Manganese oxide nanoparticle carbon microparticle electrocatalyst and method of making from Albizia procera leaf

Patent metadata

Field	Value
Publication number	US-11680329-B2
Application number	US-201916589711-A
Country	US
Kind code	B2
Filing date	Oct 1, 2019
Priority date	Oct 1, 2019
Publication date	Jun 20, 2023
Grant date	Jun 20, 2023

Abstract

A method for making an electrocatalyst containing manganese oxide nanoparticles present on carbon obtained from Albizia procera (MnO x NPs-C) for electrochemical water oxidation. The method includes a thermal decomposition and forms a product with specific morphological variations, including crystalline structure, elemental composition, and chemical compatibility. The manganese oxide nanoparticles are well dispersed over the carbon. The amount of manganese oxide nanoparticles increases by increasing the amount of precursor. Single-phase formation of the Mn 3 O 4 , and Mn 3 O 4 along with MnO phase occurs at low and high amount of the precursor materials, respectively. The electrocatalyst can be used for the purpose electrolytic water splitting.

First claim

The invention claimed is:

1. An electrocatalyst, consisting of:
manganese oxide nanoparticles supported on carbon microparticles, the carbon microparticles having a flat platelet morphology with a thickness of less than 10 μm; and
optionally, at least one binder selected from the group consisting of a conductive polymer, polyethylene, polypropylene, polytetrafluoroethylene, polyvinylidene fluoride, styrene butadiene rubber, a tetrafluoroethylene hexafluoroethylene copolymer, a tetrafluoroethylene hexafluoropropylene copolymer, a tetrafluoroethylene perfluoroalkyl vinyl ether copolymer, ethylene-tetrafluoroethylene copolymer, polychlorotrifluoroethylene resin, a propylene-tetrafluoroethylene copolymer, and an ethylene-chlorotrifluoroethylene copolymer,
wherein the manganese oxide nanoparticles are in the form of crystallites having an average diameter in a range of from greater than 10 to 25 nm, and the carbon microparticles are derived from Albizia procera leaves and have an average longest dimension in the range of from 100 to 300 μm,
wherein the manganese oxide nanoparticles comprise hausmannite, tetragonal Mn 3 O 4 and optionally further cubic MnO, and
wherein the electrocatalyst has an Mn:C atomic ratio in a range of from 5:1 to 1:1.

2. The electrocatalyst of claim 1 , wherein the manganese oxide nanoparticles have an average longest dimension in a range of from 10 to 15 nm.

3. The electrocatalyst of claim 1 , wherein the manganese oxide nanoparticles have peaks in the XRD at 2(θ) Bragg angles of 37±1° and 42±1°.

4. The electrocatalyst of claim 1 , having an Mn:C atomic ratio in a range of from 1.6875:1 to 1.12625:1.

5. The electrocatalyst of claim 1 , wherein the crystallites of the manganese oxide have an average diameter in a range of from 13 to 15 nm.

6. The electrocatalyst of claim 1 , consisting of only the manganese oxide nanoparticles, the manganese oxide nanoparticles consisting of the hausmannite, tetragonal Mn 3 O 4 and optionally further the cubic MnO.

7. The electrocatalyst of claim 1 , wherein the manganese oxide nanoparticles have XRD peaks at 2θ at 18°, 30°, 31°, 32°, 36°, 38°, 44°, 510, 54°, 56°, 59°, 60°, 65°, and 74°.

8. An electrode, comprising:
an electrically conductive substrate coated with the electrocatalyst of claim 1 ,
wherein the electrode has a current density in a range of from 6 to 18 mA/cm 2 at 1.5 V, and
wherein the electrode has an over potential in a range of from 800 to 900 mV at 5 mA/cm 2 in 0.1 M NaOH.

9. The electrode of claim 8 , wherein the electrocatalyst is present on the surface of the electrode in an amount in a range of 0.2 to 10 mg/cm 2 .

10. The electrode of claim 9 , wherein the BET surface area of the electrode is in a range of from 140 to 230 m 2 /g.

11. The electrode of claim 10 , wherein the electrically conductive substrate is glassy carbon, graphite, gold, platinum, silver, iron, copper, aluminum, or a combination thereof.

12. An electrochemical cell, comprising:
a cathode electrode;
an anode electrode;
reference electrode; and
an electrolyte,
wherein at least one of electrodes is the electrode of claim 8 .

13. The electrochemical cell of claim 12 , wherein the electrolyte is an aqueous alkali metal hydroxide or a mineral acid at a concentration in a range of from 0.1 to 2.0 M.

14. The electrochemical cell of claim 12 , wherein the electrolyte is 0.5 M aqueous sulfuric acid.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Aziz Md Abdul
• Shah Syed Shaheen
• Yamani Zain Hassan

Classifications

• C25B11/079

  Manganese dioxide; Lead dioxide · CPC title

• C25B9/17

  Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof · CPC title

• C25B11/051

  Electrodes formed of electrocatalysts on a substrate or carrier · CPC title

• C25B1/04

  by electrolysis of water · CPC title

• C25B11/077 Primary

  the compound being a non-noble metal oxide · CPC title