Method and device for carrying out endothermic gas phase-solid or gas-solid reactions

Patent metadata

Field	Value
Publication number	US-11691115-B2
Application number	US-201716346672-A
Country	US
Kind code	B2
Filing date	Oct 26, 2017
Priority date	Nov 4, 2016
Publication date	Jul 4, 2023
Grant date	Jul 4, 2023

Abstract

The present invention relates to a process for conducting endothermic gas phase or gas-solid reactions, wherein the endothermic reaction is conducted in a production phase in a first reactor zone, the production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections/or in the form of a fluidized bed, and the product-containing gas stream is drawn off from the production zone in the region of the highest temperature level plus/minus 200 K and the product-containing gas stream is guided through a second reactor zone, the heat recycling zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed, and, in the subsequent purge step, a purge gas is guided through the production zone and the heat recycling zone in the same flow direction, and, in a heating zone disposed between the production zone and the heat recycling zone, the heat required for the endothermic reaction is introduced into the product-containing gas stream and into the purge stream or into the purge stream, and then, in a regeneration phase, a gas is passed through the two reactor zones in the reverse flow direction and the production zone is heated up; the present invention further relates to a structured reactor comprising three zones, a production zone containing solid particles, a heating zone and a heat recycling zone containing a fixed bed, wherein the solid particles and the fixed bed consist of different materials.

First claim

The invention claimed is:

1. A process for conducting an endothermic gas phase or gas-solid reactions, the process comprising:
conducting an endothermic reaction of a reactant-containing gas in a production step in a first reactor zone, a production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections, or in the form of a fluidized bed,
drawing off a product-containing gas stream from the production zone, wherein the product-containing gas stream comprises one or more of carbon, hydrogen, olefins, propylene, butene, styrene, benzene, synthesis gas, CO, or HCN,
guiding the product-containing gas stream through a second reactor zone, a heat recovery zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed,
in a subsequent purge step, guiding an inert purge gas through the production zone and the heat recovery zone in the same flow direction as that of the product-containing gas stream,
wherein the purge gas comprises at least one gas selected from the group consisting of hydrogen, carbon monoxide, carbon dioxide, steam, nitrogen, argon, and mixtures thereof,
in a heating zone disposed between the production zone and the heat recovery zone, introducing the heat required for the endothermic reaction into the product-containing gas stream and into the purge stream or into the purge stream,
and then, in a regeneration phase, passing a gas through the two reactor zones in a reverse flow direction compared to the flow direction of the purge gas and heating up the production zone,
wherein the process is operated cyclically,
wherein the production step takes between 20% and 60% of a period duration of the process, the purge step takes between 10% and 40% of the period duration, and the regeneration phase between 20% and 60% of the period duration.

2. The process according to claim 1 , wherein the heat required for the endothermic reaction is introduced into the purge stream.

3. The process according to claim 1 wherein, during the regeneration phase, heat input in the heating zone has a heating output per unit volume of the heating zone of less than 100 kW/m 3 .

4. The process according to claim 1 , wherein a rate of descent of a solid stream in the production zone, averaged over a period, is in the range from 0 m/h to 50 m/h.

5. The process according to claim 1 , wherein a specific interfacial area between the solid particles in the production zone and a gas phase and/or the fixed bed in the heat recovery zone and a gas phase is greater than 50 in 2 /m 3 .

6. The process according to claim 1 , wherein the solid particles in the production zone are a catalyst for an endothermic gas phase reaction, a solid-state catalyst for an endothermic gas-solid reaction, and/or the product of an endothermic reaction, and wherein the fixed bed in the heat recovery zone is chemically inert in relation to a reverse reaction of the endothermic reaction.

7. The process according to claim 1 , wherein the ratio between the heat capacity of the gases that flow through the production bed during the regeneration phase and the heat capacity of the gases that flow through the production bed during the production phase is between 0.5 and 2.

8. The process according to claim 1 , wherein the heat required for the endothermic reaction is supplied by combustion of a fuel gas with the aid of an oxygen-rich gas in the heating zone, where the fuel gas is present in a main flow leaving the production zone during the production step or during the purge step and the fuel gas enters the heating zone at temperatures of 350° C. to 1200° C.

9. The process according to claim 1 , wherein the loading and unloading of the production zone with solid particles takes place while no reactant-containing gas is flowing through the production zone.

10. The process according to claim 1 , wherein the reactant-containing gas is introduced in a reactant-containing stream with a flow rate in the production zone of 0.001 to 20 m/s.

11. The process according to claim 1 , wherein the endothermic gas phase or gas-solid reactions that are conducted are the following processes:
preparation of hydrogen, of synthesis gas, of styrene, propene, hutene and/or benzene, of acetylene, of carbon monoxide, and of hydrogen cyanide.

12. The process according to claim 11 , wherein the endothermic gas phase or gas-solid reactions that are conducted are one of the following processes: preparation of synthesis gas, of styrene, propene, butene and/or benzene, of acetylene, of carbon monoxide, or of hydrogen cyanide.

13. The process according to claim 1 , wherein the product-containing gas stream comprises one or more of carbon, olefins, propylene, butene, styrene, benzene, synthesis gas, CO, or HCN.

14. A process comprising:
(a) introducing a reactant-containing gas in a flow direction into a preheated production zone and conducting an endothermic reaction in the production zone which is at least partly filled with solid particles to produce a product-containing gas stream, wherein the reactant-containing gas comprises one or more of carbon, hydrogen, olefins, propylene, butene, styrene, benzene, synthesis gas, CO, or HCN;
(b) optionally introducing heat into the product-containing gas stream in a heating zone downstream of the production zone;
(c) transferring heat from the product-containing stream from (b) to a packing of solid particles and/or structured internals in a heat recovery zone downstream of the heating zone;
(d) stopping the introduction of reactant-containing gas and purging the production zone and the heat recovery zone with an inert purge gas flowing in the same flow direction as that of the reactant-containing gas;
(e) introducing heat into the inert purge gas stream in the heating zone downstream of the production zone;
(f) stopping the introduction of inert purge gas and introducing a regeneration gas into the heat recovery zone with opposite flow direction compared to the inert purge gas;
(g) transferring heat from the solid particles and/or structured internals heated in (c) to the regeneration gas;
(h) transferring heat from the regeneration gas heated in (e) to the solid particles in the production zone; and
(i) stopping the introduction of regeneration gas into the heat recovery zone,
wherein the process is operated cyclically,
wherein the steps (a-c) takes between 20% and 60% of a period duration of the process, steps (d-e) takes between 10% and 40% of the period duration, and steps (f-i) takes between 20% and 60% of the period duration.

15. The process according to claim 14 , wherein the purge gas comprises at least one selected from the group consisting of hydrogen, carbon monoxide, carbon dioxide, steam, nitrogen, argon, and mixtures thereof.

Assignees

• Basf Se

Inventors

• Kolios Grigorios
• Zoels Bernd
• Kern Matthias
• Bernnat Jens
• Koenig Rene
• Glenk Friedrich
• Wechsung Achim

Classifications

• C01B2203/043

  Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration · CPC title

• C01B3/56

  by contacting with solids; Regeneration of used solids · CPC title

• B01J8/0492

  Feeding reactive fluids (for solid material, see B01J8/0015) · CPC title

• B01J38/32

  Indirectly heating or cooling material within regeneration zone or prior to entry into regeneration zone · CPC title

• B01J2219/0004

  Processes in series · CPC title