Method and installation for cryogenic separation of a gaseous mixture by methane scrubbing

Patent metadata

Field	Value
Publication number	US-11680747-B2
Application number	US-201716349698-A
Country	US
Kind code	B2
Filing date	Nov 16, 2017
Priority date	Nov 18, 2016
Publication date	Jun 20, 2023
Grant date	Jun 20, 2023

Abstract

In a process for the combined production of a) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or b) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, a still liquor is extracted from a scrubbing column and sent to a stripping column, a still liquor is extracted from the stripping column and sent to a separating column for carbon monoxide and methane and a cooling fluid is used at a pressure greater than that of the head of the separating column for cooling at least one fluid extracted at an intermediate level from the scrubbing column.

First claim

The invention claimed is:

1. A process for a combined production of i) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or ii) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, the process comprising the steps of:
a. cooling a gaseous mixture comprising hydrogen, carbon monoxide, and methane in a heat exchanger to form a cooled mixture;
b. sending the cooled mixture to a scrubbing column;
c. introducing a methane-rich liquid into the scrubbing column as scrubbing liquid;
d. withdrawing a hydrogen-enriched gas from the scrubbing column;
e. withdrawing a first vessel liquid from the scrubbing column and sending said first vessel liquid to a stripping column;
f. withdrawing a second vessel liquid from the stripping column and sending the second vessel liquid to a separation column that is configured to separate carbon monoxide and methane;
g. withdrawing a first carbon monoxide-rich fluid from a volume located above a top of the separation column;
h. withdrawing a second carbon monoxide-rich fluid from the volume located above the top of the separation column;
i. expanding the second carbon monoxide-rich fluid to an expanded pressure (P E ) and then warming the second carbon monoxide-rich fluid in the heat exchanger to form an expanded carbon monoxide gas;
j. introducing the expanded carbon monoxide gas into an inlet stage of a centrifugal compressor; and
k. using the first carbon monoxide-rich fluid as coolant fluid for cooling at least one fluid drawn off at an intermediate level of the scrubbing column,
wherein at least a portion of a third vessel liquid from the separation column constitutes the methane-rich liquid of the step c,
wherein the coolant fluid is at a greater pressure than that of the top of the separation column and the expanded pressure (P E ), and in that the coolant fluid, after having served to cool the at least one fluid drawn off at the intermediate level of the scrubbing column, is sent to an intermediate stage of the centrifugal compressor at a pressure exceeding the expanded pressure (P E ) in order to be compressed therein, such that the coolant fluid and the expanded carbon monoxide gas are introduced at different stages of the centrifugal compressor with the inlet stage being at a lower pressure than the intermediate stage.

2. The process as claimed in claim 1 , wherein a liquid from the volume located above the top of the separation column is reduced in pressure and sent to the separation column.

3. The process as claimed in claim 1 , wherein a pressure difference between the coolant fluid and that of the top of the separation column is at least 0.5 bar.

4. The process as claimed in claim 1 , wherein a pressure difference between the coolant fluid and that of the top of the separation column is at least 0.9 bar.

5. The process as claimed in claim 1 , wherein a portion of the third vessel liquid from the separation column is recovered as methane-rich product in liquid form or, after having been vaporized in the heat exchanger, in gaseous form.

6. The process as claimed in claim 1 , wherein a carbon monoxide-enriched gas provides reboiling duty for the stripping column and/or the separation column and is sent to the volume above the top of the separation column after reduction in pressure in a valve.

7. The process as claimed in claim 1 , wherein at least a portion of a carbon monoxide-rich liquid from the volume located above the top of the separation column is reduced in pressure and sent to the top of the separation column to be vaporized on contact with vapor rising inside the separation column and is subsequently mixed with a portion of a top gas of the separation column.

8. The process as claimed in claim 1 , wherein the separation column is operated at 1.6 bar.

9. The process as claimed in claim 1 , wherein a gas from the top of the separation column is sent to the inlet stage of the centrifugal compressor.

10. The process as claimed in claim 1 , wherein a carbon monoxide cycle comprising CO cycle gas is used to heat the stripping column and the separation column and to cool the top of the separation column, the centrifugal compressor serving to compress the CO cycle gas.

11. A process for a combined production of i) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or ii) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, the process comprising the steps of:
a. cooling a gaseous mixture comprising hydrogen, carbon monoxide, and methane in a heat exchanger to form a cooled mixture;
b. sending the cooled mixture to a scrubbing column;
c. introducing a methane-rich liquid into the scrubbing column as a scrubbing liquid;
d. withdrawing a hydrogen-enriched gas from the scrubbing column;
e. withdrawing a first vessel liquid from the scrubbing column and sending said first vessel liquid to a stripping column;
f. withdrawing a second vessel liquid from the stripping column and sending the second vessel liquid to a separation column that is configured to separate carbon monoxide and methane; and
g. withdrawing a first carbon monoxide-rich fluid from a volume located above a top of the separation column;
h. using the first carbon monoxide-rich fluid as a coolant fluid for cooling at least one fluid drawn off at an intermediate level of the scrubbing column; and
i. cooling a carbon monoxide stream in the heat exchanger and then introducing the carbon monoxide stream into an inlet stage of the centrifugal compressor, the carbon monoxide stream being at a first pressure,
wherein the carbon monoxide stream is comprised of carbon monoxide sourced from a location selected from the group consisting of the top of the separation column, the volume located above the top of the separation column, and combinations thereof,
wherein at least a portion of a third vessel liquid from the separation column constitutes the methane-rich liquid of the step c,
wherein the coolant fluid is at a greater pressure than that of the top of the separation column and the first pressure, and in that the coolant fluid, after having served to cool the at least one fluid drawn off at the intermediate level of the scrubbing column, is sent to an intermediate stage of the centrifugal compressor at a pressure exceeding the first pressure in order to be compressed therein, such that the coolant fluid and the carbon monoxide stream are introduced at different stages of the centrifugal compressor with the inlet stage being at a lower pressure than the intermediate stage.

Assignees

• Air Liquide

Inventors

• Billy Jean
• Gaertner Axelle
• Hernandez Antoine
• Tsevery Jean-Marc
• Victor Marie-Pascal

Classifications

• F25J2230/32

  Compression of the product stream · CPC title

• F25J2200/06

  in a classical double column flow-sheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column · CPC title

• F25J3/0271

  separation of H2/CO mixtures, i.e. of synthesis gas (production of carbon monoxide containing gas in general C01B32/40, C10J, C10K, production of hydrogen containing gas C01B3/00) · CPC title

• F25J2290/12

  Particular process parameters like pressure, temperature, ratios · CPC title

• F25J2205/30

  using a washing, e.g. "scrubbing" or bubble column for purification purposes · CPC title