Preparation of a fuel blend

Patent metadata

Field	Value
Publication number	US-11692148-B2
Application number	US-201816765991-A
Country	US
Kind code	B2
Filing date	Nov 22, 2018
Priority date	Nov 27, 2017
Publication date	Jul 4, 2023
Grant date	Jul 4, 2023

Abstract

A method is disclosed for preparing a renewable fuel blend. The method includes subjecting at least two feedstocks of different biological origins to catalytic cracking in a catalytic cracking unit and to hydrotreatment in a hydrotreatment unit to form a fuel blend having an aromatic hydrocarbon content from 26 to 42 wt-% and a paraffinic hydrocarbon content of less than 53 wt-%, as measured according to ASTM D2425-04 (2011). The fuel blend is formed by mixing the at least two feedstocks together before subjecting them to the catalytic cracking and hydrotreatment, or by obtaining a first fuel component and at least one further fuel component from the catalytic cracking and hydrotreatment of the at least two feedstocks, and mixing the first fuel component and the at least one further fuel component together.

First claim

The invention claimed is:

1. A method for preparing a renewable diesel fuel blend, the method comprising:
subjecting at least two different feedstocks of renewable biological origin, the at least two different feedstocks including a feedstock for obtaining a first fuel component and a feedstock for obtaining a further fuel component, to catalytic cracking in a catalytic cracking unit and to hydrotreatment in a hydrotreatment unit to form a renewable diesel fuel blend having an aromatic hydrocarbon content from 26 to 42 wt-% and a paraffinic hydrocarbon content of less than 53 wt-%, as measured according to ASTM D2425-04 (2011);
wherein the feedstock for obtaining the first fuel component of the renewable diesel fuel blend is tall oil pitch (TOP), and the feedstock for obtaining the further fuel component of the renewable diesel fuel blend includes at least one of used cooking oil (UCO) and animal fat (AF),
wherein the formed renewable diesel fuel blend contains 25-75 wt-% first fuel component obtained from tall oil pitch (TOP), and 25-75 wt-% further fuel component obtained from at least one of used cooking oil (UCO) and animal fat (AF),
wherein the renewable diesel fuel blend is formed by:
obtaining the first fuel component and the further fuel component from the catalytic cracking and hydrotreatment of the at least two feedstocks, and mixing said first fuel component and said further fuel component together; and

wherein a measured cloud point of the renewable diesel fuel blend is lower than a calculated cloud point of the fuel blend as a weighted mean of measured cloud points of individual components thereof, the individual components being the first fuel component and the at least one further fuel component, wherein the measured cloud points are measured according to ASTM D7689-11 (2012).

2. The method according to claim 1 , wherein 33 wt-% or more of the paraffinic hydrocarbon content of the renewable diesel fuel blend is i-paraffins.

3. The method according to claim 1 , wherein at least one of a first fuel component or at least one further fuel component of the renewable diesel fuel blend is a renewable middle distillate fuel component having a distillation range from 160° C. to 370° C.

4. The method as claimed in claim 1 , wherein the catalytic cracking comprises:
thermofor catalytic cracking (TCC).

5. The method as claimed in claim 1 , wherein the hydrotreatment is performed at a temperature from 200° C. to 400° C. and at a pressure from 20 bar to 150 bar in a presence of a hydrotreatment catalyst.

6. The method as claimed in claim 1 , wherein the method comprises:
subjecting at least one of a first fuel component or a further fuel component to isomerization.

7. The method as claimed in claim 1 , wherein the catalyst in the catalytic cracking includes at least one of aluminium based catalyst, lanthanum based catalyst, titanium based catalyst or silicon based catalyst.

8. The method as claimed in claim 1 , wherein the temperature in the catalytic cracking is from 450° C. to 470° C.

9. The method as claimed in claim 1 , wherein the method comprises:
subjecting the feedstock having animal fat to pretreatment before the catalytic cracking by at least one of adsorption, treatment with an ion exchange resin, or washing.

10. The method as claimed in claim 1 , wherein the method comprises:
subjecting a first and a further fuel component to fractionation by distillation.

11. The method according to claim 1 , wherein 33 to 40 wt-% or more of the paraffinic hydrocarbon content of the renewable diesel fuel blend is i-paraffins.

12. The method according to claim 2 , wherein at least one of a first fuel component or at least one further fuel component of the renewable diesel fuel blend is a renewable middle distillate fuel component having a distillation range from 180° C. to 360° C.

13. The method as claimed in claim 1 , wherein the temperature in the catalytic cracking is from 455° C. to 465° C.

14. The method as claimed in claim 1 , wherein the renewable diesel fuel blend has a cloud point that is lowered by approximately 20-30% than the cloud points of the individual fuel components.

15. A method for preparing a renewable diesel fuel blend, the method comprising:
subjecting at least two different feedstocks of renewable biological origin, the at least two different feedstocks including a feedstock for obtaining a first fuel component and a feedstock for obtaining a further fuel component, to catalytic cracking in a catalytic cracking unit and to hydrotreatment in a hydrotreatment unit to form a renewable diesel fuel blend having an aromatic hydrocarbon content from 26 to 42 wt-% and a paraffinic hydrocarbon content of less than 53 wt-%, as measured according to ASTM D2425-04 (2011);
wherein the feedstock for obtaining the first fuel component of the renewable diesel fuel blend is tall oil pitch (TOP), and the feedstock for obtaining the further fuel component of the renewable diesel fuel blend includes at least one of used cooking oil (UCO) and animal fat (AF),
wherein the formed renewable diesel fuel blend contains 25-75 wt-% first fuel component obtained from tall oil pitch (TOP), and 25-75 wt-% further fuel component obtained from at least one of used cooking oil (UCO) and animal fat (AF),
wherein the renewable diesel fuel blend is formed by:
mixing the at least two feedstocks together before subjecting them to the catalytic cracking and hydrotreatment; and
wherein a measured cloud point of the renewable diesel fuel blend is lower than a calculated cloud point of the fuel blend as a weighted mean of measured cloud points of individual components thereof, the individual components being the first fuel component and the at least one further fuel component, wherein the measured cloud points are measured according to ASTM D7689-11 (2012).

Assignees

• Neste Oyj

Inventors

• Nortio Jenni
• Kiiski Ulla
• Saikkonen Pirjo

Classifications

• C10G2300/1018

  of animal origin · CPC title

• C10G2300/1007

  Used oils · CPC title

• C10G69/14 Primary

  plural parallel stages only · CPC title

• C10G2300/1081

  Alkanes · CPC title

• C10G3/44

  characterised by the catalyst used · CPC title