Mold for glass forming and methods for forming glass using a mold

Patent metadata

Field	Value
Publication number	US-11697609-B2
Application number	US-202117905022-A
Country	US
Kind code	B2
Filing date	Feb 26, 2021
Priority date	Feb 27, 2020
Publication date	Jul 11, 2023
Grant date	Jul 11, 2023

Abstract

The present disclosure relates to a mold for glass forming, wherein the mold comprises a ceramic material, and wherein the ceramic material comprises aluminum nitride and hexagonal boron nitride, and wherein the ceramic material comprises from 50 to 80% by weight of aluminum nitride and from 20 to 50% by weight of hexagonal boron nitride, based on the total weight of the ceramic material. The present disclosure further relates to a process for using such molds to form curved glass plates.

First claim

The invention claimed is:

1. A mold for glass forming, wherein the mold comprises a ceramic material comprising from 50 to 80% by weight of aluminum nitride and from 20 to 50% by weight of hexagonal boron nitride, based on the total weight of the ceramic material,
and wherein the mean grain size of the aluminum nitride in the ceramic material is from 1.0 to 5.0 μm,
and wherein the density of the ceramic material is at least 85% of the theoretical density of the ceramic material,
and wherein the ceramic material further comprises boron oxide (B 2 O 3 ) in an amount of up to 2% by weight, based on the total weight of the ceramic material,
and wherein the ceramic material has a hardness of from 50 to 300 HBW 2.5/62.5, wherein the hardness is measured by the Brinell method according to DIN EN ISO 6506-1 (2013),
and wherein the mold has a contact surface having a surface roughness R a of at least 0.2 μm and at most 2.0 μm,
and wherein the mean grain size of the aluminum nitride in the ceramic material is determined by measuring the grain size of aluminum nitride on scanning electron microscopy (SEM) micrographs with a magnification of 10,000× of polished samples, wherein the longest diameter of each individual aluminum nitride grain is measured and the mean grain size is calculated as the average value of the longest diameter of 50 individual aluminum nitride grains,
and wherein the theoretical density of the ceramic material is calculated by the density of the pure aluminum nitride, which is 3.26 g/cm 3 , and the density of the pure hexagonal boron nitride, which is 2.25 g/cm 3 , and the respective fractions of aluminum nitride and hexagonal boron nitride in the ceramic material,
and wherein the surface roughness of the contact surface is measured according to ISO 4287 (1997).

2. The mold according to claim 1 , wherein the mean grain size of the aluminum nitride in the ceramic material is from 1.0 to 3.0 μm.

3. The mold according to claim 1 , wherein the ceramic material comprises from 55 to 65% by weight of aluminum nitride and from 35 to 45% by weight of hexagonal boron nitride.

4. The mold according to claim 1 , wherein the ceramic material comprises from 60 to 80% by weight of aluminum nitride and from 20 to 40% by weight of hexagonal boron nitride.

5. The mold according to claim 1 , wherein the ceramic material comprises up to 12% by weight of oxygen, based on the total weight of the ceramic material.

6. A method of forming a glass component having a curved surface, the method comprising
placing a glass plate between an upper part of a mold and a lower part of a mold to form an assembly, wherein the upper part of the mold is a mold according to claim 1 and the lower part of the mold is a mold according to claim 1 ,
placing the assembly into a furnace and heating it up to a temperature which is above the glass transition temperature of the glass to be formed; and
pressing the upper part of the mold for a defined time against the glass plate and the lower part of the mold, thereby forming the glass component having a curved surface.

7. The method of claim 6 , wherein the glass plate is brought into contact with the contact surface of the upper part of the mold and the contact surface of the lower part of the mold, wherein at least one of the contract surfaces is curved.

8. The method of claim 7 , wherein both of the contact surfaces are curved.

9. The method of claim 6 , wherein the ceramic material comprises from 55 to 65% by weight of aluminum nitride and from 35 to 45% by weight of hexagonal boron nitride, based on the total weight of the ceramic material.

10. The method of claim 6 , wherein the mean grain size of the aluminum nitride in the ceramic material is from 1.0 to 3.0 μm.

11. The method of claim 6 , wherein the density of the ceramic material is at least 87% of the theoretical density of the ceramic material.

12. The method of claim 6 , wherein the ceramic material comprises up to 8% by weight of oxygen, based on the total weight of the ceramic material.

13. A method of forming a glass component having a curved surface, the method comprising
placing a glass plate on a mold according to claim 1 to form an assembly, wherein the mold is a lower mold or an upper mold,
placing the assembly into a furnace and heating it up to a temperature which is above the glass transition temperature of the glass to be formed; and
applying a vacuum for a defined time, thereby forming the glass component having a curved surface.

14. The method of claim 13 , wherein the glass plate is brought into contact with the contact surface of the mold.

15. The method of claim 14 , wherein the contact surface is curved.

16. The method of claim 13 , wherein the ceramic material comprises from 55 to 65% by weight of aluminum nitride and from 35 to 45% by weight of hexagonal boron nitride, based on the total weight of the ceramic material.

17. The method of claim 13 , wherein the mean grain size of the aluminum nitride in the ceramic material is from 1.0 to 3.0 μm.

18. The method of claim 13 , wherein the density of the ceramic material is at least 87% of the theoretical density of the ceramic material.

19. The method of claim 13 , wherein the ceramic material comprises up to 8% by weight of oxygen, based on the total weight of the ceramic material.

Assignees

• 3M Innovative Properties Company

Inventors

• Joly Samuel F
• Victor Georg P
• Ruisinger Bernd

Classifications

• C04B2235/3409

  Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax · CPC title

• C04B2235/656

  characterised by specific heating conditions during heat treatment · CPC title

• C03B2215/07

  Ceramic or cermets · CPC title

• C03B11/084 Primary

  material composition or material properties of press dies therefor · CPC title

• C04B2235/9669

  Resistance against chemicals, e.g. against molten glass or molten salts · CPC title