Ionic Liquid-based Absorption Cooling System with High Coefficient of Performance
US-2018259229-A1 · Sep 13, 2018 · US
US11703266B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11703266-B2 |
| Application number | US-201716612650-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 11, 2017 |
| Priority date | May 11, 2017 |
| Publication date | Jul 18, 2023 |
| Grant date | Jul 18, 2023 |
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A cooling system and a related method is presented. The cooling system includes a reservoir configured to selectively supply a cooling fluid; a circulation loop fluidly coupled to the reservoir, and configured to circulate the cooling fluid to and from the reservoir, and a heat exchanger thermally coupled to the circulation loop and configured to exchange heat with the cooling fluid. The reservoir includes a refrigerant and an anti-freeze additive. The anti-freeze additive is characterized by a lower critical solution temperature (LCST) such that when an operating temperature of the reservoir is greater than the LCST, the reservoir is configured to supply a cooling fluid including the refrigerant to the circulation loop; and when the operating temperature of the reservoir is lower than the LCST, the reservoir is configured to supply a cooling fluid including the refrigerant and the anti-freeze additive to the circulation loop.
Opening claim text (preview).
What is claimed is: 1. A cooling system, comprising: a steam turbine; a condenser that receives a flow of steam from the steam turbine; an evaporator; a reservoir disposed in the evaporator and configured to selectively supply a cooling fluid, the reservoir including a first outlet disposed proximate a top end of the reservoir and a second outlet disposed proximate a bottom end of the reservoir, the first outlet fluidly coupled to a first outlet valve and the second outlet fluidly coupled to a second outlet valve, wherein the reservoir comprises a refrigerant and an anti-freeze additive, the anti-freeze additive characterized by a lower critical solution temperature (LCST), wherein the first outlet valve is configured to open and the second outlet valve is configured to close when a reservoir operating temperature is greater than the LCST, wherein the first outlet valve is configured to close and the second outlet valve is configured to open when the reservoir operating temperature is less than the LCST; a circulation loop fluidly coupled to the reservoir, and configured to circulate the cooling fluid to and from the reservoir; an agitator disposed within the reservoir and configured to mix the refrigerant and the anti-freeze additive when the reservoir operating temperature is less than the LCST, and wherein the agitator is configured to turn off when the reservoir operating temperature is greater the LCST; and a heat exchanger thermally coupled to the circulation loop and configured to exchange heat between the cooling fluid and the flow of steam in the condenser; wherein when the reservoir operating temperature is greater than the LCST, the reservoir is configured to supply a first mixture of the cooling fluid comprising the refrigerant and less than 5 weight percent of the anti-freeze additive to the circulation loop; and when the reservoir operating temperature is lower than the LCST, the reservoir is configured to supply a second mixture of the cooling fluid comprising the refrigerant and between about 5 weight percent and about 60 weight percent of the anti-freeze additive to the circulation loop. 2. The cooling system of claim 1 , wherein when the reservoir operating temperature is lower than the LCST, the refrigerant and the anti-freeze additive are present in the reservoir as a substantially miscible phase, and when the reservoir operating temperature is greater than the LCST, the refrigerant and the anti-freeze additive are present in the reservoir as substantially immiscible phases. 3. The cooling system of claim 1 , wherein the LCST of the anti-freeze additive is in a range from about 1° C. to about 60° C. 4. The cooling system of claim 1 , wherein the anti-freeze additive comprises amines, polyalkylene glycols, polyamines, ionic liquids, or combinations thereof. 5. The cooling system of claim 1 , wherein the anti-freeze additive and the refrigerant have a density difference greater than 30 kg/m 3 . 6. The cooling system of claim 1 , wherein the reservoir is configured to supply the cooling fluid to the circulation loop via the first outlet. 7. The cooling system of claim 1 , wherein the reservoir is configured to supply the cooling fluid to the circulation loop via the second outlet. 8. The cooling system of claim 1 , wherein the reservoir is disposed directly downstream of the heat exchanger such that the reservoir is configured to receive a heated cooling fluid from the heat exchanger. 9. The cooling system of claim 1 , wherein the circulation loop is configured to circulate a portion of the cooling fluid into the heat exchanger and a remaining portion of the cooling fluid is circulated directly into the reservoir. 10. The cooling system of claim 1 , further comprising a heat rejection device thermally coupled to the circulation loop, the heat rejection device configured to cool the cooling fluid before the cooling fluid exchanges heat with the heat exchanger. 11. A method of cooling using a cooling system comprising a steam turbine, a condenser that receives a flow of steam from the steam turbine, an evaporator, a reservoir disposed in the evaporator, a circulation loop, and a heat exchanger, wherein the reservoir comprises a refrigerant and an anti-freeze additive, the anti-freeze additive characterized by a lower critical solution temperature (LCST), the method comprising: selectively supplying a cooling fluid from the reservoir to the circulation loop, such that when a reservoir operating temperature is greater than the LCST, a first mixture of the cooling fluid comprising the refrigerant and less than 5 weight percent of the anti-freeze additive is supplied to the circulation loop; and when the reservoir operating temperature is lower than the LCST, a second mixture of the cooling fluid comprising the refrigerant and between about 5 weight percent and about 60 weight percent of the anti-freeze additive is supplied to the circulation loop; operating an agitator disposed within the reservoir to mix the refrigerant and the anti-freeze additive when the reservoir operating temperature is less than the LCST and turning off the agitator when the reservoir operating temperature is greater the LCST; circulating the cooling fluid via the circulation loop from the reservoir to the heat exchanger by opening one of a first outlet valve or a second outlet valve and leaving the other of the first outlet valve or the second outlet valve closed, the first outlet valve fluidly coupled to a first outlet that is disposed proximate to a top end of the reservoir, the second outlet valve fluidly coupled to a second outlet that is disposed proximate to a bottom end of the reservoir, wherein the first outlet valve is open and the second outlet valve is closed when the reservoir operating temperature is greater than the LCST, wherein the first outlet valve is closed and the second outlet valve is open when the reservoir operating temperature is less than the LCST, and wherein the cooling fluid exchanges heat with the flow of steam within the condenser via the heat exchanger; and circulating the cooling fluid from the heat exchanger to the reservoir via the circulation loop. 12. The method of claim 11 , wherein when the reservoir operating temperature is lower than the LCST, the refrigerant and the anti-freeze additive are present in the reservoir as a substantially miscible phase, and when the reservoir operating temperature is greater than the LCST, the refrigerant and the anti-freeze additive are present in the reservoir as substantially immiscible phases. 13. An absorption cycle apparatus, comprising: a steam turbine; a condenser that receives a flow of steam from the steam turbine; and an evaporator; a reservoir disposed in the evaporator and configured to selectively supply a cooling fluid, the reservoir including a first outlet disposed proximate a top end of the reservoir and a second outlet disposed proximate a bottom end of the reservoir, the first outlet fluidly coupled to a first outlet valve and the second outlet fluidly coupled to a second outlet valve, wherein the reservoir comprises a refrigerant and an anti-freeze additive, the anti-freeze additive characterized by a lower critical solution temperature (LCST), wherein the first outlet valve is configured to open and the second outlet valve is configured to close when a reservoir operating temperature is greater than the LCST, wherein the first outlet valve is configured to close and the second outlet valve is configured to open when the reservoir operating temperature is less than the LCST; a circulation loop fluidly coupled to the reservoir, and configured to circulate the cooling fluid to an
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