Process and plant for the production of liquid hydrogen

Patent metadata

Field	Value
Publication number	US-11680746-B2
Application number	US-202016923896-A
Country	US
Kind code	B2
Filing date	Jul 8, 2020
Priority date	Jul 8, 2019
Publication date	Jun 20, 2023
Grant date	Jun 20, 2023

Abstract

Process and plant for the production of liquid hydrogen with a liquefier that has a variable cooling power dependent on the electrical power consumed. The liquefier is supplied with electricity by a first source of electricity at least one additional source of electricity that provides an intermittent or variable amount of electricity over time. Liquid hydrogen is produced at first thermodynamic conditions when the liquefier is supplied with a predetermined nominal electrical energy level and produced at subcooled conditions, with respect to the first thermodynamic conditions, when electricity supplied to the liquefier exceeds the nominal level.

First claim

What is claimed is:

1. A process for production of liquid hydrogen though use of a liquefier fed by a source of gaseous hydrogen, the liquefier having a variable cooling power dependent on an amount of electrical power consumed, the liquefier being supplied with electricity by a first source of electricity and at least one additional source of electricity that provides an amount of electricity which is intermittent or variable over time, wherein the liquid hydrogen is produced by the liquefier at first thermodynamic conditions when the liquefier is supplied with the electricity at a predetermined nominal electrical energy level and, when the liquefier is supplied with the electricity at an energy level exceeding the said nominal level, the hydrogen produced by the liquefier is subcooled with respect to the first thermodynamic conditions.

2. The process of claim 1 , wherein the liquid hydrogen produced by the liquefier at the first thermodynamic conditions is in a saturated state.

3. The process of claim 1 , wherein at least a portion of the electrical energy exceeding the nominal level, which is provided to the liquefier, is provided by the at least one additional source of electricity.

4. The process of claim 1 , wherein the liquefier produces an amount of the liquid hydrogen, which is predetermined over time with or without subcooling, wherein the amount of the liquid hydrogen produced during subcooling is a function of the energy level of the electrical energy exceeding the nominal level with which the liquefier is provided.

5. The process of claim 1 , wherein a temperature the subcooled hydrogen produced by the liquefier is lowered by 0.01 to less than 7 K, with respect to the first thermodynamic conditions, to the triple point of hydrogen.

6. The process of claim 1 , wherein a temperature the subcooled hydrogen produced by the liquefier is lowered by 0.01 to less than 4 K, with respect to the first thermodynamic conditions, to the triple point of hydrogen.

7. The process of claim 1 , wherein the electricity at the energy level exceeding the nominal level varies between 0% and 25% of the nominal level.

8. The process of claim 1 , wherein the electricity at the energy level exceeding the nominal level varies between 0% and 15% of the nominal level.

9. The process of claim 1 , wherein the first source comprises a power grid to which the liquefier is connected.

10. The process of claim 1 , wherein the at least one additional source ( 5 , 6 ) of electricity comprises at least one between: a generator ( 5 ) of electricity powered by wind energy, a generator ( 6 ) of electricity powered by solar energy.

11. The process of claim 1 , wherein the liquid hydrogen produced by the liquefier is transferred into a liquid storage facility.

12. The process of claim 11 , wherein:
when the liquefier is supplied with the electricity at the nominal electrical energy level, the liquid hydrogen produced by the liquefier is transferred into a tank at the first thermodynamic conditions, the first thermodynamic conditions corresponding to the bubble point of hydrogen at a storage pressure in the tank; and
when the liquefier is supplied with the electricity at the energy level exceeding the nominal level, the liquid hydrogen produced by the liquefier is transferred into the tank at a temperature lower than the bubble point of hydrogen at the storage pressure in the tank.

13. The process of claim 1 , wherein the liquid hydrogen is produced by the liquefier with a stable or unchanging flow rate.

14. A plant for production of liquid hydrogen, comprising a liquefier, a source of gaseous hydrogen connected to the liquefier, a first source of electricity connected to the liquefier in order to supply the liquefier with the electricity, at least one additional source of electricity which provides an amount of electricity which is intermittent or variable over time and which is connected to the liquefier in order to supply the liquefier with electricity, and an electronic controller, wherein:
the liquefier has a variable cooling power which depends on an amount of electrical power consumed;
the electronic controller is adapted and configured to manage a refrigerating power of the liquefier in order to produce the liquid hydrogen at first thermodynamic conditions when the liquefier is supplied with the electricity at a predetermined nominal electrical energy level, and produce the liquid hydrogen, which is subcooled with respect to the first thermodynamic conditions when the liquefier is supplied with the electricity at an energy level exceeding the said nominal level.

15. The plant of claim 14 , wherein the electronic controller is electrically connected to the first source of electricity, to the at least one additional source of electricity and to the liquefier, and the electronic controller is further adapted and configured to supply the liquefier with the electricity at the predetermined nominal electrical energy level from the first source, and to supply the liquefier with electricity at a greater electrical energy level than the predetermined nominal level by supplementing the electrical energy provided by the first source of electricity with available additional electrical energy provided by the at least one additional source of electricity.

Assignees

• Air Liquide

Inventors

• Allidieres Laurent
• Rigout Gregoire
• Barjhoux Pierre
• Marlier Pierre-Germain

Classifications

• H02J2101/24

  Photovoltaics · CPC title

• H02J2101/28

  Wind energy · CPC title

• F17C1/12

  with provision for thermal insulation ({F17C1/14, F17C1/16 take precedence}; thermal insulation in general F16L59/00) · CPC title

• F17C2221/012

  Hydrogen · CPC title

• F17C2225/041

  Stratification · CPC title