Process for managing hydrogen sulfide in a refinery

Patent metadata

Field	Value
Publication number	US-11708267-B2
Application number	US-202117547969-A
Country	US
Kind code	B2
Filing date	Dec 10, 2021
Priority date	Dec 18, 2020
Publication date	Jul 25, 2023
Grant date	Jul 25, 2023

Abstract

A process and apparatus for managing hydrogen sulfide in a refinery is provided. In the process, a hydrogen sulfide stream from said refinery is fed to a sulfur recovery unit to produce sulfur and a sulfur compound stream or to a thermal oxidizer. The sulfur compound stream and the hydrogen sulfide stream are then thermally oxidized to produce a sulfur oxide stream. The sulfur oxide stream is then reacted with an ammonia stream. In aspect, the product of the reaction can be a fertilizer. The ammonia stream can be obtained from stripping the hydrogen sulfide stream.

First claim

The invention claimed is:

1. A process for managing hydrogen sulfide in a refinery comprising:
thermally oxidizing a first hydrogen sulfide stream from said refinery to produce a sulfur oxide stream;
reacting said sulfur oxide stream with an ammonia stream;
feeding a second hydrogen sulfide stream from said refinery to a sulfur recovery unit to produce sulfur and a sulfur compounds stream; and
thermally oxidizing said sulfur compounds stream with said hydrogen sulfide stream.

2. The process of claim 1 further comprising taking one of said first hydrogen sulfide stream and said second hydrogen sulfide stream from a sour water stripper and/or a solvent regeneration column.

3. The process of claim 2 wherein said sour water stripper strips hydrogen sulfide from a sour water stream to provide said first hydrogen sulfide stream and a hydrogen sulfide lean stream comprising said ammonia stream.

4. The process of claim 3 further comprising thermally oxidizing said reacted stream to provide a second flue gas stream comprising sulfur oxide.

5. The process of claim 3 further comprising stripping ammonia from said hydrogen sulfide lean stream to provide said ammonia stream.

6. The process of claim 5 further comprising thermally oxidizing said reacted stream to provide a second flue gas stream comprising sulfur oxide.

7. The process of claim 6 further comprising reacting an adsorbent with sulfur oxides in said second flue gas stream to provide a sulfate salt and removing said sulfate salt from said second flue gas.

8. The process of claim 3 further comprising reacting remnant NOx in a reacted flue gas stream from said reacting step with ammonia from said sour water stripper to produce molecular nitrogen.

9. The process of claim 1 further comprising passing said sulfur compounds stream comprising carbon sulfides to said thermal oxidizing step.

10. The process of claim 1 further comprising combusting hydrogen sulfide in the sulfur recovery unit to produce elemental sulfur, condensing the elemental sulfur from the flue gas to provide the sulfur compounds stream and thermally oxidizing the sulfur compounds stream.

11. The process of claim 1 further comprising combusting a fuel stream from said refinery to generate heat for said thermal oxidizing step.

12. The process of claim 11 wherein said fuel stream is taken from a pressure swing adsorption tail gas and/or from an off-gas stream from a fractionation column in a hydroprocessing unit.

13. The process of claim 1 further comprising reducing the temperature of said sulfur oxide stream by heat exchange before it is reacted with said ammonia stream.

14. The process of claim 13 further comprising quenching said sulfur oxide stream with water from a sour water stripper.

15. The process of claim 1 further comprising reacting remnant NOx in a reacted flue gas stream from said reacting step with ammonia to produce molecular nitrogen.

16. The process of claim 1 further comprising feeding a third hydrogen sulfide stream to a sulfidation reaction in which ammonium bisulfite from said reacting step is sulfided with hydrogen sulfide from said third hydrogen sulfide stream to produce ammonium thiosulfate.

17. The process of claim 1 wherein said reacting step produces a product of ammonium sulfate and drying said product with an air stream and returning said air stream upstream of the reacting step.

18. The process of claim 17 further comprising returning said air stream to said thermal oxidizing step.

19. The process of claim 18 wherein said drying step includes a water separation step and further comprising spraying an oxidation agent into the water separation step to oxidize residual hydrogen sulfide.

20. A process for managing hydrogen sulfide in a refinery comprising:
stripping hydrogen sulfide from a sour water stream from said refinery to provide a hydrogen sulfide rich stream and a hydrogen sulfide lean stream comprising ammonia;
feeding said hydrogen sulfide rich stream to a sulfur recovery unit to produce sulfur and a sulfur compounds stream, wherein said hydrogen sulfide rich stream has less than 10 mol % ammonia;
thermally oxidizing said hydrogen sulfide stream to produce a sulfur oxide stream; and
reacting said sulfur oxide stream with the hydrogen sulfide lean stream to produce a reacted flue gas stream.

21. The process of claim 20 further comprising stripping ammonia from said hydrogen sulfide lean stream to provide said ammonia stream.

22. The process of claim 21 further comprising reacting said sulfur oxide stream with ammonia in a first ammonia stream and reacting remnant NOx in said reacted flue gas stream with ammonia in a second ammonia stream to produce molecular nitrogen and either or both of said first ammonia stream and said second ammonia stream can be taken from said hydrogen sulfide lean stream.

23. The process of claim 20 further comprising feeding a second hydrogen sulfide stream from said refinery to a sulfur recovery unit to produce sulfur and a sulfur compounds stream; and
thermally oxidizing said sulfur compounds stream with said hydrogen sulfide stream.

24. A process for producing fertilizer in a refinery comprising:
feeding a hydrogen sulfide stream from said refinery to a sulfur recovery unit to produce sulfur and a sulfur compounds stream, wherein said hydrogen sulfide stream has less than 10 mol % ammonia;
thermally oxidizing said sulfur compounds stream comprising carbon sulfides to produce a sulfur oxide stream; and
reacting said sulfur oxide stream with an ammonia stream.

25. The process of claim 24 further comprising taking said hydrogen sulfide stream from a sour water stripper and/or an amine regeneration unit.

Assignees

• Uop Llc

Inventors

• De Ren Jan
• Wang Haiyan
• Alves Joao Jorge Da Silva Ferreira
• Clarke Ian
• Whyman William J

Classifications

• B01D53/96

  Regeneration, reactivation or recycling of reactants · CPC title

• B01D53/75

  Multi-step processes · CPC title

• C01B17/0408 Primary

  Pretreatment of the hydrogen sulfide containing gases · CPC title

• B01D53/047

  Pressure swing adsorption · CPC title

• C01B17/501

  by reduction of sulfur compounds · CPC title