Iron based powder

Patent metadata

Field	Value
Publication number	US-11685979-B2
Application number	US-201716087377-A
Country	US
Kind code	B2
Filing date	Mar 15, 2017
Priority date	Mar 23, 2016
Publication date	Jun 27, 2023
Grant date	Jun 27, 2023

Abstract

Disclosed is a new diffusion-bonded powder consisting of an iron powder having 1-5%, preferably 1.5-4% and most preferably 1.5-3.5% by weight of copper particles diffusion bonded to the surfaces of the iron powder particles. The new diffusion bonded powder is suitable for producing components having high sintered density and minimum variation in copper content.

First claim

The invention claimed is:

1. A process for producing an iron-based powder comprising the following steps:
providing an iron powder having a content of oxygen of 0.3-1.2% by weight, a content of carbon of 0.1-0.5% by weight, a maximum particle size of at most 250 μm and at most 30% by weight below 45 μm and providing a copper containing powder having a maximum particle size, X 90 , of at most 22 μm and a weight average particle size, X 50 , of at most 15 μm,
mixing said iron powder and said copper containing powder,
subjecting said mixture to a reduction annealing process in a reducing atmosphere at 800-980° C. for a period of 20 minutes to 2 hours to obtain a cake, and
crushing the obtained cake and separating a resulting powder by desired particle size to form the iron-based powder.

2. The process according to claim 1 , wherein the iron-based powder has a maximum particle size of 250 μm, at least 75% is below 150 μm and at most 30% is below 45 μm, wherein the iron-based powder has an apparent density of at least 2.70 g/cm3 and an oxygen content of at most 0.16% by weight, and wherein other impurities are at most 1% by weight of the iron-based powder.

3. The process according to claim 2 , wherein the iron-based powder has a SSF-factor of at most 2.0, wherein the SSF-factor is defined as the quotient between the Cu content in weight % in the fraction of the iron-based powder which passes a 45 μm sieve and the Cu content in weight % in the fraction of the iron-based powder which does not pass a 45 μm sieve.

4. A process for forming a sintered component, the process comprising forming the iron-based powder according to claim 1 and forming the sintered component, wherein a maximum copper content in a cross section of the sintered component made from the iron-based powder is at most 100% higher than a nominal copper content,
wherein the sintered component is produced by:
mixing the iron-based powder with 0.5% of graphite, having a particle size, X90, of at most 15 μm measured with laser diffraction according to ISO 13320:1999, and 0.9% of lubricant;
transferring the obtained mixture into a compaction die for production of tensile strength samples (TS-bars) according to ISO 2740: 2009 and subjecting the obtained mixture to a compaction pressure of 600 MPa;
ejecting the compacted sample from the compaction die; and
subjecting the compacted sample to a sintering process at 1120° C. for a period of 30 minutes in an atmosphere of 90% nitrogen/10% hydrogen at atmospheric pressure,
wherein the maximum copper content is determined through lines scanning in a Scanning Electron Microscope (SEM) equipped with a system for Energy Dispersive Spectroscopy (EDS), wherein the magnification is 130×, working distance is 10 mm and the scanning time is 1 minute.

5. A process for forming a sintered component, the process comprising forming the iron-based powder according to claim 1 and forming the sintered component, wherein a largest pore area in a cross section of the sintered component made from the iron-based powder is at most 4000 μm 2 ,
wherein the sintered component is produced by:
mixing the iron-based powder with 0.5% of graphite, having a particle size, X90, of at most 15 μm measured with laser diffraction according to ISO 13320:1999, and 0.9% of lubricant;
transferring the obtained mixture into a compaction die for production of tensile strength samples (TS-bars) according to ISO 2740: 2009 and subjecting the obtained mixture to a compaction pressure of 600 MPa;
ejecting the compacted sample from the compaction die; and
subjecting the compacted sample to a sintering process at 1120° C. for a period of 30 minutes in an atmosphere of 90% nitrogen/10% hydrogen at atmospheric pressure,
wherein the largest pore area is determined in a Light Optical Microscope (LOM) at a magnification of 100× with the aid of a digital video camera and a computer based software and the total measured area is 26.7 mm 2 .

6. A process for forming a composition, the process comprising forming the iron-based powder according to claim 1 and mixing the iron-based powder with graphite and lubricant to form a composition, the composition comprising:
10 to 99.8 weight % of the iron-based powder;
graphite, in an amount of up to 1.5% weight %;
lubricant, in an amount of 0.3-1.5 weight %; and
optionally, at least one machinability enhancing additive, in an amount of up to 1.0 weight %.

7. The process according to claim 6 , the composition comprising:
50 to 99.8 weight % of the iron-based powder;
graphite, in an amount of up to 1.5% weight %;
lubricant, in an amount of 0.3-1.5 weight %; and
optionally, at least one machinability enhancing additive, in an amount of up to 1.0 weight %.

8. A process for forming a sintered component, the process comprising forming the composition according to claim 6 , the process further comprising:
subjecting the composition to a compaction process at a compaction pressure of at least 400 MPa to form a green component;
ejecting the green component;
sintering the green component in a neutral or reducing atmosphere at a temperature of about 1050-1300° C. for a period of 10 to 75 minutes; and
optionally, hardening the sintered component in a hardening process, wherein the hardening process is a process selected from case hardening, through hardening, induction hardening, and a hardening process including gas or oil quenching.

9. The process according to claim 8 , wherein a maximum copper content in a cross section of the sintered component is at most 100% higher than the nominal copper content, wherein the maximum copper content is determined through lines scanning in a Scanning Electron Microscope (SEM) equipped with a system for Energy Dispersive Spectroscopy (EDS), and wherein the magnification is 130×, working distance is 10 mm and the scanning time is 1 minute.

10. The process according to claim 8 , wherein a largest pore area of the sintered component is at most 4000 μm 2 , wherein the largest pore area is determined in a Light Optical Microscope (LOM) at a magnification of 100× with the aid of a digital video camera and a computer based software and the total measured area is 26.7 mm 2 .

Assignees

• Hoeganaes Ab Publ

Inventors

• Larsson Caroline
• Engström Ulf
• Szabo Christophe

Classifications

• Y10T428/12014

  having metal particles · CPC title

• B22F9/04

  starting from solid material, e.g. by crushing, grinding or milling ({C22C1/1084 takes precedence}; crushing, grinding or milling, in general, see the relevant subclasses, e.g. B02C) · CPC title

• C22C33/0264 Primary

  the maximum content of each alloying element not exceeding 5% · CPC title

• B22F2003/248

  Thermal after-treatment · CPC title

• B22F1/06

  Metallic powder characterised by the shape of the particles (nanosized particles B22F1/054) · CPC title