Aqueous electrolyte-containing adjuvant compositions, active ingredient-containing compositions and the use thereof

Patent metadata

Field	Value
Publication number	US-11700852-B2
Application number	US-201515536593-A
Country	US
Kind code	B2
Filing date	Dec 17, 2015
Priority date	Dec 19, 2014
Publication date	Jul 18, 2023
Grant date	Jul 18, 2023

Abstract

The invention relates to adjuvant compositions which contain a) one or more polyalkylene glycol sulfate salts or polyalkylene glycol sulfonate salts, b) water, and c) one or more electrolytes dissociated into ions. Said adjuvant compositions can be preferably used combined with pharmaceutical active ingredients, agrochemical active ingredients, biocides or repellents which have a high electrolyte content.

First claim

The invention claimed is:

1. A spray liquor produced by diluting a concentrate formulation with water, the concentrate formulation comprising:
a) at least one sulfated polyalkylene glycol having the structural formula:
(HO—(CH 2 —CH 2 —O—) n (CH 2 —CH(CH 3 )—O) m —CH 2 —CH 2 —O—SO 2 —O − ) q M q+ ,

in which
n and m are independently in the range of 2 to 40,
q is 1 or 2, and
M is mono- or divalent cation,

wherein the at least one component a) is present in an amount from 2% to 90% by weight, based on the total weight of the concentrate formulation;
b) water; and
c) at least one electrolyte dissociated into ions selected from the group consisting of water-soluble salts of glyphosate and water-soluble salts of glufosinate,

wherein the spray liquor contains at least 0.25 g/L of the at least one sulfated polyalkylene glycol.

2. The spray liquor of claim 1 , further comprising at least one water-insoluble active ingredient d).

3. The spray liquor of claim 1 , further comprising at least one of components e) to g):
e) at least one alkylglucamide of the formula (I)

in which
R1 is a linear or branched alkyl group having 5 to 12 carbon atoms,
R2 is an alkyl group having 1 to 3 carbon atoms,

f) propylene glycol, dipropylene glycol, mixtures of propylene glycol and dipropylene glycol, each optionally in a mixture with polypropylene glycol and/or polyethylene glycol, each having up to ten repeat units,
g) at least one cosolvent, and/or
h) at least one auxiliary.

4. The spray liquor of claim 2 , wherein the at least one water-insoluble active ingredient d) is at least one water-insoluble pesticide.

5. The spray liquor of claim 1 , wherein the at least one electrolyte c) is selected from water-soluble salts of glufosinate.

6. The spray liquor of claim 2 , further comprising at least one customary formulation auxiliaries h) that are selected from the group consisting of nonpolar solvents, inert materials, stickers, wetters, dispersants, emulsifiers, penetrants, preservatives, fillers, carriers, dyes, agents that affect the pH or the viscosity, functional polymers, further adjuvants, and defoamers.

7. The spray liquor of claim 2 , wherein the water-insoluble active ingredient d) is selected from the group consisting of active pharmaceutical ingredients, active agrochemical ingredients, biocides and repellents.

8. The spray liquor of claim 2 , further comprising at least one of the following additional components e) to g):
e) at least one alkylglucamide of the formula (I)

in which
R1 is a linear or branched alkyl group having 5 to 12 carbon atoms,
R2 is an alkyl group having 1 to 3 carbon atoms,

f) propylene glycol, dipropylene glycol, mixtures of propylene glycol and dipropylene glycol, each optionally in a mixture with polypropylene glycol and/or polyethylene glycol, each having up to ten repeat units,
g) at least one cosolvent, and/or
h) at least one auxiliary.

9. The spray liquor of claim 1 , wherein the at least one electrolyte c) is selected from water-soluble salts of glyphosate.

10. The spray liquor of claim 1 , wherein the degree of polymerization of the at least one sulfated polyalkylene glycol is in the range of 5-60 repeat units per molecule.

11. The spray liquor of claim 1 , wherein the degree of polymerization of the at least one sulfated polyalkylene glycol is in the range of 10-80 repeat units per molecule.

12. The spray liquor of claim 1 , wherein the at least one sulfated polyalkylene glycol is provided as a mixture of oligomers or polymers having different degrees of polymerizations and/or different molecular weights.

13. The spray liquor of claim 1 , wherein
the proportion of the at least one sulfated polyalkylene glycol a) in the concentrate is 5% to 60% by weight, based on the total weight of the concentrate;
the proportion of water b) in the concentrate is 20% to 70% by weight, based on the total weight of the concentrate;
the proportion of the at least one electrolyte c) in the concentrate is 10% to 70% by weight, based on the total weight of the concentrate.

14. The spray liquor of claim 1 , wherein the spray liquor comprises 0.001% to 10% by weight of the at least one electrolyte c).

15. The spray liquor of claim 1 , wherein the spray liquor comprises 0.02% to 3% by weight of the at least one electrolyte c).

16. A method for improving plant wettability by a reduction in dynamic surface tension, comprising applying the spray liquor of claim 1 to a plant.

17. A method for control and/or abatement of unwanted plant growth, comprising contacting the unwanted plant, or habitat thereof with the spray liquor of claim 1 .

18. The method of claim 17 , wherein the spray liquor further comprises at least one water-insoluble active ingredient d).

Assignees

• Clariant Int Ltd

Inventors

• Baur Peter
• Aponte John
• Schweinitzer Gerd

Classifications

• A01N25/30 Primary

  characterised by the surfactants · CPC title

• A01N25/24

  containing ingredients to enhance the sticking of the active ingredients · CPC title

• C11D1/12

  Sulfonic acids or sulfuric acid esters; Salts thereof · CPC title

• C11D1/29

  Sulfates of polyoxyalkylene ethers · CPC title

• C11D3/046

  Salts · CPC title