Sealant-containing tire and related processes

Patent metadata

Field	Value
Publication number	US-11697306-B2
Application number	US-201716466949-A
Country	US
Kind code	B2
Filing date	Dec 14, 2017
Priority date	Dec 15, 2016
Publication date	Jul 11, 2023
Grant date	Jul 11, 2023

Abstract

Processes for producing a sealant layer-tire inner liner combination as well as a sealant layer-containing tire and related processes involving the sealant layer-containing tire are disclosed. The sealant layer is adhered to the tire inner liner, has a thickness of 2-8 mm and comprises 100 parts of at least one rubber, 90-500 phr of at least one tackifier, optionally one or more extenders, optionally at least one hydroscopic substance, and a cure package.

First claim

What is claimed is:

1. A process for producing a sealant layer-tire inner liner combination comprising:
a. providing a tire inner liner, wherein the inner liner includes a radially inward facing surface and a radially outward facing surface,
b. providing a sealant layer having an upper surface, a lower surface, and a thickness of 2-8 mm, and comprising a mixture of
i. 100 parts of at least one rubber selected from the group consisting of butyl rubber (optionally halogenated), natural rubber, polyisoprene, polybutadiene rubber, styrene-butadiene rubber, styrene-butadiene-isoprene rubber, isoprene-butadiene rubber, polychloroprene rubber, EPDM, nitrile rubber, polyisobutylene, and combinations thereof, wherein at least 60 parts of the at least one rubber comprise butyl rubber, halogenated butyl rubber, EPDM, or a combination thereof;
ii. 310-450 phr of at least one tackifier;
iii. one or more extenders in a total amount of 20 to 35 phr wherein the one or more extenders is selected from the group consisting of carbon black, silica, clay, titanium dioxide, calcium carbonate, graphite, talc, or a combination thereof, wherein carbon black is present in an amount of 20 to 30 phr;
iv. optionally at least one hydroscopic substance in an amount of 0.5 to 10 phr; and
v. a cure package including a vulcanizing agent limited to a sulfur-based compound and wherein the cure package excludes any peroxide or quinoline compounds; and

c. adhering the sealant layer either:
i. to the radially inward facing surface of the inner liner so that the lower surface of the sealant layer faces radially outward, or
ii. to the radially outward facing surface of the inner liner so that the lower surface of the sealant layer faces radially outward,

thereby producing a sealant layer-tire inner liner combination, wherein the mixture of the sealant layer contains less than 10 phr of any block copolymer and has an elongation at break of 400-1200% at 25° C.

2. The process of claim 1 , wherein
up to 200 parts of the at least one tackifier comprise polybutene.

3. The process of claim 1 , wherein the at least one tackifier comprises at least one of
a. at least one low molecular weight polymer or oligomer having a Mw of 700-150,000 grams/mole and a Mn of 500-100,000 grams/mole;
b. at least one resin selected from the group consisting of phenolic resins, aliphatic resins, cycloaliphatic resins, aromatic resins, terpene resins, guayule resins, and combinations thereof; or
c. polybutene having a Mn of 500-5000 grams/mole.

4. The process of claim 1 , wherein the at least one tackifier comprises a polar-functionalized polybutadiene having a Mn of 1200 to 10000 grams/mole, preferably maleic anhydride functionalized polybutadiene.

5. The process of claim 1 , wherein the extender includes 25 to 30 phr of carbon black.

6. The process of claim 1 , wherein the 10-35 phr of extender includes 1-10 phr of fumed silica.

7. The process of claim 1 , wherein the sealant layer is cured.

8. The process of claim 1 , wherein the upper surface of the sealant layer is cured and the remainder is uncured.

9. The process of claim 1 , wherein the upper surface of the sealant layer further comprises an outwardly facing detackifier coating.

10. The process of claim 1 , wherein the sealant layer further comprises a removable backing upon its lower surface which is removed prior to (c).

11. The process of claim 1 , wherein the radially inward facing surface of the inner liner comprises a polysiloxane-containing release and the adhering of the lower surface of the sealant layer in (c) is preceded by treating the radially inward facing surface of the inner liner with a rubber-containing liquid wherein the rubber-containing liquid comprises at least one conjugated diene monomer-containing rubber, polyurethane and at least one solvent to create an adhesion surface thereon.

