Acid/metal bifunctional catalyst systems produced with carbon coatings

Patent metadata

Field	Value
Publication number	US-11691139-B2
Application number	US-202016947706-A
Country	US
Kind code	B2
Filing date	Aug 13, 2020
Priority date	Aug 15, 2019
Publication date	Jul 4, 2023
Grant date	Jul 4, 2023

Abstract

A method of producing bifunctional catalyst systems that include a carbon-coated metal catalyst may comprise: coating a metal catalyst particle with a carbon-containing small molecule to produce a coated metal catalyst particle; carbonizing the carbon-containing small molecule on the coated metal catalyst particle to produce a carbon-coated metal catalyst particle; and mixing the carbon-coated metal catalyst particle with an acid catalyst particle to produce an acid/metal bifunctional catalyst system. Further, a method of producing bifunctional catalyst systems that include a carbon-coated acid catalyst may be similarly performed by coating a metal catalyst particle with a carbon-containing small molecule to produce a coated metal catalyst particle; carbonizing the carbon-containing small molecule on the coated metal catalyst particle to produce a carbon-coated metal catalyst particle; and mixing the carbon-coated metal catalyst particle with an acid catalyst particle to produce an acid/metal bifunctional catalyst system.

First claim

The invention claimed is:

1. A method comprising:
coating a metal catalyst particle with a carbon-containing small molecule to produce a coated metal catalyst particle;
carbonizing the carbon-containing small molecule on the coated metal catalyst particle to produce a carbon-coated metal catalyst particle; and
mixing the carbon-coated metal catalyst particle with an acid catalyst particle to produce an acid/metal bifunctional catalyst system.

2. The method claim 1 , wherein the acid catalyst particle is a carbon-coated acid catalyst particle.

3. The method of claim 1 , wherein carbonizing comprises:
exposing the coated metal catalyst particle to an elevated temperature of 200° C. to 400° C. in an inert atmosphere for 10 minutes to 24 hours.

4. The method claim 1 , wherein coating comprises:
exposing the metal catalyst particle to an aqueous suspension of the carbon-containing small molecule.

5. The method of claim 1 , wherein an amount of the carbon-containing small molecule used for the coating step is 75% or greater of an absorption capacity of the metal catalyst particle.

6. The method of claim 1 , wherein the carbon-containing small molecule is selected from the group consisting of: a saccharide, a polysaccharide, ethylene glycol, a polyethylene glycol, propylene glycol, a polypropylene glycol and any combination thereof.

7. The method of claim 1 , wherein the acid catalyst particle is selected from the group consisting of a zeolite, an ion exchanged zeolite, a molecular sieve, a metal oxide, and any combination thereof.

8. The method of claim 1 , wherein the metal catalyst particle is a M1/M2/Al catalyst, wherein M1 is selected from the group consisting of Cu, Ag, Au, Ru, Rh, Pd, Re, Os, Ir, Pt, and any combination thereof, and wherein M2 is selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Zn, a rare earth metal, a La series metal, a Y series metal, and any combination thereof.

9. The method of claim 1 , wherein the acid catalyst particle is present at 10 wt % to 90 wt % relative to a total catalyst weight in the acid/metal bifunctional catalyst system.

10. The method of claim 1 , wherein the acid catalyst particle is present at 25 wt % to 75 wt % relative to a total catalyst weight in the acid/metal bifunctional catalyst system.

11. The method of claim 1 , wherein the acid/metal bifunctional catalyst system further comprises inert particles up to 50 wt % of a total weight of the acid/metal bifunctional catalyst system.

12. The method of claim 1 wherein the mixing comprises:
dry mixing the carbon-coated metal catalyst particle with the acid catalyst particle to produce the acid/metal bifunctional catalyst system.

13. The method of claim 1 wherein the mixing comprises:
mixing the carbon-coated metal catalyst particle with the acid catalyst particle and a binder to form a dough; and
extruding the dough to produce the acid/metal bifunctional catalyst system.

