Process for regeneration of hydrogenation catalysts

Patent metadata

Field	Value
Publication number	US-11701649-B2
Application number	US-202117543261-A
Country	US
Kind code	B2
Filing date	Dec 6, 2021
Priority date	Dec 18, 2020
Publication date	Jul 18, 2023
Grant date	Jul 18, 2023

Abstract

The invention provides a process for regenerating a catalyst used for the ring hydrogenation of an aromatic species, especially an aromatic ester, wherein a gas stream containing a particular amount of oxygen is used for the regeneration.

First claim

The invention claimed is:

1. A process for regenerating a catalyst used for the ring hydrogenation of an aromatic species in at least one reactor, wherein the regeneration is conducted
by passing a gas stream having an oxygen content of 100 ppm to 9,000 ppm over the catalyst to be regenerated;
at a temperature of from 15 to 170° C.; and
without removing the catalyst from the at least one reactor.

2. The process according to claim 1 , wherein the gas stream has an oxygen content of from 250 ppm to 9,000 ppm.

3. The process according to claim 2 , wherein the regeneration is conducted at a temperature of from 25° C. to 150° C.

4. The process according to claim 2 , wherein the catalyst comprises at least one transition metal on a support material.

5. The process according to claim 2 , wherein the gas stream is an inert gas.

6. The process according to claim 1 , wherein the gas stream has an oxygen content of from 380 ppm to 9000 ppm.

7. The process according to claim 1 , wherein the regeneration is conducted at a temperature of from 25° C. to 150° C.

8. The process according to claim 1 , wherein the catalyst comprises at least one transition metal on a support material.

9. The process according to claim 5 , wherein the at least one transition metal is a metal selected from the group consisting of iron, ruthenium, nickel, rhodium, platinum, palladium and mixtures thereof.

10. The process according to claim 8 , wherein the support material is selected from the group consisting of activated carbon, silicon carbide, aluminium oxide, silicon dioxide, aluminosilicate, titanium dioxide, zirconium dioxide, magnesium oxide, zinc oxide and mixtures thereof.

11. The process according to claim 8 , wherein the catalyst used is an eggshell catalyst.

12. The process according to claim 1 , wherein the gas stream is an inert gas selected from the group consisting of nitrogen, helium, neon, argon, carbon dioxide and mixtures thereof.

13. The process according to claim 1 , wherein the aromatic species is an aromatic ester.

14. The process according to claim 13 , wherein the aromatic ester is an ester of a benzenecarboxylic acid, of a benzenedicarboxylic acid, of a benzenetricarboxylic acid or of a benzenetetracarboxylic acid.

15. The process according to claim 14 , wherein the aromatic ester is a C8- to C10-alkyl ester of phthalic acid or a C8- to C10-alkyl ester of terephthalic acid.

16. The process according to claim 10 , wherein the aromatic ester is an ester of benzenedicarboxylic acid or of benzenetricarboxylic acid.

17. The process according to claim 10 , wherein the aromatic ester is an ester of benzenedicarboxylic acid.

18. The process according to claim 1 , wherein the regeneration is conducted at a pressure in the range from 0.5 to 200 bar.

19. The process according to claim 1 , wherein the duration of the regeneration is at least 24 hours.

20. The process according to claim 1 , wherein the gas stream in the regeneration is guided over the catalyst in the same flow direction, based on the flow direction in the hydrogenation.

21. The process according to claim 1 , wherein the gas stream in the regeneration is guided over the catalyst in the reverse flow direction, based on the flow direction in the hydrogenation.

Assignees

• Evonik Operations Gmbh

Inventors

• Kraft Johannes
• Altmann Lena
• Anton Johan
• Grass Michael

Classifications

• B01J38/04 Primary

  Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst · CPC title

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title

• B01J23/462

  Ruthenium · CPC title

• B01J35/008

  Operations & Transport · mapped topic

• B01J38/02 Primary

  Heat treatment · CPC title