Secondary particles for anisotropic magnetic powder

Patent metadata

Field	Value
Publication number	US-11685654-B2
Application number	US-202117450451-A
Country	US
Kind code	B2
Filing date	Oct 8, 2021
Priority date	May 17, 2017
Publication date	Jun 27, 2023
Grant date	Jun 27, 2023

Abstract

Provided are a method of producing a titanium-containing rare earth-iron-nitrogen anisotropic magnetic powder having good magnetic properties, and secondary particles for a titanium-containing anisotropic magnetic powder. The method includes: obtaining a first precipitate containing R, iron, and titanium by mixing a first precipitating agent with a solution containing R, iron, and titanium, wherein R is at least one selected from Sc, Y, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, Er, Tm, and Lu; obtaining a second precipitate containing R and iron by mixing, in the presence of the first precipitate, a second precipitating agent with a solution containing R and iron; obtaining an oxide containing R, iron, and titanium by calcining the second precipitate; obtaining a partial oxide by heat treating the oxide in a reducing gas atmosphere; obtaining alloy particles by reducing the partial oxide; and obtaining an anisotropic magnetic powder by nitriding the alloy particles.

First claim

The invention claimed is:

1. Secondary particles for an anisotropic magnetic powder containing R, iron, and titanium,
each of the secondary particles comprising:
a core portion comprising primary particles containing R, iron, and titanium; and
a peripheral portion comprising primary particles containing R and iron,
wherein R is at least one selected from the group consisting of Sc, Y, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, Er, Tm, and Lu,
wherein titanium is not present in the peripheral portion.

2. The secondary particles according to claim 1 ,
wherein all of particle sizes of the secondary particles are within the range of 0.05 to 20 μm.

3. The secondary particles according to claim 1 ,
wherein all of particle sizes of the secondary particles are within the range of 0.1 to 10 μm.

4. The secondary particles according to claim 1 ,
wherein an average particle size of the secondary particles is defined as the particle size corresponding to the 50th percentile by volume from the smallest particle size in a particle size distribution, and
wherein the average particle size of the secondary particles is within the range of 0.1 to 10 μm.

5. An anisotropic magnetic powder comprising the secondary particles according to claim 1 ,
wherein the anisotropic magnetic powder is represented by the following formula:
Rv−xFe(100−v−w−t−z)NwTitLaxWz

wherein R is at least one selected from the group consisting of Sc, Y, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, Er, Tm, and Lu; 3≤v≤30; 5≤w≤15; 0<t≤1.0; 0≤x≤1.0; and 0≤z≤2.5.

6. The anisotropic magnetic powder according to claim 5 ,
wherein R is Sm.

Assignees

• Nichia Corp

Inventors

• Maehara Hisashi

Classifications

• H01F1/0593

  of tetragonal ThMn12-structure · CPC title

• H01F1/059

  and Va elements, e.g. Sm2Fe17N2 · CPC title

• C01P2002/52

  containing elements as dopants · CPC title

• H01F1/0551

  in the form of particles, e.g. rapid quenched powders or ribbon flakes · CPC title

• C01P2006/42

  Magnetic properties · CPC title