Manganese-doped nickel molybdate electrode material and methods for preparing the same

Patent metadata

Field	Value
Publication number	US-11685668-B2
Application number	US-202016838044-A
Country	US
Kind code	B2
Filing date	Apr 2, 2020
Priority date	Nov 19, 2019
Publication date	Jun 27, 2023
Grant date	Jun 27, 2023

Abstract

The present invention provides a method for producing a manganese-doped nickel molybdate electrode material including mixing a nickel salt solution with a manganese salt solution to form a mixture; adding a molybdate solution into the mixture and being subject to a thermal reaction; and obtaining the manganese-doped nickel molybdate electrode material after washing and drying of the reaction product. The nickel salt includes one or more of nickel nitrate, nickel chloride, and nickel acetate; the manganese salt includes one or more of manganese chloride, manganese nitrate, and manganese sulfate; and the molybdate includes one or more of sodium molybdate or ammonium molybdate. The present method utilizes a single reaction to produce a Mn-doped NiMoO 4 electrode material, which does not require using nickel molybdate as an intermediate product. The method simplifies the preparation process and makes it easy to be adjusted, thereby improving the electrochemical properties of the electrode material.

First claim

What is claimed is:

1. A method for producing a manganese-doped nickel molybdate electrode material, comprising:
mixing a nickel salt solution with a manganese salt solution to form a mixture;
adding a molybdate solution into the mixture and being subject to a thermal reaction to yield a reaction product;
obtaining a manganese-doped nickel molybdate electrode material after washing and drying of the reaction product;
wherein a molar ratio of solutes in the nickel salt solution to the manganese salt solution is 1:6-18; a molar ratio of solutes in the molybdate solution to the mixture of the nickel salt solution and the manganese salt solution is 1:0.6-1.5.

2. The method according to claim 1 , wherein the nickel salt comprises one or more of nickel nitrate, nickel chloride, and/or nickel acetate; the manganese salt comprises one or more of manganese chloride, manganese nitrate, and/or manganese sulfate; and the molybdate comprises one or more of sodium molybdate and/or ammonium molybdate.

3. The method according to claim 1 , wherein the nickel salt is nickel nitrate; the manganese salt is manganese nitrate; and the molybdate is sodium molybdate.

4. The method according to claim 1 , wherein a molar ratio of solutes in the nickel salt solution to the manganese salt solution is 1:9-15; a molar ratio of solutes in the molybdate solution to the mixture of the nickel salt solution and the manganese salt solution is 1:0.9-1.2.

5. The method according to claim 2 , wherein a molar ratio of solutes in the nickel salt solution to the manganese salt solution is 1:9-15; a molar ratio of solutes in the molybdate solution to the mixture of the nickel salt solution and the manganese salt solution is 1:0.9-1.2.

6. The method according to claim 3 , wherein a molar ratio of solutes in the nickel salt solution to the manganese salt solution is 1:9-15; a molar ratio of solutes in the molybdate solution to the mixture of the nickel salt solution and the manganese salt solution is 1:0.9-1.2.

7. The method according to claim 1 , wherein the nickel salt solution and the manganese salt solution have a concentration of 0.01-0.04 mol/L; the molybdate solution has a concentration of 0.01-0.04 mol/L.

8. The method according to claim 2 , wherein the nickel salt solution and the manganese salt solution have a concentration of 0.01-0.04 mol/L; the molybdate solution has a concentration of 0.01-0.04 mol/L.

9. The method according to claim 3 , wherein the nickel salt solution and the manganese salt solution have a concentration of 0.01-0.04 mol/L; the molybdate solution has a concentration of 0.01-0.04 mol/L.

10. The method according to claim 1 , wherein the thermal reaction has a reaction temperature of 140-180° C., and a reaction time thereof is from 8 to 12 hours.

11. The method according to claim 1 , wherein the thermal reaction has a reaction temperature of 150-170° C., and a reaction time thereof is from 8 to 10 hours.

Assignees

• Univ Changzhou

Inventors

• Chen Haiqun
• Chen Qun
• He Guangyu
• Zhu Junwu
• Yang Xiaowei
• Fu Yongsheng
• Chen Weidong
• Wang Hanming
• Yao Dachuan
• Zhao Yitao
• Yuan Jingjing
• Jiang Ling
• Hao Qingli

Classifications

• C01G53/82 Primary

  Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• C01P2002/52

  containing elements as dopants · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title