Single packaged air separation apparatus with reverse main heat exchanger

Patent metadata

Field	Value
Publication number	US-11709018-B2
Application number	US-201716958037-A
Country	US
Kind code	B2
Filing date	Dec 25, 2017
Priority date	Dec 25, 2017
Publication date	Jul 25, 2023
Grant date	Jul 25, 2023

Abstract

A cryogenic air separation setup in a cold box, wherein gaseous oxygen under elevated pressure is produced through hydraulic force caused by the geodetic distance between where liquid oxygen is drawn from the distillation column and where liquid oxygen is vaporized to form gaseous oxygen, such as in an auxiliary evaporator. To increase the vertical distance between the above-mentioned two location, the components are arranged directly below one another in the following sequence: the lower-pressure column, the main condenser evaporator, the higher-pressure column, the subcooler, the main heat exchanger and the auxiliary evaporator). In particular, the main heat-exchanger is positioned with the cold-end on the top to optimize piping expenditure.

First claim

The invention claimed is:

1. An air separation apparatus comprising:
(a) a first column, a main condenser evaporator and a second column, wherein the second column surmounts the first column and the first column and the second column are thermally connected by the main condenser evaporator, wherein the first column is operated at a higher pressure than the second column;
(b) an auxiliary evaporator having a liquefaction space and a vaporization space, the auxiliary evaporator being disposed below the bottom of the second column;
(c) a main heat exchanger being disposed in between the first column and the auxiliary evaporator for indirect heat exchange between the compressed and purified feed air stream and return gaseous streams from the second column, the main heat exchanger having a warm end and a cold end;
(d) means for introducing a compressed and purified feed air stream into at least the first column after cooling in the main heat exchanger;
(e) means for introducing at least a fraction from the first column into the second column;
(f) means for transporting a liquid oxygen stream from the main condenser evaporator into the vaporization space of the auxiliary evaporator, wherein at least part of the vaporized gaseous oxygen stream is warmed up in the main heat exchanger to form gaseous oxygen product and the remaining liquid oxygen stream is withdrawn as liquid oxygen product; and
(g) means for providing refrigeration to the air separation apparatus;
wherein the main heat exchanger is configured such that the return gaseous streams enter from the cold end at the top, and exit from the warm end at the bottom of the main heat exchanger.

2. The air separation apparatus of claim 1 , further comprising a subcooler disposed in between the first column and the main heat exchanger, wherein the return gaseous streams undergo heat exchange with liquid streams passed from the first column, then said return gaseous streams enter into the cold end at the top of the main heat exchanger.

3. The air separation apparatus of claim 2 , further comprising means for introducing a first part of feed air stream into the liquefaction space of the auxiliary evaporator and after partial or total condensation therein, further into a phase separator for separation into a gaseous feed air stream and a liquid feed air stream.

4. The air separation apparatus of claim 3 , wherein the means for providing refrigeration to the air separation apparatus further comprises a turbine expander configured to expand a second part of feed air stream before the second part of feed air stream enters into the first column or the second column in order to provide refrigeration to the air separation apparatus.

5. The air separation apparatus of claim 1 , wherein the second column, the main condenser evaporator, the first column, optionally the subcooler, the main heat exchanger and the auxiliary evaporator are housed in one cold box.

6. A process for producing gaseous oxygen product under elevated pressure in the air separation apparatus according to claim 1 , comprising:
(a) cooling the compressed and purified feed air stream in the main heat exchanger through indirect heat exchange with return gaseous streams from the second column followed by introducing at least part of the compressed and purified feed air stream into the first column;
(b) separating the gaseous feed air stream into oxygen-rich liquid at the bottom of the first column and transporting said oxygen-rich liquid into the second column to form a bottom liquid and waste nitrogen;
(c) condensing a gaseous nitrogen from the top of the first column against bottom liquid from the second column in the main condenser evaporator to form reflux for the first column and liquid oxygen;
(d) withdrawing liquid oxygen from the main condenser evaporator into the vaporization space of the auxiliary evaporator, wherein at least part of the vaporized gaseous oxygen stream is warmed up in the main heat exchanger to form gaseous oxygen product and the remaining liquid oxygen stream is withdrawn as liquid oxygen product; and
(e) providing refrigeration to the air separation apparatus through expanding at least part of the compressed and purified feed air stream in a turbine expander before introducing it into the second column or optionally through external source.

7. The process of claim 6 , wherein the compressed and purified feed air stream is divided into at least a first part of feed air stream and a second part of feed air stream in the main heat exchanger, the first part of feed air stream being delivered into the liquefaction space of the auxiliary evaporator to be partially or totally condensed and further delivered into a phase separator for separation into the gaseous feed air stream and a liquid feed air stream, and the gaseous feed air stream being fed into the first column and the liquid feed air stream being fed into the second column.

8. The process of claim 6 , wherein a liquid nitrogen and a lean liquid are removed from the first column and transported into the second column.

9. The process of claim 8 , wherein low pressure gaseous nitrogen is withdrawn from the second column.

10. The process of claim 9 , wherein the liquid feed air stream, the oxygen-rich liquid, the lean liquid and the liquid nitrogen are subcooled in a subcooler against return gaseous streams including waste nitrogen and optionally low pressure gaseous nitrogen before being introduced into the second column.

Assignees

• Briglia Alain
• Kurtz Remy
• Day Eric
• Xie Huali
• Fara Baptiste
• Air Liquide
• Lair Liquide Sa Pour Letude Et Lexpoitation Des Procedes Georges Claude

Inventors

• Briglia Alain
• Kurtz Remy
• Day Eric
• Xie Huali
• Fara Baptiste

Classifications

• F25J3/0409 Primary

  of oxygen · CPC title

• F25J3/04206

  including a so-called "auxiliary vaporiser" for vaporising and producing a gaseous product · CPC title

• F25J3/04303

  Lachmann expansion, i.e. expanded into oxygen producing or low pressure column · CPC title

• F25J3/04412 Primary

  in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column · CPC title

• F25J2250/40

  One fluid being air · CPC title