Method for producing a washing agent with improved optical and rheological properties

Patent metadata

Field	Value
Publication number	US-11680225-B2
Application number	US-202016937103-A
Country	US
Kind code	B2
Filing date	Jul 23, 2020
Priority date	Jul 23, 2020
Publication date	Jun 20, 2023
Grant date	Jun 20, 2023

Abstract

A method for producing a liquid, surfactant-containing washing agent containing: i) 20 to 80 wt. % surfactant; ii) 2 to 15 wt. % fatty acid; iii) 0.3 to 8 wt. % of salt of a divalent cation; iv) 8 to 35 wt. % solvent; the method including the steps of: a) providing a first flowable washing agent preparation containing a surfactant, fatty acid and solvent; b) introducing the salt of a divalent cation into the liquid composition so as to form a salt-containing composition; c) mixing the salt-containing composition.

First claim

What is claimed is:

1. A method for producing an opacified liquid, surfactant-containing washing agent containing
i) 20 to 80 wt. % surfactant comprising anionic surfactant and non-ionic surfactant in a weight ratio from 1.4:1 to 1:1;
ii) 6 to 10 wt. % fatty acid;
iii) 0.3 to 8 wt. % of salt of a divalent cation;
iv) 8 to 35 wt. % solvent;
said method comprising the steps of:
a) providing a first flowable washing agent preparation containing a surfactant, fatty acid and solvent and having a turbidity below 60 NTU;
b) introducing the salt of a divalent cation into the washing agent preparation containing a surfactant, fatty acid and solvent so as to form a cloudy salt-containing composition having a turbidity above 60 NTU, wherein step b) does not include introducing an enzyme; and
c) mixing the salt-containing composition.

2. The method according to claim 1 , wherein the first flowable washing agent preparation is continuously introduced from a buffer container into a main line.

3. The method according to claim 2 , wherein the salt of a divalent cation is continuously introduced into the main line via a secondary line.

4. The method according to claim 2 , wherein the salt of a divalent cation is introduced into the main line, via a secondary line, in the form of an aqueous solution.

5. The method according to claim 2 , wherein the salt of a divalent cation is introduced into the main line via a secondary line having an outlet opening located within a mixing zone of a mixing device positioned within the main line.

6. The method according to claim 1 , wherein the liquid, surfactant-containing washing agent contains, based on the total weight thereof, 40 to 70 wt. % surfactant.

7. The method according to claim 1 , wherein the salt of a divalent cation is selected from the group consisting of magnesium salts and calcium salts.

8. The method according to claim 1 , wherein the liquid, surfactant-containing washing agent contains, based on the total weight thereof,
i) 20 to 80 wt. % surfactant including 20 to 50 wt. % anionic surfactant and 15 to 25 wt. % non-ionic surfactant;
ii) 6 to 10 wt. % fatty acid;
iii) 0.5 to 4 wt. % of a salt of a divalent metal cation;
iv) 8 to 35 wt. % solvent.

9. The method according to claim 1 , wherein the liquid, surfactant-containing washing agent has a yield point above 0.1 Pa when measured using a rotation rheometer at 20° C. with a cone plate with 40 mm diameter and a 2° cone angle.

10. The method according to claim 1 , wherein the liquid, surfactant-containing washing agent is enclosed in a water-soluble film after step c) so as to form a washing agent portion unit.

11. The method according to claim 1 , wherein 8 to 35 wt. % solvent contains 10 to 18 wt. % organic solvent.

12. The method according to claim 7 , wherein the salt of a divalent cation is selected from the group of magnesium chloride, magnesium sulfate, calcium chloride and calcium sulfate.

13. The method according to claim 7 , wherein the salt of a divalent cation is selected from the group of magnesium chloride and calcium chloride.

14. The method according to claim 9 , wherein the liquid, surfactant-containing washing agent has a yield point above 0.3 Pa.

15. The method according to claim 1 , wherein during step b) the washing agent preparation has a temperature of between −20° C. and 40° C.

16. The method according to claim 1 , wherein the liquid, surfactant-containing washing agent further contains v) 0.5 to 4 wt. % of a salt of a monovalent cation selected from the group of sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate, and combinations thereof.

17. The method according to claim 16 , wherein the monovalent cation is sodium chloride.

18. The method according to claim 16 , wherein the monovalent cation is 0.5 to 2 wt. %.

19. The method according to claim 1 , wherein the washing agent is free of enzymes.

20. The method according to claim 1 , wherein the washing agent contains less than 1 wt. % enzymes.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Meier Frank
• Schmiedel Peter
• Piorkowski Daniel Thomas
• Ott Thorsten
• Tkacz Piotr
• Hammelstein Stefan
• Blank Volker

Classifications

• C11D3/2079

  Monocarboxylic acids-salts thereof · CPC title

• C11D1/8305

  containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains · CPC title

• C11D1/22 Primary

  derived from aromatic compounds · CPC title

• C11D11/0017

  Chemistry & Metallurgy · mapped topic

• C11D3/046

  Salts · CPC title