Porous carbon material composites and their production process, adsorbents, cosmetics, purification agents, and composite photocatalyst materials

Patent metadata

Field	Value
Publication number	US-11697106-B2
Application number	US-202017066149-A
Country	US
Kind code	B2
Filing date	Oct 8, 2020
Priority date	Sep 29, 2008
Publication date	Jul 11, 2023
Grant date	Jul 11, 2023

Abstract

A porous carbon material composite formed of a porous carbon material and a functional material and equipped with high functionality. The porous carbon material composite is formed of (A) a porous carbon material obtainable from a plant-derived material having a silicon (Si) content of 5 wt % or higher as a raw material; and (B) a functional material adhered on the porous carbon material, and has a specific surface area of 10 m2/g or greater as determined by the nitrogen BET method and a pore volume of 0.1 cm3/g or greater as determined by the BJH method and MP method.

First claim

What is claimed is:

1. A process for producing a porous carbon material composite, the process comprising:
carbonizing a silicon-containing plant-derived material at from 800° C. to 1,400° C. and generating a precursor carbonized material with oxidized silicon compounds;
reducing the silicon in the precursor carbonized material by treating the carbonized material with a hydrofluoric acid or an alkali and removing the oxidized silicon compounds;
activating the precursor carbonized material after reducing the silicon in the precursor carbonized material by subjecting the precursor carbonized material to a steam stream and generating a porous carbon material; and
causing a functional material to adhere on the porous carbon material using a complexing treatment in which the porous carbon material is (a) immersed at 25° C. for 24 hours in a 0.5 mol/L aqueous solution of iron chloride, (b) then washed with water and, (c) then subjected to heat treatment at 750° C. for three hours in a nitrogen atmosphere to complete the creation of the porous carbon material composite.

2. The process of claim 1 , comprising activating the precursor carbonized material by subjecting the precursor carbonized material to the steam stream for at least two hours, the steam being at a temperature of 900 degrees Centigrade.

3. The process of claim 1 , comprising reducing the silicon in the precursor carbonized material by treating the carbonized material with the hydrofluoric acid.

4. The process for producing the porous carbon material composite according to claim 1 , wherein:
the plant-derived material has a silicon content of 5 wt % or higher;
the porous carbon material has a silicon content of 1 wt % or lower; and
the porous carbon material composite has a specific surface area of 10 m2/g or greater as determined by the nitrogen BET method and a pore volume of 0.1 cm3/g or greater as determined by the BJH method and the MP method.

5. The process of claim 1 , wherein:
the porous carbonized material has a cumulative pore volume of at least 0.18 cm3/g for pores sized 5 nm or greater,
the functional material is in a form of fine particles, thin films, or sea islands,
the functional material is dissimilar to the porous carbonized material, and
the porous carbonized material does not contain silicon carbide.

6. The process of claim 1 , wherein the functional material is titanium oxide or zinc oxide.

7. The process of claim 1 , wherein the functional material is cadmium sulfide, lead sulfide, cadmium selenide, lead selenide, zinc selenide, indium arsenide, gallium arsenide, indium phosphide, gallium phosphide, gallium antimonide, indium antimonide, or lanthanide oxide.

8. The process of claim 1 , wherein the porous carbonized material has a specific surface area of 50 m2/g or greater as determined by the nitrogen BET method.

9. The process of claim 1 , wherein the porous carbonized material has a specific surface area of 100 m2/g or greater as determined by the nitrogen BET method.

10. The process of claim 1 , wherein the porous carbonized material has a specific surface area of 400 m2/g or greater as determined by the nitrogen BET method.

11. The process of claim 1 , wherein the porous carbonized material has a cumulative pore volume of 0.1 cm3/g or greater as determined by the BJH method and the MP method.

12. The process of claim 1 , wherein the porous carbonized material has a cumulative pore volume of 0.3 cm3/g or greater as determined by the BJH method and the MP method.

13. The process of claim 1 , wherein the plant-derived material is rice husk.

14. The process of claim 1 , wherein the plant-derived material has a silicon content of 5 wt % or greater.

15. The process of claim 1 , wherein the functional material exhibits surface plasmon absorption or light absorption by a semiconductor.

16. The process of claim 1 , wherein the functional material is a magnetic material.

17. The process of claim 1 , wherein the functional material is composed of a noble metal, noble metal alloy, oxide semiconductor or compound semiconductor.

18. The process of claim 1 , wherein the functional material is composed of a component having a moisturizing effect and/or antioxidant effect.

Assignees

• Sony Corp

Inventors

• Iida Hironori
• Tabata Seiichiro
• Yamada Shinichiro
• Noguchi Tsutomu
• Yamanoi Shun

Classifications

• B01J20/20 Primary

  comprising free carbon; comprising carbon obtained by carbonising processes · CPC title

• B05D1/18

  performed by dipping · CPC title

• B01J20/28083

  being in the range 2-50 nm, i.e. mesopores · CPC title

• B01D2255/702

  Carbon · CPC title

• B01J20/0229

  Compounds of Fe · CPC title