Wilmot Nathan
• Dermody Daniel L

Classifications

• C10M115/08 Primary

  containing nitrogen · CPC title

• C08G18/095

  oligomerisation to carbodiimide or uretone-imine groups · CPC title

• C08G18/2865

  Compounds having only one primary or secondary amino group; Ammonia · CPC title

• C08J3/092

  Hydrocarbons · CPC title

• C10M119/24 Primary

  containing nitrogen · CPC title