12. The process of claim 1 , wherein the radially inward facing surface of the inner liner is substantially free of polysiloxane-containing release and the adhering of the lower surface of the sealant layer in (c) includes use of an adhesive.

13. The process of claim 1 , wherein the lower surface of the sealant layer further comprises a barrier layer.

14. The process of claim 1 , wherein the sealant layer has a width that varies by no more than 5% from the width of the radially inward facing surface of the inner liner of the tire as measured from belt-edge-to-belt edge.

15. A tire containing the sealant layer-tire inner liner combination produced according to the process of claim 1 .

16. The process of claim 1 , wherein the at least one tackifier is present in an amount of 310-400 phr.

17. A tire containing a sealant layer comprising
one or more belts, a road-contacting tread, an inner liner with a radially inward facing surface and a radially outward facing surface, and a sealant layer having an upper surface, a lower surface, and a thickness of 2-8 mm,
wherein the sealant layer is adhered to either to the radially inward facing surface of the inner liner so that the lower surface of the sealant layer faces radially outward or to the radially outward facing surface of the inner liner so that the lower surface of the sealant layer faces radially outward,
wherein the sealant layer comprises a mixture of
i. 100 parts of at least one rubber selected from the group consisting of butyl rubber (optionally halogenated), natural rubber, polyisoprene, polybutadiene rubber, styrene-butadiene rubber, styrene-butadiene-isoprene rubber, isoprene-butadiene rubber, polychloroprene rubber, EPDM, nitrile rubber, polyisobutylene, and combinations thereof, wherein at least 60 parts of the at least one rubber comprise butyl rubber, halogenated butyl rubber, EPDM, or a combination thereof;
ii. 310-450 phr of at least one tackifier;
iii. one or more extenders in a total amount of 10 to 35 wherein the one or more extenders is selected from the group consisting of carbon black, silica, clay, titanium dioxide, calcium carbonate, graphite, talc, or a combination thereof, wherein carbon black is present in an amount of 20 to 30 phr;
iv. optionally at least one hydroscopic substance in an amount of 0.5 to 10 phr; and
v. a cure package including a vulcanizing agent limited to a sulfur-based compound and wherein the cure package excludes any peroxide or quinoline compounds, wherein the mixture of the sealant layer contains less than 10 phr of any block copolymer and has an elongation at break of 400-1200% at 25° C.

18. The tire of claim 17 , wherein
(a) at least 60 parts of the 100 parts of rubber comprise butyl rubber, halogenated butyl rubber, EPDM, or a combination thereof, and
(b) the at least one tackifier comprises at least one of
i. at least one low molecular weight polymer or oligomer having a Mw of 700-150,000 grams/mole and a Mn of 500-100,000 grams/mole;
ii. at least one resin selected from the group consisting of phenolic resins, aliphatic resins, cycloaliphatic resins, aromatic resins, terpene resins, guayule resins, and combinations thereof; or
iii. polybutene having a Mn of 500-5000 grams/mole.

19. The tire of claim 17 , wherein the at least one tackifier of the sealant layer is present in an amount of 310-400 phr.

Assignees

• Bridgestone Americas Tire Operations Llc

Inventors

• Alexander Brian S
• Plotner Bradley S
• Widenor Ross W
• Griebel Jared J
• Liao Kung-Ching

Classifications

• B29D2030/0686

  Incorporating sealants on or into tyres not otherwise provided for; auxiliary operations therefore, e.g. preparation of the tyre · CPC title

• B60C5/14 Primary

  with impervious liner or coating on the inner wall of the tyre · CPC title

• B29L2030/008

  Innerliners · CPC title

• B60C19/12

  Puncture preventing arrangements · CPC title

• B29D30/0685 Primary

  Incorporating auto-repairing or self-sealing arrangements or agents on or into tyres (auto-repairing or self-sealing arrangements or agents B29C73/16; puncture preventing arrangements B60C19/12) · CPC title