Plant health compositions comprising a water-soluble pesticide and a water-insoluble agrochemical

Patent metadata

Field	Value
Publication number	US-11700853-B2
Application number	US-202016896827-A
Country	US
Kind code	B2
Filing date	Jun 9, 2020
Priority date	Mar 12, 2010
Publication date	Jul 18, 2023
Grant date	Jul 18, 2023

Abstract

Compositions for improving plant health, the compositions comprising at least one water-soluble pesticide and at least one non-herbicidal water-insoluble agrochemical, are described. Also described are processes for preparing the compositions and methods of improving agronomic crop plant health using the compositions.

First claim

What is claimed is:

1. A microemulsion concentrate composition comprising (i) an aqueous carrier phase comprising at least one water-soluble pesticide in solution in the carrier phase, wherein the water-soluble pesticide is in the form of a salt, (ii) a surfactant phase comprising (a) a surfactant component comprising at least one surfactant and (b) at least one water-insoluble agrochemical, and (iii) an organic solvent,
wherein the at least one water-insoluble agrochemical is selected from the group consisting of azoxystrobin, beflubutamide, benalaxyl, benalaxyl-M, bromuconazole, clodinafop-propargyl, coumaphos, dinitriamine, dodemorph acetate, fentrazamide, flamprop-M-isopropyl, flamprop-M-methyl, flurochloridone, flutolanil, indanofan, ipconazole, kresoxim-methyl, metconazole, picoxystrobin, pyraclostrobin, tebuconazole, thenylchlor, thiazopyr, quizalofop-p-ethyl, and combinations thereof,
at least 50% by weight of the water-insoluble agrochemical is present as a solute in the surfactant component,
the water-soluble pesticide concentration is at least 400 grams active equivalent per liter of the concentrate composition, and
the weight ratio of the organic solvent to the water-insoluble agrochemical on an active equivalent basis is less than 3:1.

2. The composition of claim 1 wherein the water-soluble pesticide concentration is at least 450 grams active equivalent per liter.

3. The composition of claim 1 wherein the water-insoluble agrochemical concentration is from about 0.1 to about 20 percent by weight active equivalent per unit weight of the microemulsion composition.

4. The composition of claim 1 wherein the weight ratio of the organic solvent to the water-insoluble agrochemical on an active equivalent basis is less than 2.5:1.

5. The composition of claim 1 wherein the weight ratio of the water-soluble pesticide on an active equivalent basis to water-insoluble agrochemical on an active equivalent basis is from about 1:1 to about 100:1.

6. The composition of claim 1 wherein at least 75% by weight of the water-insoluble agrochemical is present as a solute in the surfactant component.

7. The composition of claim 1 wherein the weight ratio of the water-soluble pesticide on an active equivalent basis to the surfactant component is from about 1:1 to about 20:1.

8. The composition of claim 1 wherein the weight ratio of the surfactant component to the water-insoluble agrochemical on an active equivalent basis is from about 2:1 to about 10:1.

9. The composition of claim 1 wherein the water-soluble pesticide comprises at least one water-soluble herbicide.

10. The composition of claim 9 wherein the water-soluble herbicide is selected from the group consisting of ALS or AHAS inhibitors, EPSP inhibitors, glutamine synthetase inhibitors, synthetic auxins, Photosystem I inhibitors, ACCase inhibitors in the form of a salt and combinations thereof.

11. The composition of claim 10 wherein the water-soluble herbicide is selected from the group consisting of glyphosate, dicamba, 2,4-D, MCPA, glufosinate in the form of a salt and combinations thereof.

12. The composition of claim 11 wherein the water-soluble herbicide is glyphosate in the form of a salt.

13. The composition of claim 1 wherein the water-insoluble agrochemical has a molecular weight of from about 100 to about 600 grams per mole and a melting point of from about 45° C. to about 110° C.

14. The composition of claim 1 wherein the water-insoluble agrochemical is tebuconazole or pyraclostrobin.

15. The composition of claim 1 wherein the surfactant component comprises at least one surfactant selected from the group consisting of cationic surfactants, nonionic surfactants, anionic surfactants and amphoteric surfactants.

16. The composition of claim 15 wherein the surfactant is selected from the group consisting of amidoalkylamines, alkoxylated tertiary amines, alkoxylated quaternary amines, alkoxylated tertiary etheramines, alkoxylated quaternary etheramines, alkyl amine oxides, alkylpolyglucosides, alkoxylated alcohols, phosphate esters and siloxanes, and combinations thereof.

17. The composition of claim 1 wherein the cloud point is at least 50° C.

18. The composition of claim 17 having the absence of crystals after storage for 4 weeks at a temperature of −10° C.

19. The composition of claim 1 wherein the water-soluble pesticide comprises a glyphosate salt and the water-insoluble agrochemical comprises tebuconazole or pyraclostrobin.

20. A method of increasing the vigor and/or yield of an agronomic plant and of controlling weeds growing in a crop of the agronomic plants, the method comprising:
forming an application mixture from the compositions of claim 1 ,
wherein the application mixture comprises (i) a water-soluble herbicide selected from the group consisting of organophosphorus herbicides, ALS inhibitor herbicides, synthetic auxin herbicides, ACCase inhibitor herbicides in the form of a salt and combinations thereof and (ii) a water-insoluble agrochemical selected from the group consisting of azoxystrobin, beflubutamide, benalaxyl, benalaxyl-M, bromuconazole, clodinafop-propargyl, coumaphos, dinitriamine, dodemorph acetate, fentrazamide, flamprop-M-isopropyl, flamprop-M-methyl, flurochloridone, flutolanil, indanofan, ipconazole, kresoxim-methyl, metconazole, picoxystrobin, pyraclostrobin, tebuconazole, thenylchlor, thiazopyr, quizalofop-p-ethyl, and combinations thereof, and
applying the application mixture to the agronomic plant or an agronomic plant propagation material from which the agronomic plant can be obtained in an amount effective to increase the vigor and/or yield of the agronomic plant, wherein the agronomic plant has an herbicidal tolerant trait conferring tolerance to the organophosphorus herbicide, ALS inhibitor herbicide, synthetic auxin herbicide, ACCase inhibitor herbicide, or combination thereof.

Assignees

• Monsanto Technology Llc

Inventors

• Abraham William
• Dyszlewski Andrew
• Hemminghaus John W
• Kohn Frank C
• Wright Daniel R
• Zhang Junhua

Classifications

• A01N57/20 Primary

  containing acyclic or cycloaliphatic radicals · CPC title

• A01N25/04 Primary

  Dispersions, {emulsions, suspoemulsions, suspension concentrates} or gels (foams A01N25/16) · CPC title

• A01N43/60

  1,4-Diazines; Hydrogenated 1,4-diazines · CPC title

• A01N43/653

  1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles · CPC title

• A01N2300/00

  Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48 · CPC title