Electrode coated with a film obtained from an aqueous solution comprising a water-soluble binder, production method thereof and uses of same

Patent metadata

Field	Value
Publication number	US-11699781-B2
Application number	US-202017117256-A
Country	US
Kind code	B2
Filing date	Dec 10, 2020
Priority date	Nov 13, 2002
Publication date	Jul 11, 2023
Grant date	Jul 11, 2023

Abstract

A method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.

First claim

The invention claimed is:

1. A process for preparing an electrochemical separator comprising spreading an aqueous solution on a support, the aqueous solution comprising:
at least one water soluble binder; and
at least one water soluble thickening agent, wherein the water soluble thickening agent is selected form the group consisting of natural celluloses, modified celluloses, natural polysaccharides and modified polysaccharides,
wherein the aqueous solution is essentially free of active materials and carbon, and
wherein the support comprises at least one metal.

2. The process according to claim 1 , wherein constituents of the aqueous solution have been prepared without using organic solvents.

3. The process according to claim 1 , wherein the resultant electrochemical separator has a porosity between 10 and 90%.

4. The process according to claim 1 , wherein the resultant electrochemical separator has a porosity between 30 and 50%.

5. The process according to claim 1 , wherein the aqueous solution is free of active materials and carbon.

6. The process according to claim 1 , wherein at least 90% of the water soluble binder and/or the water soluble thickening agent are soluble at room temperature.

7. The process according to claim 1 , wherein the water soluble thickening agent has a molecular weight between 27,000 and 250,000.

8. The process according to claim 1 , wherein the water soluble thickening agent is selected from the group consisting of carboxymethylcelluloses, hydroxymethylcelluloses and methylethylhydroxycelluloses.

9. The process according to claim 1 , wherein the water soluble thickening agent is a carboxymethylcellulose.

10. The process according to claim 1 , wherein the water soluble binder is a natural or synthetic rubber.

11. The process according to claim 1 , wherein the water soluble binder is a water soluble rubber is selected from the group consisting of SBRs, NBRs, HNBRs, CHRs and ACMs.

12. The process according to claim 1 , wherein the water soluble binder is an SBR.

13. The process according to claim 1 , wherein the water soluble binder is an SBR in the form of a paste at room temperature.

14. The process according to claim 1 , wherein the water soluble binder is a non-fluorinated binder.

15. The process according to claim 1 , wherein the water soluble binder is a non-fluorinated SBR in the form of a paste at room temperature.

16. The process according to claim 1 , wherein at least 95% of the water that is present in the aqueous solution is evaporated after spreading.

17. The process according to claim 16 , further comprising heat treatment in line of an extrusion process or by infrared.

18. The process according to claim 17 , wherein the heat treatment is conducted at a temperature between 80 and 130° Celsius for a period of time between 1 and 12 hours.

19. The process according to claim 1 , wherein the spreading is carried out in ambient air and by using an electrostatic method.

20. An electrochemical separator prepared according to claim 1 .

21. The electrochemical separator according to claim 20 , wherein the separator is cross-linked by UV thermal heating, E-Beam, or IR.

22. An electrochemical system comprising the separator of claim 20 .

Assignees

• Hydro Quebec

Inventors

• Zaghib Karim
• Armand Michel
• Guerfi Abdelbast
• Perrier Michel
• Dupuis Elisabeth
• Charest Patrick

Classifications

• H01M2300/0037

  Mixture of solvents · CPC title

• H01M2300/0042

  Four or more solvents · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/661

  Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence) · CPC title

• H01M4/1391

  of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title