Multiphase coatings with separated functional particles, and methods of making and using the same

Patent metadata

Field	Value
Publication number	US-11692109-B2
Application number	US-202117564903-A
Country	US
Kind code	B2
Filing date	Dec 29, 2021
Priority date	Aug 10, 2017
Publication date	Jul 4, 2023
Grant date	Jul 4, 2023

Abstract

Some variations provide a multiphase polymer composition comprising a first polymer material and a second polymer material that are chemically distinct, wherein the first polymer material and the second polymer material are microphase-separated on a microphase-separation length scale from about 0.1 microns to about 500 microns, wherein the multiphase polymer composition comprises first solid functional particles selectively dispersed within the first polymer material, and wherein the first solid functional particles are chemically distinct from the first polymer material and the second polymer material. Some embodiments provide an anti-corrosion composition comprising first corrosion-inhibitor particles or precursors selectively dispersed within the first polymer material, wherein the multiphase polymer composition optionally further comprises second corrosion-inhibitor particles or precursors selectively dispersed within the second polymer material. These multiphase polymer compositions may be used for other applications, such as self-cleaning, self-healing, or flame-retardant coatings. Methods of making and using these multiphase polymer compositions are disclosed.

First claim

What is claimed is:

1. A multiphase polymer composition comprising a first polymer material and a second polymer material that are chemically distinct, wherein said first polymer material and said second polymer material are microphase-separated on a microphase-separation length scale from 0.1 microns to 500 microns, wherein said multiphase polymer composition comprises first solid functional particles selectively dispersed within said first polymer material, and wherein said first solid functional particles are chemically distinct from said first polymer material and said second polymer material.

2. The multiphase polymer composition of claim 1 , wherein said first solid functional particles are capable of reacting with said second polymer material, in response to an environmental input selected from the group consisting of ultraviolet light, change in temperature, change in pressure, environmental solvents, change in humidity, change in pH, and combinations thereof.

3. The multiphase polymer composition of claim 1 , wherein said multiphase polymer composition is disposed on a surface, and wherein said first solid functional particles are capable of reacting with said surface, in response to an environmental input selected from the group consisting of ultraviolet light, change in temperature, change in pressure, environmental solvents, change in humidity, change in pH, and combinations thereof.

4. The multiphase polymer composition of claim 1 , wherein said first solid functional particles are dissolvable in water or an aqueous solvent.

5. The multiphase polymer composition of claim 1 , wherein said first solid functional particles are dissolvable in an organic solvent.

6. The multiphase polymer composition of claim 1 , wherein said multiphase polymer composition further comprises second solid functional particles selectively dispersed within said second polymer material, and wherein said second solid functional particles are chemically distinct from said first polymer material and said second polymer material.

7. The multiphase polymer composition of claim 1 , wherein said multiphase polymer composition is disposed on a surface, and wherein said second solid functional particles are capable of reacting with said surface, in response to an environmental input selected from the group consisting of ultraviolet light, change in temperature, change in pressure, environmental solvents, change in humidity, change in pH, and combinations thereof.

8. The multiphase polymer composition of claim 1 , wherein said first solid functional particles include inorganic particles, organic particles, or a combination thereof.

9. The multiphase polymer composition of claim 1 , wherein said first solid functional particles include oxidizing agents, reducing agents, or a combination thereof.

10. The multiphase polymer composition of claim 1 , wherein said first solid functional particles are selected from the group consisting of metals, metal oxides, organic oxides, ceramics, salts, polymers, and combinations thereof.

11. The multiphase polymer composition of claim 1 , wherein said first solid functional particles are surface-treated to enhance chemical compatibility with said first polymer material.

12. The multiphase polymer composition of claim 1 , wherein said first solid functional particles have an average particle size from 50 nanometers to 500 microns.

13. The multiphase polymer composition of claim 1 , wherein said first polymer material and said second polymer material are independently selected from the group consisting of polyesters, polyethers, polyacrylates, polymethacrylates, polyepoxides, polysiloxanes, cellulosic polymers, and combinations thereof.

14. The multiphase polymer composition of claim 1 , wherein one of said first polymer material or said second polymer material is a continuous matrix, and the other of said first polymer material or said second polymer material is a plurality of inclusions, dispersed within said continuous matrix.

15. The multiphase polymer composition of claim 1 , wherein said multiphase polymer composition contains a segmented block copolymer, wherein said first polymer material contains first soft segments of said segmented block copolymer, and wherein said second polymer material contains second soft segments of said segmented block copolymer.

16. The multiphase polymer composition of claim 15 , wherein said segmented copolymer composition comprises:
(a) one or more said first soft segments selected from fluoropolymers having an average molecular weight from 500 g/mol to 10,000 g/mol, wherein said fluoropolymers are (α,ω)-hydroxyl-terminated and/or (α,ω)-amine-terminated;
(b) one or more said second soft segments selected from polyesters or polyethers, wherein said polyesters or polyethers are (α,ω)-hydroxyl-terminated and/or (α,ω)-amine-terminated, wherein the molar ratio of said second soft segments to said first soft segments is optionally less than 2.0;
(c) one or more isocyanate species, or a reacted form thereof, possessing an isocyanate functionality of 2 or greater; and
(d) one or more polyol or polyamine chain extenders or crosslinkers, or a reacted form thereof.

17. The multiphase polymer composition of claim 15 , wherein said segmented block copolymer has the structure:

wherein:
X, Y═CH 2 —(O—CH 2 —CH 2 ) p -T, and X and Y are independently selected;
p=1 to 50;
T is a hydroxyl or amine terminal group;
m=1 to 100; and
n=0 to 100.

18. The multiphase polymer composition of claim 1 , wherein said multiphase polymer composition is present in or as a coating.

Assignees

• Hrl Lab Llc

Inventors

• Dustin Ashley M
• Nowak Andrew P
• Graetz Jason A
• Vajo John J
• Rodriguez April R

Classifications

• C08L101/02

  characterised by the presence of specified groups {, e.g. terminal or pendant functional groups} · CPC title

• C09D201/02

  characterised by the presence of specified groups {, e.g. terminal or pendant functional groups} · CPC title

• C08G81/00

  Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers (involving only carbon-to-carbon unsaturated bond reactions C08F299/00 {; polyester-amides C08G69/44; polyester-imides C08G73/16; polyamides-imides C08G73/14; block- or graft polymers containing polysiloxane sequences C08G77/42}) · CPC title

• C09D171/02 Primary

  Polyalkylene oxides · CPC title

• C08G2650/22

  characterised by the initiator used in polymerisation · CPC title