14. The method of claim 1 wherein the mixing comprises:
mixing the carbon-coated metal catalyst particle with the acid catalyst particle and a solvent to form a slurry;
heating the slurry; and
drying the slurry to produce the acid/metal bifunctional catalyst system.

15. The method of claim 1 , further comprising:
activating the acid/metal bifunctional catalyst system in hydrogen at 150° C. to 350° C.; and
reacting the activated acid/metal bifunctional catalyst system with a feedstream comprising hydrogen and carbon monoxide.

16. A method comprising:
coating an acid catalyst particle with a carbon-containing small molecule to produce a coated acid catalyst particle;
carbonizing the carbon-containing small molecule on the coated acid catalyst particle to produce a carbon-coated acid catalyst particle; and
mixing the carbon-coated acid catalyst particle with a metal catalyst particle to produce an acid/metal bifunctional catalyst system.

17. The method claim 16 , wherein the metal catalyst particle is a carbon-coated metal catalyst particle.

18. The method of claim 16 , wherein carbonizing comprises:
exposing the coated acid catalyst particle to an elevated temperature of 200° C. to 400° C. in an inert atmosphere for 10 minutes to 24 hours.

19. The method of claim 16 , wherein coating comprises:
exposing the acid catalyst particle to an aqueous suspension of the carbon-containing small molecule.

20. The method of claim 16 , wherein the carbon-containing small molecule is selected from the group consisting of: a saccharide, a polysaccharide, ethylene glycol, a polyethylene glycol, propylene glycol, a polypropylene glycol and any combination thereof.

21. The method of claim 16 , wherein the acid catalyst particle is selected from the group consisting of a zeolite, an ion exchanged zeolite, a molecular sieve, a metal oxide, and any combination thereof.

22. The method of claim 16 , wherein the metal catalyst particle is a M1/M2/Al catalyst, wherein M1 is selected from the group consisting of Cu, Ag, Au, Ru, Rh, Pd, Re, Os, Ir, Pt, and any combination thereof, and wherein M2 is selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Zn, a rare earth metal, a La series metal, a Y series metal, and any combination thereof.

23. The method of claim 16 , wherein the metal catalyst particle is present at 10 wt % to 90 wt % relative to a total catalyst weight in the acid/metal bifunctional catalyst system.

24. The method of claim 16 , wherein the metal catalyst particle is present at 25 wt % to 75 wt % relative to a total catalyst weight in the acid/metal bifunctional catalyst system.

25. The method of claim 16 , wherein the acid/metal bifunctional catalyst system further comprises inert particles up to 50 wt % of a total weight of the acid/metal bifunctional catalyst system.

26. The method of claim 16 , wherein the mixing comprises:
dry mixing the carbon-coated acid catalyst particle with the metal catalyst particle to produce the acid/metal bifunctional catalyst system.

27. The method of claim 16 , wherein the mixing comprises:
mixing the carbon-coated acid catalyst particle with the metal catalyst particle and a binder to form a dough; and
extruding the dough to produce the acid/metal bifunctional catalyst system.

28. The method of claim 16 , wherein the mixing comprises:
mixing the carbon-coated acid catalyst particle with the metal catalyst particle and a solvent to form a slurry;
heating the slurry; and
drying the slurry to produce the acid/metal bifunctional catalyst system.

29. The method of claim 16 , further comprising:
activating the acid/metal bifunctional catalyst system in hydrogen at 150° C. to 350° C.; and
reacting the activated acid/metal bifunctional catalyst system with a feedstream comprising hydrogen and carbon monoxide.

Assignees

• Exxonmobil Technology & Engineering Company

Inventors

• Bai Chuansheng
• CUNNINGHAM Majosefina
• Dakka Jihad M
• Kamakoti Preeti
• Ramkrishnan Aruna
• Kovvali Anjaneya S
• Lee Anita S

Classifications

• B01J29/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively · CPC title

• B01J37/084 Primary

  Decomposition of carbon-containing compounds into carbon · CPC title

• B01J23/80

  with zinc, cadmium or mercury · CPC title

• B01J21/18

  Carbon · CPC title

• C07C41/01

  Preparation of ethers · CPC title